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Sensing of Dibutyl Sulfide Using Carboxylic Acid Functionalized Single Walled Nanotubes

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The Physics of Semiconductor Devices (IWPSD 2017)

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Abstract

Functionalization group enhanced the response, sensitivity and repeatability of the gas sensor towards target analyte. In this paper we are reporting, fabrication of carboxylic acid functionalized single walled nanotubes (SWCNT-COOH) based gas sensor for sensing of Dibutyl Sulfide (DBS) a simulant of sulfur mustards. These gas sensors are fabricated by vacuum filtration method on flexible membrane. These fabricated gas sensor films are characterized by using SEM and Raman spectroscopy. It is observed that, CNTs are randomly distributed on the gas sensor surface. The Id/Ig ratio is 0.049, which indicates defect present on the gas sensor surface due to functionalization. These gas sensors are exposed to 3.36 ppm of DBS generated by permeation tube. The gas sensor gives repeatable response over five exposed cycles for 3.36 ppm of DBS. The detection limit of the gas sensor is <21 ppb of DBS.

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References

  1. http://nationalinterest.org/feature/the-five-most-deadly-chemical-weapons-war-10897 (Accessed 30 Oct 2017)

  2. https://www.opcw.org/about-chemical-weapons/types-of-chemical-agent/mustard-agents (Accessed 13 June 2017)

  3. J. Kong, N.R. Franklin, C. Zhou, M.G. Chapline, S. Peng, K. Cho, H. Dai, Nanotube molecular wires as chemical sensors. Science 287, 622–625 (2000)

    Article  ADS  Google Scholar 

  4. M. Asad, M.H. Sheikhi, M. Pourfath, M. Moradi, High sensitive and selective flexible H2S gas sensors based on Cu nanoparticle decorated SWCNTs. Sens. Actuators B Chem. 210, 1–8 (2015)

    Article  Google Scholar 

  5. J. Chaste, A. Eichler, J. Moser, G. Ceballos, R. Rurali, A. Bachtold, A nanomechanical mass sensor with yoctogram resolution. Nat. Nanotechnol. 7, 301–304 (2012)

    Article  ADS  Google Scholar 

  6. A.K. Naik, M.S. Hanay, W.K. Hiebert, X.L. Feng, M.L. Roukes, Towards single-molecule nanomechanical mass spectrometry. Nat. Nanotechnol. 4, 445–450 (2009)

    Article  ADS  Google Scholar 

  7. Y. Wang, J.T.W. Yeow, A review of carbon nanotubes-based gas sensors. J. Sens. 2009, 24 (2009)

    Article  Google Scholar 

  8. T. Zhang, S. Mubeen, N.V. Myung, M.A. Deshusses, Recent progress in carbon nanotube-based gas sensors. Nanotechnology 19, 332001 (2008)

    Article  Google Scholar 

  9. D. Kumar, P. Jha, A. Chouksey, J.S.B.S. Rawat, R.P. Tandon, P.K. Chaudhury, 4-(Hexafluoro-2-hydroxy isopropyl)aniline functionalized highly sensitive flexible SWCNT sensor for detection of nerve agent simulant dimethyl methylphosphonate. Mater. Chem. Phys. 181, 487–494 (2016)

    Article  Google Scholar 

  10. L. Kong, J. Wang, T. Luo, F. Meng, X. Chen, M. Li et al., Novel pyrenehexafluoroisopropanol derivative-decorated single-walled carbon nanotubes for detection of nerve agents by strong hydrogen-bonding interaction. Analyst 135, 368–374 (2010)

    Article  ADS  Google Scholar 

  11. S.L.H. Rebelo, A. Guedes, M.E. Szefczyk, A.M. Pereira, J.P. Araújo, C. Freire, Progresses on the Raman spectra analysis of covalently functionalized multiwall carbon nanotubes: unraveling disorder on graphitic materials. Phys. Chem. Chem. Phys. 1–40 (2016)

    Google Scholar 

  12. V.T. Le, C.L. Ngo, Q.T. Le, T.T. Ngo, D.N. Nguyen, M.T. Vu, Surface modification and functionalization of carbon nanotube with some organic compounds. Adv. Nat. Sci. Nanosci. Nanotechnol. 4(3) (2013)

    ADS  Google Scholar 

  13. P.K. Sharma, B. Sikarwar. G. Gupta, A.K. Nigam, B.K. Tripathi, P. Pandey, M. Boopathi, K Ganesan, B. Singh, A simple degradation method for sulfur mustard at ambient conditions using nickelphthalocyanine incorporated polypyrrole modified electrode. Appl. Nanosci. 4(1), 37–46 (2014)

    Article  ADS  Google Scholar 

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Correspondence to Deepak Kumar .

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Kumar, D., Jha, P., Chouksey, A., Rawat, J.S. (2019). Sensing of Dibutyl Sulfide Using Carboxylic Acid Functionalized Single Walled Nanotubes. In: Sharma, R., Rawal, D. (eds) The Physics of Semiconductor Devices. IWPSD 2017. Springer Proceedings in Physics, vol 215. Springer, Cham. https://doi.org/10.1007/978-3-319-97604-4_139

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