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The Sol-Gel Chemistry of Oxides from Alkoxides

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Introduction to Sol-Gel Processing

Abstract

This chapter is focused on the chemical transformations of alkoxides or precursors derived from alkoxides in solution, to synthesize oxide sol-gel materials. It follows a pattern similar to Chap. 2. After addressing the structure of alkoxides, their hydrolysis and condensation reactions are next described, followed by a short review of the behavior of a few simple oxides made from these precursors: boron, silicon, aluminum, zirconium, and titanium oxides. The chemistry of silicon alkoxide is a special case, as it has seen a tremendous expansion during the last 20 years. The applications of glycol complexed silanes and polyhedral oligomeric silsesquioxanes (POSS) are summarized in special paragraphs. However, the functionalization of organo-alkoxysilane is largely connected to the very rich domain of hybrid organic-inorganic materials, and hence many of its aspects are treated separately in Chap. 10. The mixing of alkoxides with other alkoxides or precursors comes in a further section. Very interesting new sol-gel procedures, such as non-hydrolytic routes in water-free solvents, appear in the last section of this chapter along with their short review.

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References

  • R. Aelion, A. Loebel, F. Elrich, J. Am. Chem. Soc. 72, 5705–5712 (1950)

    Article  CAS  Google Scholar 

  • P.A. Agaskar, Inorg. Chem. 30, 2707–2708 (1991)

    Article  CAS  Google Scholar 

  • P.A. Agaskar, W.G. Klemperer, Inorg. Chim. Acta 229, 355–364 (1995)

    Article  CAS  Google Scholar 

  • C. Allié, R. Pirard, A.J. Lecloux, J.P. Pirard, J. Non-Cryst. Solids 246, 216–228 (1999)

    Article  Google Scholar 

  • M. Andrianainarivelo, R. Corriu, D. Leclercq, P.H. Mutin, A. Vioux, J. Mater. Chem. 6, 1665–1671 (1996)

    Article  CAS  Google Scholar 

  • K.A. Andrianov, B.A. Izmailov, Zh. Obshch. Khim. 46, 329–335 (1976)

    CAS  Google Scholar 

  • P. Arnal, R.J.P. Corriu, D. Leclercq, P.H. Mutin, A. Vioux, J. Mater. Chem. 6, 1925–1932 (1996)

    Article  CAS  Google Scholar 

  • T. Assih, A. Ayral, M. Abenoza, J. Phalippou, J. Mater. Sci. 23, 3326–3331 (1988)

    Article  CAS  Google Scholar 

  • R.H. Baney, Some Organometallic Routes to Ceramics, in Ultrastructure Processing of Ceramics, Glasses and Composites, ed. by L. L. Hench, D. R. Ulrich, (John Wiley, New York, 1984), pp. 245–255

    Google Scholar 

  • D. Banerjea, J. Indian Chem. Soc. LI, 90–94 (1974)

    Google Scholar 

  • E.A. Barringer, H.K. Bowen, Comm. Am. Soc., C199–C201 (1982)

    Google Scholar 

  • S. Baskaran, L. Song, J. Liu, Y.L. Chen, G.L. Graff, J. Am. Ceram. Soc. 81, 401–408 (1998)

    Article  CAS  Google Scholar 

  • A.R. Bassindale, I.A. MacKinnon, M.G. Maesano, P.G. Taylor, Chem. Commun., 1382–1383 (2003)

    Google Scholar 

  • A.F. Bedilo, K.J. Klabunde, J. Nano Mater. 8, 119–135 (1997)

    Article  CAS  Google Scholar 

  • M. Bent, Y. Gun’ko, J. Organomet. Chem. 690, 463–468 (2005)

    Article  CAS  Google Scholar 

  • S. Bi, C. Wang, Q. Cao, C. Zhang, Coord. Chem. Rev. 248, 441–455 (2004)

    Article  CAS  Google Scholar 

  • J.B. Blum, S.R. Gurkovich, J. Mater. Sci. 20, 4479–4483 (1985)

    Article  CAS  Google Scholar 

  • C. Bonhomme, M. Henry, J. Livage, J. Non-Cryst. Solids 159, 22–30 (1993)

    Article  CAS  Google Scholar 

  • J.M. Boulton, J. Thompson, H.H. Fox, I. Gorodisher, G. Teowee, P.D. Calvert, D.R. Uhlmann, Mater. Res. Soc. Symp. Proc. 180, 987–994 (1990)

    Article  CAS  Google Scholar 

  • L. Bourget, R.J.P. Corriu, D. Leclercq, P.H. Mutin, A. Vioux, J. Non-Cryst. Solids 242, 81–91 (1998a)

    Article  CAS  Google Scholar 

  • L. Bourget, P.H. Mutin, A. Vioux, J.M. Frances, J. Polym. Sci. A 36, 2415–2425 (1998b)

    Article  CAS  Google Scholar 

  • L. Bourget, D. Leclercq, A. Vioux, J. Sol-Gel Sci. Technol. 14, 137–147 (1999)

    Article  CAS  Google Scholar 

  • T. Boyd, J. Polym. Sci. 7, 591–602 (1951)

    Article  CAS  Google Scholar 

  • D.C. Bradley, D.G. Carter, Can. J. Chem. 39, 1434–1443 (1961)

    Article  CAS  Google Scholar 

  • D.C. Bradley, W. Wardlaw, J Chem. Soc. Lond., 280–285 (1951)

    Google Scholar 

  • D.C. Bradley, R.C. Mehotra, D.P. Gaur, Metal Alkoxides (Academic Press, London, 1978)

    Google Scholar 

  • D.C. Bradley, R.C. Mehrotra, I.P. Rothwell, A. Singh, Alkoxo and Aryloxo Derivatives of Metals (Academic Press, New York, 2001)

    Google Scholar 

  • C.J. Brinker, J. Non-Cryst. Solids 99, 359–370 (1988)

    Article  Google Scholar 

  • C.J. Brinker, S.P. Mukherjee, Thin Solid Films 77, 141–148 (1981)

    Article  CAS  Google Scholar 

  • C.J. Brinker, K.D. Keefer, D.W. Schaefer, C.S. Ashley, J. Non-Cryst. Solids 48, 47–64 (1982)

    Article  CAS  Google Scholar 

  • C.J. Brinker, K.J. Ward, K.D. Keefer, E. Holupta, P.J. Bray, Mater. Res. Soc. Symp. Proc. 73, 57–68 (1986a)

    Article  CAS  Google Scholar 

  • C.J. Brinker, B.C. Bunker, D.R. Tallant, K.J. Ward, J. Chim. Phys. 83(83), 851–858 (1986b)

    Article  CAS  Google Scholar 

  • C.J. Brinker, G.W. Scherer, Sol-Gel Science—The Physics and Chemistry of Sol- Gel Processing (Academic Press, New York, 1990)

    Google Scholar 

  • J.F. Brown, The polycondensation of phenylsilanetriol. J. Am. Chem. Soc. 87, 4317–4324 (1965)

    Article  CAS  Google Scholar 

  • L.M. Brown, K.S. Mazdiyasni, J. Am. Ceram. Soc. 55, 541 (1972)

    Article  CAS  Google Scholar 

  • J.F. Brown, L.H. Vogt, J. Am. Chem. Soc. 87, 4313–4317 (1965)

    Article  CAS  Google Scholar 

  • J.F. Brown, L.H. Vogt, P.I. Prescott, J. Am. Chem. Soc. 86, 1120–1125 (1964)

    Article  CAS  Google Scholar 

  • K. Bürglová, A. Noureddine, J. Hodačová, G. Toquer, X. Cattoën, M. Wong Chi Man, Chem. Eur. J. 20, 10371–10382 (2014). https://doi.org/10.1002/chem.201403136

    Article  CAS  Google Scholar 

  • J. Caruso, M.J. Hampden-Smith, J. Sol-Gel Sci. Technol. 8, 35–39 (1997)

    CAS  Google Scholar 

  • X. Cattoën, A. Noureddine, J. Croissant, N. Moitra, K. Burglová, J. Hodačová, O. De los Cobos, M. Lejeune, F. Rossignol, D. Toulemon, S. Bégin-Colin, B. Pichon, L. Raehm, J.-O. Durand, M. Wong Chi Man, J. Sol-Gel Sci. Technol. 70, 245–253 (2014)

    Google Scholar 

  • Y. Chen, X. Ai, C. Huang, Mater. Sci. Eng. B77, 221–228 (2000)

    Article  CAS  Google Scholar 

  • T. Chevallier, T. Woignier, J. Toucet, E. Blanchart, P. Dieudonne, J. Sol-Gel Sci. Technol. 48, 231–238 (2008)

    Article  CAS  Google Scholar 

  • H.M. Cho, H. Weissman, S.R. Wilson, J.S. Moore, J. Am. Chem. Soc. 128, 14742–14743 (2006)

    Article  CAS  Google Scholar 

  • Y. Chujo, E. Ihara, S. Kure, K. Suzuki, T. Saegusa, Makromol. Chem. Macromol. Symp. 42/43, 303–312 (1991)

    Article  CAS  Google Scholar 

  • P. Colomban, L’industrie Ceramique 697, 531–535 (1976)

    CAS  Google Scholar 

  • P. Colomban, L’industrie Ceramique 792–793, 186–196 (1985)

    Google Scholar 

  • B.K. Coltrain, C.J.T. Landry, J.M. O’Reilly, A.M. Chamberlain, G.A. Rakes, J.S.S. Sedita, L.W. Kels, M.R. Landry, V.K. Long, Chem. Mater. 5, 1445–1455 (1993)

    Article  CAS  Google Scholar 

  • D.B. Cordes, P.D. Lickiss, F. Rataboul, Chem. Rev. 110, 2081–2173 (2010)

    Article  CAS  Google Scholar 

  • R.J.P. Corriu, C. Guerin, J.E.E. Moreau, Top. Stereochem. 15, 43–198 (1984)

    CAS  Google Scholar 

  • R.J.P. Corriu, D. Leclercq, A. Vioux, M. Pauthe, J. Phalippou, in Ultrastructure Processing of Advanced Ceramics, ed. by J. D. Mackenzie, D. R. Ulrich, (Wiley, New York, 1988), p. 113

    Google Scholar 

  • R.J.P. Corriu, J.J.E. Moreau, P. Thepot, M. Wong Chi Man, Chem. Mater. 4, 1217–1224 (1992a)

    Article  CAS  Google Scholar 

  • R.J.P. Corriu, D. Leclercq, P. Lefevre, P.H. Mutin, A. Vioux, Chem. Mater. 4, 961–963 (1992b)

    Article  CAS  Google Scholar 

  • H.M. Crocker, R. Herold, M. Crocker, A. Guy Orpen, Chem. Commun., 2411–2412 (1997)

    Google Scholar 

  • J. Croissant, M. Maynadier, O. Mongin, V. Hugues, M. Blanchard-Desce, A. Chaix, X. Cattoën, M. Wong Chi Man, A. Gallud, M. Gary-Bobo, M. Garcia, L. Raehm, J.-O. Durand, Small 11, 295–299 (2015)

    Article  CAS  Google Scholar 

  • S. Dai, Y.H. Ju, H.J. Gao, J.S. Lin, S.J. Pennycook, C.E. Barnes, Chem. Commun., 243–244 (2000)

    Google Scholar 

  • V.W. Day, T.A. Eberspacher, W.G. Klemperer, C.W. Park, J. Am. Chem. Soc. 113, 8190 (1991)

    Article  CAS  Google Scholar 

  • N. de la Rosa-Fox, L. Esquivias, A.F. Craievich, J. Zarzycki, J. Non-Cryst. Solids 121, 211–215 (1990)

    Article  Google Scholar 

  • N. de la Rosa-Fox, V. Morales-Florez, M. Pinero, L. Esquivias, Key Eng. Mater. 391, 45–78 (2009)

    Article  Google Scholar 

  • J.C. Debsikdar, J. Mater. Sci. 20, 4454–4458 (1985)

    Article  CAS  Google Scholar 

  • J.C. Debsikdar, J. Non-Cryst. Solids 86, 231–240 (1986)

    Article  CAS  Google Scholar 

  • Z. Deng, J. Wang, J. Wei, J. Shen, B. Zhou, L. Chen, J. Sol-Gel Sci. Technol. 19, 677–680 (2000)

    Article  CAS  Google Scholar 

  • P. Dieudonne, A. Hafidi Alaoui, P. Delord, J. Phalippou, J. Non-Cryst. Solids 262, 155–161 (2000)

    Article  CAS  Google Scholar 

  • H. Dislich, Angew. Chem. Int. Ed. Engl. 10, 363–370 (1971)

    Article  CAS  Google Scholar 

  • H. Dislich, J. Non-Cryst. Solids 57, 371–388 (1983)

    Article  CAS  Google Scholar 

  • M. Ebelmen, Ann. Chim. Phys. 16, 129–166 (1846)

    Google Scholar 

  • M. Ebelmen, C. R. Acad. Sci. Paris 25, 854–856 (1847)

    Google Scholar 

  • J.O. Edwards, V. Ross, J. Inorg. Nucl. Chem. 15(15), 329–337 (1960)

    Article  CAS  Google Scholar 

  • M.A. Einarsrud, E. Nilsen, A. Rigacci, G.M. Pajonk, S. Buathier, D. Valette, M. Durant, P. Cheva-lier, P. Nitz, F. Ehrburger-Dolle, J. Non-Cryst. Solids 285, 1–7 (2001)

    Article  CAS  Google Scholar 

  • H. El Rassy, P. Buisson, B. Bouali, A. Perrard, A.C. Pierre, Langmuir 19, 358–363 (2003)

    Article  CAS  Google Scholar 

  • R.J. Errington, Advanced Practical Inorganic and Metal Organic Chemistry (Blackie Acad, London, 1997)

    Google Scholar 

  • L. Esquivias, M. Piiiero, V. Morales-Fierez, N. de la Rosa-Fox, Chapter 20: Aerogels Synthesis by Sono-Catalysis: Sonogels, in Aerogels Handbook, Advanced in Sol-Gel Derived Materials and Technology, ed. by M. A. Aegerter, N. Leventis, M. M. Koebel, (Springer Science+Business Media, New York, 2011), pp. 419–445

    Google Scholar 

  • F.J. Feher, J. Am. Chem. Soc. 108, 3850–3852 (1986)

    Article  CAS  Google Scholar 

  • F.J. Feher, T.A. Budzichowski, J. Organomet. Chem. 373, 153–163 (1989)

    Article  CAS  Google Scholar 

  • F.J. Feher, D. Soulivong, F. Nguyen, Chem. Commun. (Camb.), 1279–1280 (1998)

    Google Scholar 

  • F.J. Feher, R. Terroba, J.W. Ziller, Chem. Commun. (Camb.), 2153–2154 (1999)

    Google Scholar 

  • D. Frąckowiak, P. Żak, G. Spólnik, M. Pyziak, B. Marciniec, Organometallics 34, 3950–3958 (2015)

    Article  CAS  Google Scholar 

  • G. Garnweitner, M. Antonietti, M. Niederberger, Chem. Commun., 397–399 (2005)

    Google Scholar 

  • G. Garnweitner, N. Tsedev, H. Dierke, M. Niederberger, Eur. J. Inorg. Chem. 2008, 890–895 (2008)

    Article  CAS  Google Scholar 

  • A.E. Gash, T.M. Tillotson, J.H. Satcher Jr., L.W. Hrubesh, R.L. Simpson, J. Non-Cryst. Solids 285, 22–28 (2001)

    Article  CAS  Google Scholar 

  • V.C. Gibson, A.J. Graham, D.L. Ormsby, B.P. Ward, A.J.P. White, D.J. Williams, J. Chem. Soc. Dalton Trans., 2597 (2002)

    Google Scholar 

  • R.H. Glaser, G.L. Wilkes, Polym. Bull. 19, 51–57 (1988)

    Article  CAS  Google Scholar 

  • R.G. Gossink, H.A.M. Coenen, A.R.C. Engelfriet, M.L. Verheijke, J.C. Verplanke, Mater. Res. Bull. 10(10), 35–40 (1975)

    Article  CAS  Google Scholar 

  • G.H. Haertling, C.E. Land, J. Am. Ceram. Soc. 54, 1–11 (1971)

    Article  CAS  Google Scholar 

  • G.H. Haertling, C.E. Land, Ferroelectric 3, 269–280 (1972)

    Article  CAS  Google Scholar 

  • A. Hafidi Alaoui, T. Woignier, J. Phalippou, G.W. Scherer, J. Sol-Gel Sci. Technol. 13, 365–369 (1998)

    Article  Google Scholar 

  • L.B. Hammouda, I. Mejri, M.K. Younes, A. Ghorbel, Chapter 6: ZrO2 Aerogels, in Aerogels Handbook, Advanced in Sol-Gel Derived Materials and Technology, ed. by M. A. Aegerter, N. Leventis, M. M. Koebel, (Springer Science+Business Media, New York, 2011), pp. 127–143

    Google Scholar 

  • J.H. Harreld, T. Ebina, N. Tsubo, G. Stucky, J. Non-Cryst. Solids 298, 241–251 (2002)

    Article  CAS  Google Scholar 

  • T. Hayashi, H. Saito, J. Mater. Sci. 15, 1971–1977 (1980)

    Article  CAS  Google Scholar 

  • G. Helgesson, S. Jagner, O. Poncelet, L.G. Hubert-Pfalzgraf, Polyhedron 10, 1559 (1991)

    Article  CAS  Google Scholar 

  • K. Higuchi, S. Naka, S.S. Hirano, Adv. Ceram. Mater. 1, 104–107 (1986)

    CAS  Google Scholar 

  • H. Hirashima, Chapter 7: Preparation of TiO2 Aerogels-Like Materials Under Ambient Pressure, in Aerogels Handbook, Advanced in Sol-Gel Derived Materials and Technology, ed. by M. A. Aegerter, N. Leventis, M. M. Koebel, (Springer Science+Business Media, New York, 2011), pp. 145–153

    Google Scholar 

  • D. Hoebbel, L. Pitsch, D. Heidemann, H. Jancke, W. Hiller, Z. Anorg. Allg. Chem. 583, 133–144 (1990)

    Article  CAS  Google Scholar 

  • D.M. Hoffman, D. Lappas, D.A. Wierda, J. Am. Chem. Soc. 111, 1531 (1989)

    Article  CAS  Google Scholar 

  • L.G. Hubert-Pfalzgraf, Polyhedron 13, 1181 (1994)

    Article  CAS  Google Scholar 

  • L.G. Hubert-Pfalzgraf, Coordination Chem. Rev. 6, 102–120 (2003)

    Google Scholar 

  • M. Iwasaki, A. Yasumori, S. Shibata, M. Yamane, J. Sol-Gel Sci. Technol. 2, 387–391 (1994)

    Article  CAS  Google Scholar 

  • M. Jansen, E. Guenther, Water- and Hydroxyl Group-Free Gels and Xerogels Based on a Net-work of Oxygen-Bridged Metal and/or Semimetal Atoms, and Their Manufacture and Use, Eur. Pat. Appl. (Cerdec Aktiengesellschaft Keramische Farben, Germany) (1996), p. 11

    Google Scholar 

  • A.R. Jennings, S.T. Iacono, J.M. Mabry, Chapter 4.9: Polyhedral Silsesquioxanes, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, New York, 2016)

    Google Scholar 

  • L. Jin, D.R. Tolentino, M. Melaimi, G. Bertrand, Sci. Adv., 1(5) (2015). https://doi.org/10.1126/sciadv.1500304

    Article  CAS  Google Scholar 

  • C.E. Johnson, D.K. Hickey, D.C. Marris, Mater. Res. Soc. Symp. 73, 785–789 (1986)

    Article  CAS  Google Scholar 

  • A.C. Jones, J. Mater. Chem., 2576 (2002)

    Google Scholar 

  • M. Kakihana, M. Tada, M. Shiro, V. Petrykin, M. Osada, Y. Nakamura, Inorg. Chem. 40, 891–894 (2001)

    Article  CAS  Google Scholar 

  • K. Kamiya, M. Ohya, T. Yoko, J. Non-Cryst. Solids 83, 208–222 (1986)

    Article  CAS  Google Scholar 

  • B. Karkamar, D. Ganguli, Trans. Indian Ceram. Soc. 44, 10–14 (1985)

    Article  Google Scholar 

  • A. Karout, A.C. Pierre, J. Non-Cryst. Solids 353, 2900–2909 (2007)

    Article  CAS  Google Scholar 

  • A. Karout, A.C. Pierre, J. Sol-Gel Sci. Technol. 49, 364–372 (2009a)

    Article  CAS  Google Scholar 

  • A. Karout, A.C. Pierre, Catal. Commun. 10(10), 349–351 (2009b)

    Google Scholar 

  • K.D. Keefer, Mater. Res. Soc. Symp. Proc. 32, 15–24 (1984)

    Article  CAS  Google Scholar 

  • E. Kemnitz, J. Noack, Dalton Trans. 44, 19411–19431 (2015)

    Article  CAS  Google Scholar 

  • V.G. Kessler, Chem. Commun., 1213 (2003)

    Google Scholar 

  • V.G. Kessler, Chapter 6-17: The Synthesis and Solution Stability of Alkoxide Precursors, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, New York, 2016)

    Google Scholar 

  • V.G. Kessler, G.A. Seisenbaeva, Inorg. Chem. Commun. 3, 203 (2000)

    Article  CAS  Google Scholar 

  • V.G. Kessler, A.V. Shevelkov, L. Kloo, MoO(OiPr)4 decomposition pathways on aging. Polyhedron 17, 965 (1998a)

    Article  CAS  Google Scholar 

  • V.G. Kessler, A.N. Panov, N.Y. Turova, Z.A. Starikova, A.I. Yanovsky, F.M. Dolgushin, A.P. Pisarevsky, Y.T. Struchkov, Dalton Trans., 21 (1998b)

    Google Scholar 

  • T. Kishimoto, H. Kozuka, J. Mater. Res. 18, 466–474 (2003)

    Article  CAS  Google Scholar 

  • L.C. Klein, Annu. Rev. Mater. Sci. 15, 227–248 (1985)

    Article  CAS  Google Scholar 

  • L.C. Klein, Sol–Gel Optics: Processing and Applications (Springer, Berlin, 1994)

    Book  Google Scholar 

  • M. Kobayashi, H. Kato, M. Kakihana, Chapter 7.3: Water-Dispersed Silicates and Water-Soluble Phosphates, and Their Use in Sol–Gel Synthesis of Silicate- and Phosphate-Based Materials, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, New York, 2016)

    Google Scholar 

  • S. Kohjiya, K. Ochial, S. Yamashita, J. Non-Cryst. Solids 119, 132–135 (1990)

    Article  CAS  Google Scholar 

  • H.C. Kolb, M.G. Finn, K.B. Sharpless, Angew. Chem. Int. Ed. 40, 2004–2021 (2001)

    Article  CAS  Google Scholar 

  • S. Komarneni, R. Roy, E. Breval, J. Am. Ceram. Soc. 68, C41–C42 (1985)

    CAS  Google Scholar 

  • W.L. Konijnendijk, M. von Duuren, H. Groenendijk, Verres Refractaires 27, 11–17 (1973)

    CAS  Google Scholar 

  • R. König, G. Scholz, N.H. Thong, E. Kemnitz, Chem. Mater. 19, 2229–2237 (2007)

    Article  CAS  Google Scholar 

  • H. Kozuka, T. Kishimoto, Chem. Lett. 11, 1150–1151 (2001)

    Article  Google Scholar 

  • J. Kramer, R.K. Prud’homme, P. Wiltzius, J. Colloid Interface Sci. 118, 294–296 (1987)

    Article  CAS  Google Scholar 

  • B. Lee, J. Zhang, Thin Solid Films 388, 107–113 (2001)

    Article  CAS  Google Scholar 

  • P.D. Lickiss, F. Rataboul, Fully Condensed Polyhedral Oligosilsesquioxanes (POSS): From Synthesis to Application, in Advances in Organometallic Chemistry, ed. by F. H. Anthony, J. F. Mark, (Academic, Oxford, 2008), pp. 1–116

    Google Scholar 

  • X. Liu, Y. Wang, J. Non-Cryst. Solids 80, 564–570 (1986)

    Article  CAS  Google Scholar 

  • J. Livage, M. Henry, C. Sanchez, Prog. Solid State Chem. 18, 259–341 (1998)

    Article  Google Scholar 

  • J. Livage, M. Henry, J.P. Jolivet, C. Sanchez, Mater. Res. Soc. Bull., 18 (1990)

    Google Scholar 

  • A.B. Lowe, Polym. Chem. 1, 17–36 (2010)

    Article  CAS  Google Scholar 

  • D.A. Loy, Chapter 3-18: Mesoporous Polysilsesquioxanes: Preparation, Properties, and Applications, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, New York, 2016)

    Google Scholar 

  • F. Mahtab, J.W.Y. Lam, Y. Yu, J.Z. Liu, W.Z. Yuan, P. Lu, B.Z. Tang, Small 7, 1448–1455 (2011)

    Article  CAS  Google Scholar 

  • E. Matijevic, in Ultrastructure Processing of Ceramics, Classes, and Composites, ed. by L. L. Hench, D. R. Ulrich, (Wiley, New York, 1984), p. 334

    Google Scholar 

  • S. Matsuda, A. Kato, Appl. Catal. 8, 149–165 (1983)

    Article  CAS  Google Scholar 

  • C. Mauriello-Jimenez, J. Croissant, M. Maynadier, X. Cattoën, M. Wong Chi Man, J. Vergnaud, V. Chaleix, V. Sol, M. Garcia, M. Gary-Bobo, L. Raehm, J.-O. Durand, J. Mater. Chem. B 3, 3681–3684 (2015)

    Article  CAS  Google Scholar 

  • K.S. Mazdiyasni, Ceram. Int. 8, 42–56 (1982)

    Article  CAS  Google Scholar 

  • K.S. Mazdiyasni, L.M. Brown, J. Am. Ceram. Soc. 11, 539–543 (1971)

    Article  Google Scholar 

  • K.S. Mazdiyasni, L.M. Brown, J. Am. Ceram. Soc. 55, 548–552 (1972)

    Article  CAS  Google Scholar 

  • K.S. Mazdiyasni, C.T. Lynch, J.S. Smith II, J. Am. Ceram. Soc. 48, 372–375 (1965)

    Article  CAS  Google Scholar 

  • K.S. Mazdiyasni, C.T. Lynch, J.S. Smith II, J. Am. Ceram. Soc. 50, 532–537 (1967)

    Article  CAS  Google Scholar 

  • R.C. Mehotra, R. Bohra, D.P. Gaur, Metal β-Diketonates and Allied Derivatives (Academic Press, London, 1978)

    Google Scholar 

  • M. Meldal, C.W. Tornøe, Chem. Rev. 108, 2952–3015 (2008)

    Article  CAS  Google Scholar 

  • P. Mezza, J. Phalippou, R. Sempere, J. Non-Cryst. Solids 243, 75–79 (1967)

    Article  Google Scholar 

  • M.V. Migliorini, R.K. Donato, M.A. Benvegnu, R.S. Gonçalves, H.S. Schrekker, J. Sol-Gel Sci. Technol. 48, 272–276 (2008)

    Article  CAS  Google Scholar 

  • H. Möckel, M. Giersig, F. Willig, J. Mater. Chem. 9, 3051–3056 (1999)

    Article  Google Scholar 

  • N. Moitra, J.J.E. Moreau, X. Cattoën, M. Wong Chi Man, Chem. Commun. 46, 8416–8418 (2010)

    Article  CAS  Google Scholar 

  • G. Monchâtre, L’Actualite Chimique, 11–21 (1984)

    Google Scholar 

  • M. Moner-Girona, A. Roig, E. Molins, J. Sol-Gel Sci. Technol. 26, 645–649 (2003)

    Article  CAS  Google Scholar 

  • A. Morikawa, Y. Iyoku, M. Kakimoto, Y. Imai, J. Mater. Chem. 2, 679–690 (1992)

    Article  CAS  Google Scholar 

  • B. Morosin, P.S. Peercy, Chem. Phys. Lett. 40, 263–266 (1976)

    Article  CAS  Google Scholar 

  • A. Mosset, J. Galy, C. R. Acad. Sci. II 307, 1747 (1988)

    CAS  Google Scholar 

  • T.H. Mourey, S.M. Miller, J.A. Wesson, T.E. Long, L.W. Kelts, Macromolecules 25, 45–52 (1992)

    Article  CAS  Google Scholar 

  • R.L. Mozzi, B.E. Warren, J. Appl. Crystallogr. 2, 164–172 (1969)

    Article  CAS  Google Scholar 

  • J. Mühlebach, K. Müller, G. Schwarzenbach, Inorg. Chem. 9, 2381–2390 (1970)

    Article  Google Scholar 

  • S.P. Mukherjee, J. Non-Cryst. Solids 42, 477–488 (1980)

    Article  CAS  Google Scholar 

  • S.P. Mukherjee, J. Zarzycki, J.P. Traverse, J. Mater. Sci. 11, 341–355 (1976)

    Article  CAS  Google Scholar 

  • P.H. Mutin, A. Vioux, Chem. Mater. 21, 582–596 (2009)

    Article  CAS  Google Scholar 

  • M. Nabavi, C. Sanchez, J. Livage, Eur. J. Solid State Inorg. Chem. 28, 1173 (1991)

    CAS  Google Scholar 

  • K. Nakanishi, H. Minakuchi, N. Soga, N. Tanaka, J. Sol-Gel Sci. Technol. 13, 163–169 (1998)

    Article  CAS  Google Scholar 

  • G.A. Nicolaon, S.J. Teichner, Bull. Soc. Chim. Fr., 1906–1911 (1968)

    Google Scholar 

  • M. Niederberger, G. Garnweitner, Chem. Eur. J. 12, 7282–7302 (2006)

    Article  CAS  Google Scholar 

  • M. Niederberger, M.H. Bartl, G.D. Stucky, J. Am. Chem. Soc. 124, 13642–13643 (2002)

    Article  CAS  Google Scholar 

  • M. Nogami, Y. Moriya, J. Non-Cryst. Solids 48, 359–366 (1982)

    Article  CAS  Google Scholar 

  • T. Ohya, T. Ban, Y. Ohya, Y. Takahashi, Ceram. Trans. 112, 47–52 (2001)

    CAS  Google Scholar 

  • T. Ohya, A. Nakayama, T. Ban, Y. Ohya, Y. Takahashi, Chem. Mater. 14, 3082–3089 (2002)

    Article  CAS  Google Scholar 

  • T. Ohya, A. Nakayama, Y. Shibata, T. Ban, Y. Ohya, Y. Takahashi, J. Sol-Gel Sci. Technol. 26, 799–802 (2003)

    Article  CAS  Google Scholar 

  • K. Olsson, C. Axen, Ark. Kemi. 22, 237–244 (1964)

    CAS  Google Scholar 

  • S. Ono, S. Hirano, J. Am. Ceram. Soc. 80, 2533–2540 (1997)

    Article  CAS  Google Scholar 

  • S. Ono, T. Takeo, S. Hirano, J. Am. Ceram. Soc. 9, 1343–1350 (1996)

    Article  Google Scholar 

  • Y. Paoting, L. Hsiaoming, W. Yuguang, J. Non-Cryst. Solids 52, 511–522 (1982)

    Article  Google Scholar 

  • C.S. Parkhurst, W.F. Doyle, L.A. Silverman, S. Singh, M.P. Andersen, D. McClug, G.E. Wnek, D.R. Uhlmann, Mater. Res. Soc. Symp. Proc. 73, 769–773 (1986)

    Article  CAS  Google Scholar 

  • B.P. Partlow, B.E. Yoldas, J. Non-Cryst. Solids 46, 153–161 (1981)

    Article  CAS  Google Scholar 

  • A. Parvathy Rao, G.M. Pajonk, A. Venkateswara Rao, J. Mater. Sci. 40, 3481–3489 (2005)

    Article  CAS  Google Scholar 

  • L. Pauling, The Nature of Chemical Bonds, 3rd edn. (Cornell University Press, USA, 1960)

    Google Scholar 

  • L. Pei, W.D. Xiang, X.L. Zhao, X.J. Liang, X.Y. Yang, H.T. Liu, Z.P. Chen, C.P. Xie, X. Ma, C.L. Zhang, L. Ma, J.L. Zhao, Mater. Res. Bull. 59, 154–161 (2014)

    Article  CAS  Google Scholar 

  • P.F.S. Pereira, M.G. Matos, C.M.A. Ferreira, E.H. De Faria, P.S. Calefi, L.A. Rocha, K.J. Ciuffi, E.J. Nassar, J. Lumin. 146, 394–397 (2014)

    Article  CAS  Google Scholar 

  • P.P. Phule, S. Raghavan, S.H. Risbud, J. Am. Ceram. Soc. 70, C108–C109 (1987)

    Article  Google Scholar 

  • A.C. Pierre, D.R. Uhlmann, Mater. Res. Soc. Symp 32, 119–124 (1984)

    Article  CAS  Google Scholar 

  • A.C. Pierre, R. Begag, G. Pajonk, J. Mater. Sci. 34, 4937–4944 (1999)

    Article  CAS  Google Scholar 

  • N. Pinna, G. Garnweitner, M. Antonietti, M. Niederberger, Adv. Mater. 16, 2196–2200 (2004)

    Article  CAS  Google Scholar 

  • E.R. Pohl, F.D. Osterholtz, in Molecular Characterization of Composite Interfaces, ed. by H. Ishida, G. Kumar, (Plenum, New York, 1985), p. 157

    Google Scholar 

  • P.N. Prasad, Quantum-Confined Materials, in Nanophotonics, ed. by P. N. Prasad, (Wiley, Hoboken, 2004), pp. 79–127

    Chapter  Google Scholar 

  • M. Prassas, J. Phalippou, L.L. Hench, J. Zarzycki, J. Non-Cryst. Solids 48, 79–95 (1982)

    Article  CAS  Google Scholar 

  • G. Reichenauer, J. Manara, H. Weinlaeder, Stud. Surf. Sci. Catal. 160, 25–32 (2007)

    Article  CAS  Google Scholar 

  • E. Rikowski, H.C. Marsmann, Polyhedron 16, 3357–3361 (1997)

    Article  CAS  Google Scholar 

  • J.J. Ritter, R.S. Roth, J.E. Blendell, J. Am. Ceram. Soc. 69, 155–162 (1986)

    Article  CAS  Google Scholar 

  • F.G. Rochow, The Chemistry of Organometallic Compounds (Wiley, New York, 1957)

    Book  Google Scholar 

  • S.A. Rodriguez, L.A. Colon, Anal. Chim. Acta 397, 207–215 (1989)

    Article  Google Scholar 

  • V.V. Rostovtsev, L.G. Green, V.V. Fokin, K.B. Sharpless, Angew. Chem. Int. Ed. 41, 2596–2599 (2002)

    Article  CAS  Google Scholar 

  • R. Roy, J. Am. Ceram. Soc. 52, 344–345 (1969)

    Article  CAS  Google Scholar 

  • S. Sakka, Gel Method for Making Glass, in Treatise on Materials Science and Technology, ed. by M. Tomazawa, R. H. Doremus, vol. 22, (Academic Press, Orlando, FL, 1982), pp. 129–167

    Chapter  Google Scholar 

  • S. Sakka, Handbook of Sol–Gel Science and Technology: Processing, Characterization and Applications (Kluwer Academic Publishers, Dordrecht, 2005)

    Google Scholar 

  • S. Sakka, K. Kamiya, Amorphous Materials Produced from Metal Alcoholates, in Process. Kinet. Prop. Electron. Mag. Ceram. Proc. US- Jpn. Semin. Basic Sci. Ceram, ed. by W. Komatsu, R. M. Fulrath, Y. Oishi, M. Koizumi, S. Somiya, (Springer, Boston, 1976), pp. 135–143

    Google Scholar 

  • C. Sanchez, J. Mater. Chem. 15, 3557–3558 (2005)

    Article  CAS  Google Scholar 

  • C. Sanchez, F. Ribot, New J. Chem. 18, 1007–1047 (1994)

    CAS  Google Scholar 

  • C. Sanchez, M. In, P. Toledano, P. Griesmar, Mater. Res. Soc. Symp. Proc. 271, 669–680 (1992)

    Article  CAS  Google Scholar 

  • A.Y. Sane, Refractory Metal Borides, Carbides and Nitrides, and Composites Containing Them, European Patent 0115745—Eltech Systems Corporation, 15.08 (1984)

    Google Scholar 

  • R. Schmid, A. Mosset, J. Galy, Dalton Trans., 1999 (1991)

    Google Scholar 

  • H. Schmidt, A. Kaiser, Glastech. Ber. 54, 338–342 (1981)

    CAS  Google Scholar 

  • H. Schmidt, H. Scholze, A. Kaiser, J. Non-Cryst. Solids 48, 65–77 (1982)

    Article  CAS  Google Scholar 

  • U. Schubert, E. Arpac, W. Glaubitt, A. Helmerich, C. Chau, Chem. Mater. 3, 291–295 (1992)

    Article  Google Scholar 

  • D.W. Scott, J. Am. Chem. Soc. 68, 356–358 (1946)

    Article  CAS  Google Scholar 

  • K. Shea, D.A. Loy, O. Webster, J. Am. Chem. Soc. 114, 6700–6710 (1992)

    Article  CAS  Google Scholar 

  • S. Shenoi-Perdoor, A. Noureddine, F. Dubois, M. Wong Chi Man, X. Cattoën, Chapter 2-5: Click Functionalization of Sol–Gel Materials, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, New York, 2016)

    Google Scholar 

  • K. Shimizu, H. Imai, H. Hirashima, K. Tsukuma, Thin Solid Films 351, 220–224 (1999)

    Article  CAS  Google Scholar 

  • G.D. Smith, C.N. Gaughlan, J.A. Campbell, Inorg. Chem. 11, 2989 (1972)

    Article  CAS  Google Scholar 

  • V.E. Shklover, Y.T. Struchkov, N.N. Makarova, A.A. Zhdanov, Cryst. Struct. Commun. 9, 1–5 (1980)

    CAS  Google Scholar 

  • D. Skoda, A. Styskalik, Z. Moravec, P. Bezdicka, C.E. Barnes, J. Pinkas, J. Sol-Gel Sci. Technol. 74, 810–822 (2015a)

    Article  CAS  Google Scholar 

  • D. Skoda, A. Styskalik, Z. Moravec, P. Bezdicka, J. Pinkas, J. Mater. Sci. 50, 3371–3382 (2015b)

    Article  CAS  Google Scholar 

  • J.S. Smith II, R.T. Dolloff, K.S. Mazdiyasni, J. Am. Ceram. Soc. 53, 91–95 (1970)

    Article  CAS  Google Scholar 

  • D.A. Soleimani, M.H. Abbasi, J. Mater. Proc. Technol. 199, 10–26 (2008)

    Article  CAS  Google Scholar 

  • G.D. Soraru, N. Dallabona, C. Gervais, F. Babonneau, Chem. Mater. 1, 910–919 (1999)

    Article  Google Scholar 

  • G. Speranza, L. Minati, A. Chiasera, M.G. Ferrari, C. Righini, G. Ischia, J. Phys. Chem. C 113, 4445–4450 (2009)

    Article  CAS  Google Scholar 

  • N. Steunou, F. Ribot, K. Boubekeur, J. Maquet, C. Sanchez, New J. Chem. 23, 1079–1086 (1999)

    Article  CAS  Google Scholar 

  • C. Stocker, A. Baiker, J. Non-Cryst. Solids 223, 165–178 (1998)

    Article  CAS  Google Scholar 

  • W.H. Stockmayer, J. Chem. Phys. 11(11), 45–55 (1943)

    Article  CAS  Google Scholar 

  • A. Styskalik, D. Skoda, J. Pinkas, S. Mathur, J. Sol-Gel Sci. Technol. 63, 463–472 (2012)

    Article  CAS  Google Scholar 

  • D.J. Suh, T.J. Park, J.H. Sonn, J.C. Lim, J. Mater. Sci. Lett. 18, 1473–1475 (1999)

    Article  CAS  Google Scholar 

  • R. Sui, A.S. Rizkalla, P.A. Charpentier, Langmuir 22, 4390–4396 (2006)

    Article  CAS  Google Scholar 

  • G.S. Sur, J.E. Mark, Eur. Polym. J. 21, 1051–1052 (1985)

    Article  CAS  Google Scholar 

  • K.S. Suslick, J.P. Price, Annu. Rev. Mater. Sci. 29, 295–326 (1999)

    Article  CAS  Google Scholar 

  • Y. Suzuki, M. Kakihana, J. Ceram. Soc. Jpn. 117, 330–334 (2009)

    Article  CAS  Google Scholar 

  • C.G. Swain, M. Esteve, R.H. Jones, J. Chem. Soc. 11, 965 (1949)

    Article  Google Scholar 

  • N. Takahashi, Y. Suzuki, M. Kakihana, J. Ceram. Soc. Jpn. 117, 313–331 (2009)

    Article  CAS  Google Scholar 

  • I.M. Thomas, Porous Beads Doped with Small Quantities of Other Oxides, U.S. Patent 3,709,833 (09 Jan 1973)

    Google Scholar 

  • T.M. Tillotson, L.W. Hrubesh, J. Non-Cryst. Solids 145, 44–50 (1992)

    Article  CAS  Google Scholar 

  • N. Tohge, G.S. Moore, J.D. Mackenzie, J. Non-Cryst. Solids 63, 95–103 (1984)

    Article  CAS  Google Scholar 

  • C.W. Tornøe, C. Christensen, M. Meldal, J. Org. Chem. 67, 3057–3064 (2002)

    Article  CAS  Google Scholar 

  • N.Y. Turova, E.P. Turevskaya, V.G. Kessler, M.I. Yanovskaya, The Chemistry of Metal Alkoxides (Kluwer, Boston, 2002)

    Google Scholar 

  • A. Tuteja, W. Choi, M. Ma, J.M. Mabry, S.A. Mazzella, G.C. Rutledge, et al., Science 318, 1618–1622 (2007)

    Article  CAS  Google Scholar 

  • M. Unno, S.B. Alias, H. Saito, H. Matsumoto, Organometallics 15, 2413–2414 (1996)

    Article  CAS  Google Scholar 

  • M. Unno, A. Suto, H. Matsumoto, Pentacyclic Laddersiloxane. J. Am. Chem. Soc. 124, 1574–1575 (2002)

    Article  CAS  Google Scholar 

  • M. Unno, Y. Imai, H. Matsumoto, Silicon Chem. 2, 175–178 (2003)

    Article  CAS  Google Scholar 

  • M. Unno, A. Suto, T. Matsumoto, Russ. Chem. Rev. 82, 289 (2013)

    Article  CAS  Google Scholar 

  • M. Veith, Dalton Trans., 2405 (2002)

    Google Scholar 

  • D.L. Venezky, Inorganic Polymer, in Encyclopedia of Polymer Science and Technology, ed. by J. Wiley, vol. 7, (Interscience, New York, 1967), pp. 664–691

    Google Scholar 

  • A. Venkateswara Rao, D. Haranath, Microporous Mesoporous Mater. 30, 267–273 (1999)

    Article  Google Scholar 

  • A. Venkastewara Rao, S.D. Bhagat, H. Hirashima, G.M. Pajonk, J. Colloid Interface Sci. 300, 279–285 (2006)

    Article  CAS  Google Scholar 

  • M.A. Vicarini, G.A. Nicolaon, S. Teichner, Bull. Soc. Chem. Fr. 2, 1651–1664 (1970)

    Google Scholar 

  • A.C. Vieira Coelho, G.A. Rocha, P. Souza Santos, H. Souza Santos, P.K. Kiyohara, Rev. Mater. 13, 329–341 (2008)

    Google Scholar 

  • A. Vioux, Chem. Mater. 9, 2292–2299 (1997)

    Article  CAS  Google Scholar 

  • A. Vioux, P.H. Mutin, Chapter 4.4: Nonhydrolytic Sol-Gel Technology, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, New York, 2016)

    Google Scholar 

  • D.R. Vollet, L.M. Nunes, D.A. Donatti, R.A. Ibanez, H. Maceti, J. Non-Cryst. Solids 354, 1467–1474 (2008)

    Article  CAS  Google Scholar 

  • K. Wada, S. Sakugawa, M. Inoue, Chem. Commun. 48, 7991–7993 (2012)

    Article  CAS  Google Scholar 

  • P.B. Wagh, R. Begag, G.M. Pajonk, A. Venkateswara Rao, D. Haranath, Mater. Chem. Phys. 57, 214–218 (1999)

    Article  CAS  Google Scholar 

  • E. Wiberg, W. Simmler, Z. Anorg. Allg. Chem. 282, 330–344 (1955)

    Article  CAS  Google Scholar 

  • G.L. Wilkes, B. Orler, H.H. Huang, Polym. Prep. 26(26), 300–301 (1985)

    CAS  Google Scholar 

  • R.R. Wills, R.A. Markle, S.P. Mukherjee, Am. Ceram. Soc. Bull. 62, 904–911 (1983)

    CAS  Google Scholar 

  • T. Woignier, J. Phalippou, J. Zarzycki, J. Non-Cryst. Solids 63, 117–130 (1984)

    Article  CAS  Google Scholar 

  • M. Wong Chi Man, X. Cattoën, N. Moitra, K. Bürglová, J. Hodačová Précurseurs Organo-Silanes Polysilylés Fonctionnalisables. French Patent FR 2992963, WO 2014006222 (2014a)

    Google Scholar 

  • M. Wong Chi Man, X. Cattoën, K. Bürglová, J. Hodačová, Composés Organosilanes Polysi-lylés. French Patet FR 2992964, WO 2014006221 (2014b)

    Google Scholar 

  • B.T. Worrell, J.A. Malik, V.V. Fokin, Science 340(6131), 457–460 (2013)

    Article  CAS  Google Scholar 

  • S. Wuttke, A. Vimont, J.C. Lavalley, M. Daturi, E. Kemnitz, J. Phys. Chem. C 114, 5113–5120 (2010)

    Article  CAS  Google Scholar 

  • W. Xiang, J. Jiasong Zhong, Chapter 1.17: Borosilicates Obtained by Sol–Gel Method, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, New York, 2016)

    Google Scholar 

  • W.D. Xiang, H.J. Zhao, J.S. Zhong, X.Y. Yang, Y.Q. Guo, H.Y. Luo, X.J. Liang, J. Am. Ceram. Soc. 95, 1588–1594 (2012)

    Article  CAS  Google Scholar 

  • W.D. Xiang, H.H. Gao, L. Ma, X. Ma, Y.Y. Huang, L. Pei, X.J. Liang, ACS Appl. Mater. Int. 7, 10162–10168 (2015)

    Article  CAS  Google Scholar 

  • R. Yanagisawa, V. Petrykin, M. Kakihana, J. Jpn. Soc. Powder Metall. 57, 701–705 (2010)

    Article  CAS  Google Scholar 

  • M. Yamane, T. Kojima, J. Non-Cryst. Solids 44, 181–190 (1981)

    Article  CAS  Google Scholar 

  • M. Yamane, S. Inoue, K. Nakazawa, J. Non-Cryst. Solids 48, 153–159 (1982)

    Article  CAS  Google Scholar 

  • G. Yi, M. Sayer, J. Sol-Gel Sci. Technol. 6, 75–82 (1996)

    Article  CAS  Google Scholar 

  • B.E. Yoldas, J. Mater. Sci. 10, 1856–1860 (1975)

    Article  CAS  Google Scholar 

  • B.E. Yoldas, J. Mater. Sci. 12, 1203–1208 (1977)

    Article  CAS  Google Scholar 

  • B.E. Yoldas, J. Mater. Sci. 14, 1843–1849 (1979)

    Article  CAS  Google Scholar 

  • B.E. Yoldas, J. Non-Cryst. Solids 51, 105–121 (1982)

    Article  CAS  Google Scholar 

  • B.E. Yoldas, J. Mater. Sci. 21, 1080–1086 (1986)

    Article  CAS  Google Scholar 

  • K. Yoshizawa, H. Kato, M. Kakihana, J. Mater. Chem. 22, 17272–17277 (2010)

    Article  CAS  Google Scholar 

  • J. Zarzycki, Heterog. Chem. Rev. 1, 243–253 (1994)

    CAS  Google Scholar 

  • J. Zarzycki, M. Prassas, J. Phalippou, J. Mater. Sci. 17, 3371–3379 (1982)

    Article  CAS  Google Scholar 

  • B.J.J. Zelinski, D.R. Uhlmann, J. Phys. Chem. Solids 45, 1069–1090 (1984)

    Article  CAS  Google Scholar 

  • H.X. Zhang, X.D. He, Y. Li, C.Q. Hong, J. Aero Mater. 26, 337–338 (2006)

    CAS  Google Scholar 

  • L. Zhang, G. Garnweitner, I. Djerdj, M. Antonietti, M. Niederberger, Chem. Asian J. 3, 746–752 (2008)

    Article  CAS  Google Scholar 

  • Z. Zhao, D. Chen, X. Jiao, J. Phys. Chem. C Il 1, 18738–18743 (2007)

    Article  CAS  Google Scholar 

  • B. Zhou, J. Shen, W. Yuehua, G. Wu, X. Ni, Mater. Sci. Eng. C 27, 1291–1294 (2007)

    Article  CAS  Google Scholar 

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Pierre, A.C. (2020). The Sol-Gel Chemistry of Oxides from Alkoxides. In: Introduction to Sol-Gel Processing. Springer, Cham. https://doi.org/10.1007/978-3-030-38144-8_3

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