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Fractal Structure of a Cross-Linked Polymer Resin.A Pulsed Field Gradient, Paramagnetic Relaxation and Small Angle X-Ray Scattering Study

  • Conference paper
25th Congress Ampere on Magnetic Resonance and Related Phenomena

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Abstract

The diffusion of small solvent molecules in poly (4-vinylpyridine) resins (P4VP) crosslinked by divalent ions has been studied by pulsed field gradient and relaxation rate measurements, evidencing a distribution of pore size in the 3 nm-50 μm range with a surface fractal dimension of 2.6 well confirmed by small-angle X-ray scattering.

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Reference

  1. J.-P. KORB, B. SAPOVAL, C. CHACHATY, A.M. TISTCHENKO, J. Phys. Chem. (1990) 94, 953.

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Authors and Affiliations

  1. Département de Physique Générale, DPHG/SCM/BP121, CEN de Saclay, 91191, Gif-sur-Yvette cedex, France

    C. Chachaty

  2. Laboratoire de Physique de la Matière Condensée, Ecole Polytechnique, 91128, Palaiseau cedex, France

    J.-P. Korb

  3. Department of Physical and Macromolecular Chemistry, Gorlaeus Laboratories, University of Leiden, 2300 RA, Leiden, The Netherlands

    J. R. C. Van der Maarel

Authors
  1. C. Chachaty
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  2. J.-P. Korb
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  3. J. R. C. Van der Maarel
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Editor information

Editors and Affiliations

  1. Physikalisches Institut, Universität Stuttgart, Pfaffenwaldring 57, D-7000, Stuttgart 80, Fed. Rep. of Germany

    Michael Mehring , Jost Ulrich von Schütz  & Hans Christoph Wolf ,  & 

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© 1990 Springer-Verlag Berlin Heidelberg

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Chachaty, C., Korb, JP., Van der Maarel, J.R.C. (1990). Fractal Structure of a Cross-Linked Polymer Resin.A Pulsed Field Gradient, Paramagnetic Relaxation and Small Angle X-Ray Scattering Study. In: Mehring, M., von Schütz, J.U., Wolf, H.C. (eds) 25th Congress Ampere on Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-76072-3_168

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  • DOI: https://doi.org/10.1007/978-3-642-76072-3_168

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-53136-4

  • Online ISBN: 978-3-642-76072-3

  • eBook Packages: Springer Book Archive

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