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The Dimensionality of Spin Carrier Transportation: A Comparison of 3-D Cu-DCNQI with 1-D TI-DCNQI by ESR and NMR

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25th Congress Ampere on Magnetic Resonance and Related Phenomena

Abstract

Among the large variety of highly conductive DCNQI-salts with metallic counterions, only Cu- and Tl-DCNQI exhibit NMR behavior like the metals Cu and Tl, respectively, i. e. considerable Knight shifts and longitudinal relaxation rates of Cu and H nuclei. Whereas in the copper salts there is no frequency dependence of the proton spin-relaxation rate, T-1 1H of Tl-DCNQI is proportional to w-1/2 pointing to a preferential 1-d electron spin-motion.

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References

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Authors and Affiliations

  1. 3. Physikalisches Institut, Universität Stuttgart, Pfaffenwaldring 57, D-7000, Stuttgart 80, Fed. Rep. of Germany

    U. Langohr, J. U. von Schütz & H. C. Wolf

  2. Institut für Organische Chemie, Universität Würzburg, Am Hubland, D-8700, Würzburg, Fed. Rep. of Germany

    S. Hünig & H. Meixner

Authors
  1. U. Langohr
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  2. J. U. von Schütz
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  3. H. C. Wolf
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  4. S. Hünig
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  5. H. Meixner
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Editors and Affiliations

  1. Physikalisches Institut, Universität Stuttgart, Pfaffenwaldring 57, D-7000, Stuttgart 80, Fed. Rep. of Germany

    Michael Mehring , Jost Ulrich von Schütz  & Hans Christoph Wolf ,  & 

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© 1990 Springer-Verlag Berlin Heidelberg

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Langohr, U., von Schütz, J.U., Wolf, H.C., Hünig, S., Meixner, H. (1990). The Dimensionality of Spin Carrier Transportation: A Comparison of 3-D Cu-DCNQI with 1-D TI-DCNQI by ESR and NMR. In: Mehring, M., von Schütz, J.U., Wolf, H.C. (eds) 25th Congress Ampere on Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-76072-3_264

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  • DOI: https://doi.org/10.1007/978-3-642-76072-3_264

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-53136-4

  • Online ISBN: 978-3-642-76072-3

  • eBook Packages: Springer Book Archive

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