Abstract
The impact of indoor atmospheric corrosion on Ag-based cultural heritage objects stored in the basement of the Egyptian Museum was assessed in the framework of a 2-year pilot study. In this project, temperature and relative humidity data logging and sterling silver coupons, as microclimate indicators, have been employed. The environmental conditions, the indoor sources of atmospheric pollutants, and the aerosol species from Cairo city, as well as the transportation of species by the winds, are responsible for silver tarnishing and deposition of both inorganic particulates and organic carbon. Sulfides and chlorides are the main corrosive agents detected on the coupon surfaces. Different corrosion patterns were reported for each monitored location of the museum. These preliminary results contribute to the investigation of silver corrosion and provide useful guidelines for future actions regarding metal artifacts safekeeping and environmental control.
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References
Bennett HE et al (1969) Formation and growth of tarnish on evaporated silver films. J Appl Phys 40(8):3351–3360. https://doi.org/10.1063/1.1658187
Pope D, Gibbens HR, Moss RL (1968) The tarnishing of Ag at naturally-occurring H2S and SO2 levels. Corros Sci 8:883–887. https://doi.org/10.1016/S0010-938X(68)80141-6
Ingo GM et al (2015) Indoor environmental corrosion of Ag-based alloys in the Egyptian museum (Cairo, Egypt). Appl Surf Sci 326:222–235. https://doi.org/10.1016/j.apsusc.2014.11.135
Kleber C et al (2008) Initial oxidation of silver surfaces by S2− and S4+ species. Corros Sci 50:1112–1121. https://doi.org/10.1016/j.corsci.2007.12.001
Storme P, Schalm O, Wiesinger R (2015) The sulfidation process of sterling silver in different corrosive environments: impact of the process on the surface films formed and consequences for the conservation-restoration community. Herit Sci:3–25. https://doi.org/10.1186/s40494-015-0054-1
Leygraf C, Graedel T (2000) Atmospheric corrosion. Electrochemical society series. Wiley Interscience, New York, p 326
Rogers G de W (1975), Particular aspects of silver tarnishing. In: Proceedings of 1975 annual meeting of ICC-CG. Bulletin 1, vol. 1, Ottawa 1976, pp 5–8
Martina I, Wiesinger R, Schreiner M (2013) Micro-Raman investigation of early stage silver corrosion products occurring in Sulphur containing atmospheres. J Raman Spectrosc 44:770–775. https://doi.org/10.1002/jrs.4276
Franey JP, Kammlot GW, Graedel TE (1985) The corrosion of silver by atmospheric sulfurous gases. Corros Sci 25(2):133–143. https://doi.org/10.1016/0010-938X(85)90104-0
Graedel TE et al (1985) On the mechanism of silver and copper sulfidation by atmospheric H2S and OCS. Corros Sci 25(12):1163–1180. https://doi.org/10.1016/0010-938X(85)90060-5
Vassiliou P, Gouda V (2013) Silver: its past, its present and ensuring its future. In: Dillmann P, Watkinson D, Angelini E, Adriens A (eds) Corrosion and conservation of cultural heritage metallic artefacts. Woodhead Publishing for European Federation of Corrosion, Oxford, Cambridge, Philadelphia, New Delhi, pp 213–235
Knotkova D et al (2007) Indoor corrosivity in the National Museum Depositary, Prague, the Czech Republic. In: Argyropoulos V, Hein A, Harith MA (eds) Strategies for saving our cultural heritage. Papers presented at the international conference on conservation strategies for saving indoor metallic collection, technological educational Institute of Athens, pp 64–71
Hart L et al (2016) Monitoring the impact of the indoor air quality on silver cultural heritage objects using passive and continuous corrosion rate assessments. Appl Phys A. https://doi.org/10.1007/s00339-016-0456-2
Santis FD, Di Palo V, Allegrini I (1992) Determination of some atmospheric pollutants inside a museum: relationship with the concentration outside. Sci Total Environ 127:211–223. https://doi.org/10.1016/0048-9697(92)90504-L
Favez O et al (2008) Seasonality of major aerosol species and their transformations in Cairo megacity. Atmos Environ 42:1553–1516. https://doi.org/10.1016/j.atmosenv.2007.10.081
Bouquet S, Bodin C, Fiaud C (1993) Influence relative des composes soufres et chlores sur le ternissement de l’argent en milieu atmosphérique. C R Acad Sci 316:459–464
Acknowledgment
The authors would like to thank doctoral candidate Yannis Papantoniou, Mechanical Engineer from the Laboratory of Manufacturing Technology (School of Mechanical Engineering/ National Technical University of Athens) for his assistance with the AFM measurements.
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Gouda, V., Angelini, E., Grassini, S., Parvis, M., Vassiliou, P., Papadopoulou, O. (2018). Silver Corrosion in a Museum Collection Storage Facility: A Preliminary Study. In: Koui, M., Zezza, F., Kouis, D. (eds) 10th International Symposium on the Conservation of Monuments in the Mediterranean Basin. MONUBASIN 2017. Springer, Cham. https://doi.org/10.1007/978-3-319-78093-1_31
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