Abstract
The theory of NMR line shapes for systems of coupled nuclei undergoing any type of exchange is exposed, with the focus on the intermolecular processes. The issue of molecular symmetry in intermolecular exchange is addressed. The formalism is illustrated by a number of simple examples, where explicit forms of the exchange superoperators are presented.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Change history
06 February 2019
In the original version of the book, belated corrections from author for Chapters 2–7, 9 and Appendix C have been incorporated. The correction book has been updated with the changes.
References
J.I. Kaplan, G. Fraenkel, J. Am. Chem. Soc. 94, 2907 (1972)
J.I. Kaplan, J. Chem. Phys. 29, 462 (1958)
G. Binsch, J. Am. Chem. Soc. 91, 1304 (1969)
S. Szymański, Mol. Phys. 60, 897 (1987)
L.T. Kuhn (ed.), in Hyperpolarization methods in NMR Spectroscopy (Springer, Heidelberg, 2013)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2018 Springer International Publishing AG, part of Springer Nature
About this chapter
Cite this chapter
Szymański, S., Bernatowicz, P. (2018). Discrete Molecular Dynamics and NMR Line Shape Effects. General Exchange. In: Classical and Quantum Molecular Dynamics in NMR Spectra. Springer, Cham. https://doi.org/10.1007/978-3-319-90781-9_6
Download citation
DOI: https://doi.org/10.1007/978-3-319-90781-9_6
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-90780-2
Online ISBN: 978-3-319-90781-9
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)