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25th Congress Ampere on Magnetic Resonance and Related Phenomena pp 62–63Cite as

Electron Spin Resonance of Vitreous Thioborates

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Abstract

Thioborate glasses were studied by ESR at X-band (9 GHz). Without irradiation of samples, one observes an isotropic and narrow line with g=2.004 in the binary and ternary glasses; its origin is discussed and assigned to a trapped electron on a sulfur atom non-bonded to a boron one. After X-ray irradiation, three signals are detected: an unresolved hyperfine structure (hfs) in a B2S3 glass which is assigned to a BS+ 3/2 center, and two anisotropic signals, the first one being assigned to a sulfur hole center and the second one to an unpaired electron on a S-S bond.

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Author information

Authors and Affiliations

  1. Laboratoire d’Optique, Ultra-Hertzienne du CPMOH, France

    M. Haddad, R. Berger & Y. Servant

  2. Laboratoire de Chimie du Solide et ENSCPB, Université de Bordeaux-I, F-33405, Talence Cedex, France

    A. Levasseur

Authors
  1. M. Haddad
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  2. R. Berger
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  3. Y. Servant
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  4. A. Levasseur
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Editor information

Editors and Affiliations

  1. Physikalisches Institut, Universität Stuttgart, Pfaffenwaldring 57, D-7000, Stuttgart 80, Fed. Rep. of Germany

    Michael Mehring , Jost Ulrich von Schütz  & Hans Christoph Wolf ,  & 

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© 1990 Springer-Verlag Berlin Heidelberg

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Haddad, M., Berger, R., Servant, Y., Levasseur, A. (1990). Electron Spin Resonance of Vitreous Thioborates. In: Mehring, M., von Schütz, J.U., Wolf, H.C. (eds) 25th Congress Ampere on Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-76072-3_29

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  • DOI: https://doi.org/10.1007/978-3-642-76072-3_29

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-53136-4

  • Online ISBN: 978-3-642-76072-3

  • eBook Packages: Springer Book Archive

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