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Hardness, Friction and Wear Trends of Electroless Ni-W-P Coating Heat-Treated at Different Temperatures

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Advances in Materials, Mechanical and Industrial Engineering (INCOM 2018)

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Abstract

The motive of this work is to analyze the effect of heating temperature on hardness along with wear characteristics of electroless Ni-W-P coating. In binary (Ni-P) coating, tungsten (around 5.22 wt%) is incorporated and heat-treated at 200, 400 and 800 °C for constant time period (1 h). Hardness and tribological tests are conducted on both as-deposited and heat-treated specimens. Hardness is found to be in a co-relative state with wear resistance for the present coatings. However, hardness as well as wear resistance decreases upon heat treatment at 800 °C. Ni-W-P coating is also found to display a quite low and stable COF value with testing duration. Microstructural analysis shows the morphology of the coating to be nodular. With heat treatment, the coating turns fully crystalline with the precipitation of harder Ni3P phases. At higher temperature, oxide formation over the coating is also observed. Both abrasive and adhesive wear mechanisms are found to govern the wear behavior of the present electroless Ni-W-P coatings. It is found that inclusion of tungsten promotes the tribological properties of Ni-P coatings even when subjected to high-temperature heat treatment.

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References

  1. Sahoo, P., Das, S.K.: Tribology of electroless nickel coatings—a review. Mater. Des. 32(4), 1760–1775 (2011)

    Article  Google Scholar 

  2. Brenner, A., Riddell, G.E.: Nickel plating on steel by chemical reduction. J. Res. Natl. Bur. Stand. 37(1), 31–34 (1946)

    Article  Google Scholar 

  3. Agarwala, R.C., Agarwala, V.: Electroless alloy/composite coatings: a review. Sadhana 28(3), 475–493 (2003)

    Article  MathSciNet  Google Scholar 

  4. Biswas, A., Das, S.K., Sahoo, P.: Effect of heat treatment duration on tribological behavior of electroless Ni-(high)P coatings. IOP Conf. Ser. Mater. Sci. Eng. 149(1), 012045 (2016)

    Article  Google Scholar 

  5. Keong, K.G., Sha, W., Malinov, S.: Hardness evolution of electroless nickel–phosphorus deposits with thermal processing. Surf. Coat. Technol. 168(2), 263–274 (2003)

    Article  Google Scholar 

  6. Biswas, A., Das, S.K., Sahoo, P.: Correlating tribological performance with phase transformation behavior for electroless Ni-(high)P coating. Surf. Coat. Technol. 328(Supplement C), 102–114 (2017)

    Article  Google Scholar 

  7. Yoon, J.W., Park, J.H., Shur, C.C., Jung, S.B.: Characteristic evaluation of electroless nickel–phosphorus deposits with different phosphorus contents. Microelectron. Eng. 84(11), 2552–2557 (2007)

    Article  Google Scholar 

  8. Liu, H., Guo, R.X., Liu, Z.: Effects of laser nanocrystallisation on the wear behaviour of electroless Ni–W–P coatings. Surf. Coat. Technol. 219(Supplement C), 31–41 (2013)

    Article  Google Scholar 

  9. Guo, Z., Keong, K.G., Sha, W.: Crystallisation and phase transformation behaviour of electroless nickel phosphorus platings during continuous heating. J. Alloy. Compd. 358(1), 112–119 (2003)

    Article  Google Scholar 

  10. Erming, M., Shoufu, L., Pengxing, L.: A transmission electron microscopy study on the crystallization of amorphous Ni-P electroless deposited coatings, Metallurgical Coatings. In: Proceedings of the 15th International Conference on Metallurgical Coatings, pp. 273–280 (1988)

    Google Scholar 

  11. Keong, K.G., Sha, W., Malinov, S.: Crystallisation kinetics and phase transformation behaviour of electroless nickel–phosphorus deposits with high phosphorus content. J. Alloy. Compd. 334(1), 192–199 (2002)

    Article  Google Scholar 

  12. Hou, K.H., Jeng, M.C., Ger, M.D.: The heat treatment effects on the structure and wear behavior of pulse electroforming Ni–P alloy coatings. J. Alloy. Compd. 437(1), 289–297 (2007)

    Article  Google Scholar 

  13. Tomlinson, W.J., Wilson, G.R.: The oxidation of electroless Ni-B and Ni-P coatings in air at 800 to 1000°C. J. Mater. Sci. 21(1), 97–102 (1986)

    Article  Google Scholar 

  14. Balaraju, J.N., Rajam, K.S.: Electroless deposition of Ni–Cu–P, Ni–W–P and Ni–W–Cu–P alloys. Surf. Coat. Technol. 195(2), 154–161 (2005)

    Article  Google Scholar 

  15. Palaniappa, M., Seshadri, S.K.: Structural and phase transformation behaviour of electroless Ni–P and Ni–W–P deposits. Mater. Sci. Eng. A 460461(Supplement C), 638–644 (2007)

    Article  Google Scholar 

  16. Hu, Y., Wang, T., Meng, J., Rao, Q.: Structure and phase transformation behaviour of electroless Ni–W–P on aluminium alloy. Surf. Coat. Technol. 201(3), 988–992 (2006)

    Article  Google Scholar 

  17. Allahyarzadeh, M.H., Aliofkhazraei, M., Rezvanian, A.R., Torabinejad, V., Rouhaghdam, A.R.S.: Ni-W electrodeposited coatings: characterization, properties and applications. Surf. Coat. Technol. 307(Part A), 978–1010 (2016)

    Article  Google Scholar 

  18. Roy, S., Sahoo, P.: Optimization of multiple roughness characteristics of chemically deposited Ni-PW coating using weighted principal component analysis. ISRN Mechanical Engineering, Article ID 495857, pp. 7 pages (2012)

    Google Scholar 

  19. Hu, Y.J., Xiong, L., Meng, J.: Electron microscopic study on interfacial characterization of electroless Ni–W–P plating on aluminium alloy. Appl. Surf. Sci. 253(11), 5029–5034 (2007)

    Article  Google Scholar 

  20. Selvi, V.E., Chatterji, P., Subramanian, S., Balaraju, J.N.: Autocatalytic duplex Ni–P/Ni–W–P coatings on AZ31B magnesium alloy. Surf. Coat. Technol. 240(Supplement C), 103–109 (2014)

    Article  Google Scholar 

  21. Tsai, Y.Y., Wu, F.B., Chen, Y.I., Peng, P.J., Duh, J.G., Tsai, S.Y.: Thermal stability and mechanical properties of Ni–W–P electroless deposits. Surf. Coat. Technol. 146147(Supplement C), 502–507 (2001)

    Article  Google Scholar 

  22. Mukhopadhyay, A., Duari, S., Barman, T.K., Sahoo, P.: Investigation of wear behavior of electroless Ni-PW coating under dry and lubricated conditions using RSM and fuzzy logic. Portugaliae Electrochimica Acta 34(4), 231–255 (2016)

    Article  Google Scholar 

  23. Eraslan, S., Ürgen, M.: Oxidation behavior of electroless Ni–P, Ni–B and Ni–W–B coatings deposited on steel substrates. Surf. Coat. Technol. 265(Supplement C), 46–52 (2015)

    Article  Google Scholar 

  24. Duari, S., Mukhopadhyay, A., Barman, T.K., Sahoo, P.: Tribological performance optimization of electroless nickel coatings under lubricated condition. In: Design and Optimization of Mechanical Engineering Products IGI Global, pp. 250–280 (2018)

    Google Scholar 

  25. Mukhopadhyay, A., Barman, T.K., Sahoo, P.: Tribological behavior of sodium borohydride reduced electroless nickel alloy coatings at room and elevated temperatures. Surf. Coat. Technol. 321, 464–476 (2017)

    Article  Google Scholar 

  26. Mukhopadhyay, A., Duari, S., Barman, T.K., Sahoo, P.: Wear behavior of electroless Ni-P-W coating under lubricated condition—a Taguchi based approach. IOP Conf. Ser. Mater. Sci. Eng. 149(1), 012004 (2016)

    Article  Google Scholar 

  27. Duari, S., Mukhopadhyay, A., Barman, T.K., Sahoo, P.: Study of wear and friction of chemically deposited Ni-P-W coating under dry and lubricated condition. Surf. Interfaces 6, 177–189 (2017)

    Article  Google Scholar 

  28. Sahoo, P., Roy, S.: Tribological behavior of electroless Ni-P, Ni-P-W and Ni-P-Cu coatings: a comparison. Int. J. Surf. Eng. Interdisc. Mater. Sci. (IJSEIMS) 5(1), 1–15 (2017)

    Google Scholar 

  29. Mukhopadhyay, A., Barman, T.K., Sahoo, P.: Tribological behavior of electroless Ni–B–W coating at room and elevated temperatures. In: Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology, pp. 1350650118755781 (2018)

    Google Scholar 

  30. Palaniappa, M., Seshadri, S.K.: Friction and wear behavior of electroless Ni–P and Ni–W–P alloy coatings. Wear 265(5), 735–740 (2008)

    Article  Google Scholar 

  31. Balaraju, J.N., Raman, N., Manikandanath, N.T.: Nanocrystalline electroless nickel poly-alloy deposition: incorporation of W and Mo. Trans. IMF 92(3), 169–176 (2014)

    Article  Google Scholar 

  32. Balaraju, J.N., Kalavati, Rajam, K.S.: Surface morphology and structure of electroless ternary NiWP deposits with various W and P contents. J. Alloy. Compd. 486(1), 468–473 (2009)

    Article  Google Scholar 

  33. Wu, F.B., Tien, S.K., Chen, W.Y., Duh, J.G.: Microstructure evaluation and strengthening mechanism of Ni–P–W alloy coatings. Surf. Coat. Technol. 177178(Supplement C), 312–316 (2004)

    Article  Google Scholar 

  34. Tien, S.K., Duh, J.G., Chen, Y.I.: The influence of thermal treatment on the microstructure and hardness in electroless Ni–P–W deposit. Thin Solid Films 469470(Supplement C), 333–338 (2004)

    Article  Google Scholar 

  35. Koiwa, I., Usuda, M., Osaka, T.: Effect of heat-treatment on the structure and resistivity of electroless Ni-W-P alloy films. J. Electrochem. Soc. 135(5), 1222–1228 (1988)

    Article  Google Scholar 

  36. Mukhopadhyay, A., Duari, S., Barman, T.K., Sahoo, P.: Optimization of wear behavior of electroless Ni-PW coating under dry and lubricated conditions using genetic algorithm (GA). Jurnal Tribologi 11, 24–48 (2016)

    Google Scholar 

  37. Krishnaveni, K., Sankara Narayanan, T.S.N., Seshadri, S.K.: Electroless Ni–B coatings: preparation and evaluation of hardness and wear resistance. Surf. Coat. Technol. 190(1), 115–121 (2005)

    Article  Google Scholar 

  38. Karthikeyan, S., Vijayaraghavan, L.: Investigation of the surface properties of heat treated electroless Ni–P coating. Trans. IMF 94(5), 265–273 (2016)

    Article  Google Scholar 

  39. Sahoo, P.: Wear behaviour of electroless Ni–P coatings and optimization of process parameters using Taguchi method. Mater. Des. 30(4), 1341–1349 (2009)

    Article  Google Scholar 

  40. Sahoo, P., Pal, S.K.: Tribological performance optimization of electroless Ni–P coatings using the Taguchi method and grey relational analysis. Tribol. Lett. 28(2), 191–201 (2007)

    Article  Google Scholar 

  41. Gawne, D.T., Ma, U.: Wear mechanisms in electroless nickel coatings. Wear 120(2), 125–149 (1987)

    Article  Google Scholar 

  42. Kundu, S., Das, S.K., Sahoo, P.: Tribological behaviour of electroless Ni-P deposits under elevated temperature. Silicon, 1–14 (2016)

    Google Scholar 

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Acknowledgements

The first author would like to acknowledge the financial assistance and facilities provided by University Grants Commission (UGC), Govt. of India through Rajiv Gandhi National Fellowship.

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Correspondence to Abhijit Biswas .

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Biswas, A., Das, S.K., Sahoo, P. (2019). Hardness, Friction and Wear Trends of Electroless Ni-W-P Coating Heat-Treated at Different Temperatures. In: Sahoo, P., Davim, J. (eds) Advances in Materials, Mechanical and Industrial Engineering. INCOM 2018. Lecture Notes on Multidisciplinary Industrial Engineering. Springer, Cham. https://doi.org/10.1007/978-3-319-96968-8_5

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  • DOI: https://doi.org/10.1007/978-3-319-96968-8_5

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