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ESR-Investigations on the Solid Solution Mg2-x CuxP4O12

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Abstract

ESR-investigations were performed on the solid solution Mg2-xCuxP4O12. The single ion spectrum shows a tetragonal g-tensor which is caused by a planar-quadratic dynamic Jahn-Teller effect. At 2 K a HFS is observed. Pure Cu2P4O12 exhibits a static Jahn-Teller-distortion even at room temperature. The onset of ferrimagnetic ordering below 8 K leads to a pronounced shift of the g-values.

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References

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© 1990 Springer-Verlag Berlin Heidelberg

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Gunßer, W., Zimmermann, A. (1990). ESR-Investigations on the Solid Solution Mg2-x CuxP4O12 . In: Mehring, M., von Schütz, J.U., Wolf, H.C. (eds) 25th Congress Ampere on Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-76072-3_14

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  • DOI: https://doi.org/10.1007/978-3-642-76072-3_14

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-53136-4

  • Online ISBN: 978-3-642-76072-3

  • eBook Packages: Springer Book Archive

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