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Analytiker-Taschenbuch pp 225–270Cite as

Pyrolyse-Massenspektrometrie

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Part of the book series: Analytiker-Taschenbuch ((ANALYTIKERTB,volume 9))

Zusammenfassung

Die Pyrolyse (Py)-Massenspektrometrie (MS) ist ein wichtiges Verfahren zur Charakterisierung von hochmolekularen Verbindungen und wird häufig zur Untersuchung von synthetischen Polymeren, Biopolymeren, sowie komplexen Naturstoffen eingesetzt [1–4]. Die intakten makromolekularen Substanzen sind für eine direkte Untersuchung durch Massen-spektrometrie nicht geeignet, da sie nicht unzersetzt in die Gasphase gelangen. Zur massenspektrometrischen Bestimmung z. B. von Polymersequenzen ist es erforderlich, Hauptkettenbruchstücke zu erzeugen, die ohne Sekundärreaktionen in die Gasphase gebracht werden können. Während die nichtdestruktiven Analyseverfahren wie UV, IR und NMR usw. Aussagen zu funktionellen Gruppen und der unmittelbaren Nachbarschaft zwischen Untereinheiten liefern, können nach dem (destruktiven) thermischen Abbau mit der Massenspektrometrie lange Sequenzen der Polymerkette erfaßt werden.

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Author information

Authors and Affiliations

  1. Abteilung Spurenanalytik, Fachhochschule Fresenius, Dambachtal 20, D-6200, Wiesbaden, Deutschland

    H.-R. Schulten & B. Plage

Authors
  1. H.-R. Schulten
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  2. B. Plage
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Editor information

Editors and Affiliations

  1. Bismarckstr. 4, D-6940, Weinheim, Deutschland

    Helmut Günzler

  2. Sektion Chemie, Karl-Marx-Universität Leipzig, Liebigstr. 18, DDR-7010, Leipzig, Deutschland

    Rolf Borsdorf

  3. Institut Fresenius, Im Maisel, D-6204, Taunusstein, Deutschland

    Wilhelm Fresenius

  4. BASF Aktiengesellschaft, ZSZ/Analytik - M 320, D-6700, Ludwigshafen, Deutschland

    Walter Huber

  5. Rauenthaler Weg 26, D-6000, Frankfurt am Main 71, Deutschland

    Hans Kelker

  6. Analytik/Qualitätskontrolle, Dr. Karl Thomae GmbH, Postfach 1755, D-7950, Biberach, Deutschland

    Ingo Lüderwald

  7. Institut für Spektrochemie, Bunsen-Kirchhoff-Str. 11, D-4600, Dortmund 1, Deutschland

    Günter Tölg

  8. Robert-Bosch-Krankenhaus, Auerbachstr. 110, D-7000, Stuttgart 50, Deutschland

    Hermann Wisser

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© 1990 Springer-Verlag Berlin Heidelberg

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Schulten, HR., Plage, B. (1990). Pyrolyse-Massenspektrometrie. In: Günzler, H., et al. Analytiker-Taschenbuch. Analytiker-Taschenbuch, vol 9. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-75204-9_7

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  • DOI: https://doi.org/10.1007/978-3-642-75204-9_7

  • Publisher Name: Springer, Berlin, Heidelberg

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  • Online ISBN: 978-3-642-75204-9

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