Abstract
When the electric-field-gradient (efg) tensor at the site of a quadrupolar nucleus undergoes a substantial change at an order-disorder phase transition (temperature=TC), a very small admixture of the low-temperature order parameter into the high temperature phase can substantially influence the lineshape. Clear evidence of this effect is present in some crystals to temperatures T>3TC. It is shown that this is not an effect associated only with regions near an impurity, but is a bulk phenomenon. Temperature dependence of the lineshape above TC is related to the order parameter admixture
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References
John L. Bjorkstam, To be published in Ferroelectrics.
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© 1990 Springer-Verlag Berlin Heidelberg
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Bjorkstam, J.L. (1990). NMR/NQR Studies of Phase-Transition Precursors. In: Mehring, M., von Schütz, J.U., Wolf, H.C. (eds) 25th Congress Ampere on Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-76072-3_201
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DOI: https://doi.org/10.1007/978-3-642-76072-3_201
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