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Dynamic Study of Glassy Properties of Deuteron Glass Rb1-x(ND4)x D2 PO4 Using31P NMR Spin-Lattice Relaxation

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25th Congress Ampere on Magnetic Resonance and Related Phenomena
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Abstract

We report 31P NMR detection of separate T1 minima of ammonium (ND4 +) reorientations and intrabond (O-D—O) deuteron (acid) motions in the deuteron glass Rb1-x(ND4)xD2PO4. This is the first time both types of motion have been detected by means of dipolar relaxation using a spin-1/2 nucleus. The results compare favorably with similar measurements on the ammonium and acid deuterons.

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References

  1. R. Blinc, D.C. Ailion, B. Gunther, and S. Zumer, Phys. Rev. Lett 57. 2826 (1986).

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  2. R. Blinc, J. Dolinsek, V.H. Schmidt, and D.C. Ailion, Europhys. Lett. 6, 55 (1988).

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  3. S. Chen and D.C. Ailion, submitted to Phys. Rev. B (1990).

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© 1990 Springer-Verlag Berlin Heidelberg

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Chen, S., Ailion, D.C. (1990). Dynamic Study of Glassy Properties of Deuteron Glass Rb1-x(ND4)x D2 PO4 Using31P NMR Spin-Lattice Relaxation. In: Mehring, M., von Schütz, J.U., Wolf, H.C. (eds) 25th Congress Ampere on Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-76072-3_101

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  • DOI: https://doi.org/10.1007/978-3-642-76072-3_101

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-53136-4

  • Online ISBN: 978-3-642-76072-3

  • eBook Packages: Springer Book Archive

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