Abstract
The chemistry of ginger: The chapter discusses elaborately the composition of ginger rhizome; extraction, separation, and identification methods; and analytical and isolation methodology, such as liquid column chromatography, thin-layer chromatography, high-performance liquid chromatography, gas chromatography, and other GC (Cas chromatography) methods, such as dynamic headspace, GC artifacts, gas chromatography/mass spectrometry coupling, selected ion monitoring technique, chemical ionization technique, and other miscellaneous methods. Additionally, there is a discussion on oleoresins, such as gingerols, shogaols, and related compounds. Further discussion centers on synthesis and biosynthesis of pungent compounds of ginger rhizomes, including essential oils of ginger, and their physicochemical properties and chemical composition. There is a separate discussion of essential oils from India, China, and other Southeast Asian countries, including Japan. Also, there is a discussion on essential oil in ginger grown in countries such as Africa (Nigeria), Australia, Brazil, Poland, Mauritius, and Tahiti. Additionally, there is a discussion on essential oils in wild ginger. Further discussion centers on characteristic flavor and odor in ginger, chromometrics, synthesis of some authentic samples, and precursors of aroma and flavoring compounds. The last part of the chapter will dwell on properties of ginger, ginger processing like deterpenation, preservation and encapsulation, irradiation effects, and formulations and uses of ginger.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Achinewhu, S. C., Ogbonna, C. C., & Hart, A. D. (1995). Chemical composition of indigenous wild herbs, spices, fruits, nuts and leafy vegetables used as foods. Plant Foods for Human Nutrition, 48(4), 341–348. Dordrecht.
Afzal, M., Al-Hadidi Menon, M., Pesek, J., & Dhami, M. S. (2001). Zinger: An ethno-medical, chemical and pharmacological review. Drug Metabolism and Drug Interactions, 18(3–4), 159–190.
Agarwal, M., Walia, S., Dhingra, S., & Khambay, B. P. S. (2001). Insect growth, inhibition, anti-feedant and antifungal activity of compounds isolated/derived from Zingiber officinale roscoe (ginger) rhizomes. Pest Management Science, 57(3), 289–300.
Ahmad, N., Katiyar, S. K., & Mukhtar, H. (2001). Antioxidants in chemoprevention of the skin cancer. Current Problems in Dermatology, 29, 128–139.
Ahn, B., Lee, D. H., Yeo, S. G., Kany, J. H., Do, J. R., Kim, S. B., et al. (1993). Inhibitory action of natural food components on the formation of carcinogenic nitrosomine. Bulletin of the Korean Fisheries Society, 26, 289–295.
Akhila, A., & Tewari, P. (1984). Chemistry of ginger: A review. Current Research on Medicinal and Aromatic Plants, 6(3), 143–156.
Alencar, J. W., Craveiro, A. A., & Matos, F. J. A. (1984). Kovats indices as a preselection routine in mass spectra library searches of volatiles. Journal of Natural Products, 47(3), 890–892.
Altman, R. D., & Marcussen, K. C. (2001). Effects of a ginger extract on knee pain in patients with osteoarthritis. Arthritis & Rhematology, 44(11), 2531–2538.
Anderson, N. H., & Falcone, M. S. (1969). The identification of sesquiterpene hydrocarbons from GC retention data. Journal of Chromatography, 44, 52–59.
Andrews, I. S., Cadwallader, K. R., Grodner, R. M., & Chung, H. V. (1995). Chemical and microbial quality of irradiated ground ginger. Journal of Food Science, 60(4), 829–832.
Anzaldo, F. E., Coronel Violera, Q., Manalo, J. B., & Nuevo, C. R. (1986). Chemical components of local (Philippines) ginger oil. The National Institute of Science and Technology, 11(3), 11–19.
Arimura, C. T., Finger, F. L., Casali, V., & W.D. (2000). Effect of NAA and BAP on ginger (Zingiber officinale roscoe) sprouting in solid and liquid medium. The Revista Brasileira de Plantas Medicinais, 2(2), 23–26.
Association of Official Analytical Chemists (AOAC). (1984). Methods of analysis (14th ed.). Arlington: Association of Official Analytical Chemists.
Badalyan, A. G., Wilkinson, G. T., & Chun, B. S. (1998). Extraction of Australian ginger root with carbon dioxide and ethanol entrainer. Journal of Supercritical Fluids, 13(1–3), 319–324.
Balladin, D. A., & Headley, O. (1999). Liquid chromatographic analysis of the main pungent prin- ciples of solar dried west Indian ginger (Zingiber officinale roscoe.). Renewable Energy, 18(2), 257–261.
Bartley, J. P. (1995). A new method for the determination of pungent compounds in ginger (Zingiber officinale roscoe). Journal of the Science of Food and Agriculture, 68, 215–222.
Bartley, J. P., & Jacobs, A. L. (2000). Effects of drying on flavor compounds in Australian-grown ginger (Zingiber officinale). Journal of the Science of Food and Agriculture, 80(2), 209–215.
Bednarczyk, A. A. (1974). Identification and evaluation of the flavor-significant components of ginger essential oil. Dissertation Abstracts International B, 35(1), 306.
Bednarczyk, A. A., & Kramer, A. (1975). Identification and evaluation of the flavor-significant components of ginger essential oil. Chemical Senses, 1(4), 377–386.
Bhattarai, S., Tran Van, H., & Duke, C. C. (2001). The stability of gingerol and shogaol in aqueous solutions. Journal of Pharmaceutical Sciences, 80(10), 1658–1664.
Bhonsle, J. B., Deshpande, V. H., & Ravindranathan, T. (1994). Synthesis of (+)-zingiberene. Indian Journal of Chemistry (Section B), 33B(4), 313–316.
Bicchi, C., & Sandra, P. (1987). Capillary gas chromatography in essential oil analysis (C. Bicchi & P. Sandra, Eds., pp. 85–121) Heidelberg: Huethig Verlag.
Birch, E. J. (1965). Reduction/hydrolysis of p-substituted phenols (Cited from Lewis, K. G., Williams, G. J. 1965). Tetrahedron Letters 4573 and Teisseire 1991.
Boniface, C., Vernin, G., & Metzger, J. (1987). Identification informatisee de composes par ana- lyse combinee: Spctres de masse-indices de Kovats. Analusis, 15, 564–568.
Breeden, D. C., & Coates, R. M. (1995). 7-Epizingiberene, a novel bisabolene sesquiterpene from wild tomato leaves (erratum to document cited in CA 121: 276729). Tetrahedron, 51(6), 1533.
Brogle, H. (1982). Supercritical fluid CO2 extract. Chemistry and Industry, 12, 385–390.
Bruins, A. P. (1987). Capillary gas chromatography in essential oil analysis (P. Sandra & C. Bicchi, Eds., pp. 329–357). Heidelberg: Huethig Verlag.
Charles, R., Garg, S. N., & Kumar, S. (2000). New gingerdione from the rhizomes of Zingiber officinale. Fitoterapia, 71(6), 716–718.
Chau, F. T., Mok, D. K. W., Gong, F., Tsui, S. K., Wong, S. K., Huang, L. Q., et al. (2001). Fingerprinting analysis of raw herb: Application of chromometrics techniques for finding out chemical fingerprint of Chinese herb. Analytical Sciences, 17(Suppl), 419–422.
Chen, Y. H., & Guo, H. Z. (1980). A survey of the raw and dry ginger produced in Szechaun (China). Yao Hsueb Tung Pao, 15(10), 12–13.
Chen, C. C., & Ho, C. T. (1988). GC analysis of volatile components of ginger oil (Zingiber officinale roscoe) extracted with liquid carbon dioxide. Journal of Agricultural and Food Chemistry, 36(2), 322–328.
Chen, C. C., Kuo, M. C., WU, C. M., & Ho, C. T. (1986). Ginger oil extracted by liquid carbon dioxide. Shib Pin ko Hsueb, 13(3–4), 188–197.
Chen, Y., Li, Z., Xue, D., & Qi, L. (1987). Determination of volatile constituents of Chinese medicinal herbs by direct vaporization capillary gas chromatography–mass spectrometry. Analytical Chemistry, 59(5), 744–749.
Chen, Y., Cai, T., Fu, L., & Shan, J. (2001). Improved high performance liquid chromatography (HPLC) determination of pungent constituents of ginger. Shipin Kexue (Beijing), 22(4), 60–63.
Connell, D. W. (1970). Chemistry of the essential oil and oleoresin of ginger (Zingiber officinale). Flavour Industry, 10, 677–693.
Connell, D. W. (1971). Chemical composition of certain products from ginger (Zingiber officinale). Australian Chemical and Process Engineering, 24(11), 27.
Connell, D. W., & Jordan, R. A. (1971). Composition and distinctive volatile flavor characteristics of the essential oils from Australian-grown ginger (Zingiber officinale). Journal of the Science of Food and Agriculture, 22(2), 93–95.
Connell, D. W., & McLachlan, B. (1972). Natural pungent compounds IV examination of the gingerols, shogaols, paradol and related compounds by TLC and GC. Journal of Chromatography, 67(1), 29–35.
Connell, D. W., & Sutherland, M. D. (1969). A re-examination of gingerol, shogaol and zingerone, the pungent principles of ginger (Zingiber officinale roscoe). Australian Journal of Chemistry, 22, 1033–1043.
Dambatta, B. B., Kazaure, M. A., & Tapley, K. N. (1998). Extraction and characterization of essential oils from Nigerian ginger. Advances in Colour Science and Technology, 1(3), 80–82.
Data, A., & Sukul, N. (1987). Antifilarial effect of Z. officinalis on Dirofilaria immitis. Journal of Helminthology, 61, 268–270.
De Pooter, H. L., Coolsack, B. A., Dirinck, P. J., & Schamp, N. M. (1985). GLC of the headspace after concentration on Tenax GC of the essential oils of apples, fresh celery, fresh lovage, honeysuckle and ginger extracts. In A. Berkeim, J. Sweden, & J. C. Scheffer (Eds.), Essential oils and aromatic plants. Dordrecht: Martinus Nijhoff/Dr W. Junk.
Denyer, C., Jackson, P., Loakes, D. M., Ellis, M. R., & Young, D. A. (1994). Isolation of anti- rhinoviral sesquiterpenes from ginger (Zingiber officinale Rosc.). Journal of Natural Products, 57, 658–662.
Ding, A., & Ding, Q. (1988). Comparison of the contents of main chemical constituents in differ- ent processed preparations of ginger. Zhongyao Tongbao, 13(11), 657–659.
Dowdle, P. A., Corr, S., & Harris, H. (2002). Solvent extraction process. Patent WO 2002 036232 A1, date 20020510, Appl. WO 2001 GB4904.
Duke, J. A. (1994). Biologically active compounds in important spices. In G. Charalambous (Ed.), Spices, herbs and edible fungi (Vol. 34, pp. 225–250). Amsterdam: Elsevier Science.
Dung, N. X., Chin, T. D., & Leclercq, P. A. (1995). Chemical investigation of the aerial parts of Zingiber zerumbet (L.) Sm. From Vietnam. The Journal of Essential Oil Research, 7(2), 153–157.
Duve, R. N. (1980). Highlights on the chemistry and pharmacology of wild ginger (Zingiber zerumbet smith). Fiji Agricultural Journal, 42(1), 41–43.
Ebwele, R. O., & Jimoh, A. A. (1988). Local processing of ginger: Prospects and problems proceedings of the first national ginger workshop (pp. 22–33). Umudike: National Root Crops Research Institute.
Ekundayo, O., Laasko, I., & Hiltunen, R. (1988). Composition of ginger (Zingiber officinale roscoe) volatile oils from Nigeria. Flavour and Fragrance Journal, 3(2), 85–90.
El-Hamouly, M. M. A., & Mohamad. (2001). Phytochemical and biological evaluation of volatile constituents of Zizyphus phlembristi (L) wild leaves and flowering tops, cultivated in Egypt Al-Azhar. Journal of Pharmaceutical Sciences, 28, 370–379.
Endo, K., Kanno, E., & Oshima, Y. (1990). Structures of antifungal diarylhepterones, ginger- enones A, B, C and isogingerenone B, isolated from the rhizomes of Zingiber officinale. Phytochemistry, 29, 797–799.
Erler, J., Vostrowsky Strobel, H., & Knobloch, K. (1988). Essential oils from ginger (Zingiber officinale roscoe). Zeitschrift für Lebensmittel-Untersuchung und -Forschung, 186(3), 231–234.
Fagbento, O., & Jauncey, K. (1994). Chemical and nutritional quality of fermented fish silage containing potato extracts, formalin or ginger. Food Chemistry, 50(4), 383–388.
Faulhaber, S., & Shirey, R. (1998). Solid-phase microextraction for the sampling in aromatic analysis. LaborPraxis, 22(5), 52. 55–58.
Flisak, J. R., & Hall, S. S. (1986). Alkylation-reduction of carbonyl systems. 15. Efficient syntheses of beta-sesquiphellandrene and zingiberenol employing a tandem arylation-multistep reduction-hydrolysis sequence. Synthetic Communications, 16(10), 1217–1228.
Garnero, J., & Tabacchi, R. (1987). Examples of artifact formation by chromatographic tech- niques. In P. Sandra & C. Bicchi (Eds.), Capillary gas chromatography in essential oil analysis (pp. 359–366). Heidelberg: Huethig Verlag.
Goku, K. (1983). Tablets as breath refreshners. Japan Kokai Tokyo Kobo Patent Jp 58,088, 308 A2, date 1983 05 26 Appl. JP 1981–185, 655.
Gopalam, A., & Ratnambal, M. J. (1989). Essential oils of ginger. Indian Perfumer, 33(1), 63–69.
Goto, C., Kasaya, S., Koga, K., Ohmoto, H., & Kagei, N. (1990). Lethal efficacy of extract from Z. officinale or (6)-shogaol and (6)-gingerol in Anisakis larvae in vitro. Parasitology, 10, 653–656.
Grosh, W. (1994). Determination of potent odorants in foods by aroma extract dilution analysis (AEDA) and calculation of odor quality values (COAVS). Flavour and Fragrance Journal, 9, 147–158.
Guenther, E. (1952). The essential oils, 2nd ed. Individual essential oils of the plant families (Vol. 5). New York: van Nostrand.
Gujral, S., Bhumra, H., & Swaroop, M. (1978). Cholesterolemic activity of pungent principles of ginger. Nutrition Reports International, 17, 183–189.
Guo, P., Xu, J., Xu, S., & Wang, K. (1997). Inhibition of fulvic acid-induced hydrogen peroxide production in chondrocyte by ginger volatile oil. Zbongguo Zbongyao Zasshi, 22(9), 559–561.
Gurib-Fakim, A., Mandarbaccus, N., Leach, D., Doimo, L., & Wohlmuth, H. (2002). Essential oil composition of Zingiberaceae species from Mauritius. The Journal of Essential Oil Research, 14(4), 271–273.
Haq, F., Faruque, S. M., Islam, S., & Ali, E. (1986). Studies on Zingiber officinale roscoe. Part 1. Chemical investigation of the rhizome. Bangladesh Journal of Scientific and Industrial Research, 21(1–4), 61–69.
Harrison, A. G. (1983). Chemical ionization mass spectrometry. Boca Raton: CRC Press.
Harvey, D. J. (1981). Gas chromatographic studies of ginger constituents. Journal of Chromatography, 212, 75–84.
Hasnah, M. S., & Ahmad, A. R. 1993. Some important metabolites from Malaysian ginger. In N. A. Sharman (Ed.), Applications of plants in vitro technology (pp. 191–196). Proceedings of the international symposium, Serdand, Malaysia, 16–18 November 1993 Department of Biochem and Microbiology, Universiti Pertanian Malaysia, Serdang, Malaysia.
He, W., Li, L., Guo, S., & Li, Y. (1999). Extraction of ginger oil and its anti-oxidative activity for edible oils and fats. Zbongguo Youzhi, 24(1), 42–44.
He, W., Li, L., Li, Y., Guo, S., & Guo, B. (2001). Anti-oxidative activity of a new compound from ginger. Zbongguo Bingli Shenli Zashi, 17(5), 461–463.
Heath, H. P., & Reineccius, G. (1988). Flavour chemistry and technology. Westport: Avi Publishing.
Herout, V., Benesova, V., & Pliva, J. (1953). The sesquiterpenes of ginger oil. Cull Czeck Chemical Communications, 18, 248–256.
Hikino, H., Kiso, Y., Kato, N., Hamada, Y., Shiori, T., Aiyama, R., et al. (1985). Antihepatotoxic activity of gingerols and diarylheptanoids. Journal of Ethnopharmacology, 14, 31–39.
Hill, C. E., Dowdle, P. A., & Corr, S. (1999). Solvent extraction process PCT. Int. Appl. WO 0064,555 (Cl B 01 D1/00), 2 Nov 2000. G.B.Appl. 1999/9, 136, 22 April 1999.
Ho, C. T., Zhang Shi, H., & Tang, J. (1989). Flavor chemistry of Chinese foods. Food Review International, 5(3), 53–87.
Huang, X., Wang, J., & Zhang, X. (1999a). Essential oil of Zingiber officinalis. Huaxue Shijie, 30(9), 420–433.
Huang, X., Wang, J., & Zhang, X. (1999b). Determination of the pungent principles in ginger powder, ginger skin and baked ginger. Zbongcaoyae, 30(6), 423–425.
Hus, H. J., Chang, H. L., & Jian, N. (1999). Synergistic natural pesticides containing garlic. Eur. Pat. Appl. 945,066, A1, 1999 09 29, Appl. 1999-302.286 (EP) 17P. US 6231865, BI, 2001 05 15, Appl. 1999-273636.
Ibrahim, H., & Zakaria, M. B. (1987). Essential oils from three Malaysian Zingiberaceae species. Malaysian Journal of Science, 9, 73–76.
ISI. (1975). Specification for ginger oleoresin. New Delhi: Indian Standards Institution.
Jain, T. C., Varma, K. R., & Bhattacharya, C. S. (1962). Terpenoids XXVII GLC analysis of monoterpenes and its application to essential oils. Perfume Essential Oil Research, 53, 678–684.
James, A. T., & Martin, A. J. P. (1952). Gas liquid chromatography. Analysis, 77, 198.
Jennings, W., & Shibamoto, T. (1980). Qualitative analysis of flavour and fragrances volatiles by glass capillary gas chromatography. New York: Academic.
Jo, K. S. (2000). Analysis of gingerol compounds of raw ginger (Zingiber officinale roscoe.) and its paste to high performance liquid chromatography mass spectrometry (LC-MS). Hanguk Sikpum Yongyang Kwabak Hoechi, 29(5), 747–751.
Joulain, D., & Konig, W. A. (1998). The atlas of spectral data sesquiterpene hydrocarbons. Hamburg: E.B. Verlag.
Kami, T., Nakayama, N., & Hayashi, S. (1972). Volatile constituents of Zingiber officinale. Phytochemistry, 11, 3377–3381.
Kano, Y., Tanabe, M., & Yasuda, M. (1990). On the evaluation of the preparation of Chinese medicinal prescriptions (V): Diterpenes from Japanese ginger Kinto. Shoyakugaku Zasshi, 44(1), 55–57.
Kawara, H. (1998). Insecticidal baits containing ginger oil against cockroach. Japan Kokat Tokyo, 4 p. No 10, 017,405, A2, 20 Jan 1998, 1996–172, 020.
Kawashi, S., Morimitsu, Y., & Osawa, T. (1994). Chemistry of ginger components and inhibitory factors of the arachidonic acid cascade. In C. T. Ho, T. Osawa, M. T. Huang, & R. T. Rosen (Eds.), Food phytochemicals for cancer prevention II (ACS symposium series 547). Washington, DC: American Chemical Society.
Kikuzaki, H. (2000). Ginger for drug and spice purposes. In G. O. Maza & B. Dave (Eds.), Herbs, botanicals and teas (pp. 75–105). Lancaster: Technomic Publishing.
Kikuzaki, H., & Nakatami, N. (1996). Cyclic diarylheptanoids from rhizomes of Zingiber officinale. Phytochemistry, 43(1), 273–277.
Kim, D. S. H. I. (2001). Pharmaceutical composition with natural products or synthetic analogs which are useful in the prevention and treatment of beta-amyloid protein-induced disease PCT. International Patent Application WO 0,130, 335 A2 date 2001 05 03, Appl. WO 2000-US41, 436.
Kim, J. S., Koh, M. S., Kim, Y. H., Kim, M. K., & Hong, J. S. (1991). Volatile flavor components of Korean ginger (Zingiber officinale roscoe.). Hanguk Sikpum Kwabakhoechi, 23(2), 141–149.
Kim, M. K., Na, M. S., Hong, J., & Jung, S. T. (1992). Volatile flavor components of Korean ginger (Zingiber officinale roscoe) extracted with liquid carbon. Hanguk Nongbua Hakborchi, 35(1), 59–63.
Kitamura, Y., & Naguno, Y. (2000). Purification and characterization of cysteine proteinase inhibitor from fresh ginger rhizome Kenkyu Kiyo-Tokyo Kasei Daigaku 2. Shizen Kagaku, 40, 53–56.
Kiuchi, F., Shibuya, M., & Sankawa, U. (1982). Inhibitors of the biosynthesis of prostaglandins. Chemical and Pharmaceutical Bulletin Tokyo, 30, 754–757.
Kobayashi, M., Shoji, N., & Ohizumi, Y. (1987). Gingerol, a novel cardiotonic agent, activates the Ca2+ pumping ATPase in skeletal cardiac sarcoplasmic reticulum. Biochimica et Biophysica Acta, 903, 96–102.
Koedam, A. (1987). Some aspects of essential oil preparation. In P. Sandra & C. Bicchi (Eds.), Capillary gas chromatography in essential oil analysis, 903 Biochem Biophys Acta (pp. 13–28). Heidelberg: Huethig Verlag.
Koenig, W. A., Rieck, A., Hardt, I., Gehrcke, B., Kubeczka, K. H., & Muhle, H. (1994). Enantiomeric composition of the chiral constituents of essential oils. Part 2: Sesquiter- pene hydrocarbon. Journal of High Resolution Chromatography, 17(5), 315–320.
Kostrzewa, E., & Karwowska, K. (1976). Characteristics of a flavor and odor extract of ginger. Proceedings of Institute Laboratory Badav Przem Sozyw, 26(1), 63–73.
Kovats, E. (1958). Gas chromatographic characterization of organic compounds I. Retention indexes of aliphatic halides, alcohols, aldehydes, and ketones. Helvetica Chimica Acta, 41, 1915–1932.
Kovats, E. (1965). Advances in chromatography (J. C. Giddings & R. A. Keller, Eds., pp. 119–127). New York: Marcel Dekker.
Koya, K. M. A., Premkumar, T., & Gautam, S. S. S. (1988). Chemical control of shoot borer Dichocrocis punctiferalis Guen. on ginger Zingiber officinale roscoe. Journal of Plantation Crops, 16(1), 58–59.
Krishnakantha, T., & Lokesh, B. (1993). Scavenging for superoxide anions by spice principles. Indian Journal of Biochemistry & Biophysics, 30, 133–134.
Krishnamurthy, N., Nambudiri, E. S., Mathew, A. G., & Lewis, Y. S. (1970). Essential oils of ginger. Indian Perfumer, 14(1), 1–3.
Lapworth. (1917). Cited from Connell and Sutherland, 1969.
Lawrence, B. M. (1983). Recent studies on the oil of Zingiber officinale roscoe. Perfumer Flavours, 9, 2–40.
Lee, C. Y., Chiou, J. W., & Chang, W. H. (1982). Labdane-type diterpene: Galanolactone. Journal of the Chinese Agricultural Chemical Society, 20, 61–67.
Lewis, Y. S., Mathew, A. G., Nambudiri, E. S., & Krishnamurthy, N. (1972). Oleoresin ginger. Flavour Industry, 3(2), 78–81.
Li, A. (1995). Spectrometric determination of gingerol in ginger oil condiments. Zbongguo Tiaoweipin, 11, 30–32.
Li, J., Wang, Y., Ma, H., Hao, J., & Yang, H. (2001). Comparison of chemical components between dry and fresh Zingiber officinale. Zbongguo Zbongyao Zassbi, 26(11), 748–751.
Lin, Z. K., & Hua, Y. F. (1987). Chemical constituents of the essential oil from Zingiber officinale roscoe. Sichuan Youji Huaxue, 6, 444–448.
Ma, X., Gu, Y., & Fu, J. (1990). Biosynthesis of LTB4 and selection of its inhibitors. Baiquien Yike Daxue Xuebao, 16(3), 222–225.
Macleod, A. J., & Pieris, N. M. (1984). Volatile aroma constituents of Sri Lankan ginger. Phytochemistry, 9, 353–359.
Martins, A. P., Salqueiro, L., Goncalves, M. J., de Cunha, A. P., Vila, R., Canigueral, S., et al. (2001). Essential oil composition and antimicrobial activity of three Zingiberaceae from S Tome Principe. Planta Medica, 67(6), 580–584.
Masada, Y. (1976). Analysis of essential oils by gas chromatography and mass spectrometry (pp. 251–255). New York: Wiley.
Masada, Y., Inoue, T., Hashimoto, K., Fujika, M., & Shiraki, K. (1973). Studies on the pungent principles of ginger (Zingiber officinale roscoe) by GC–MS. Yakugaku Zasshi, 93(3), 318–321.
Masuda, T., Matsumura, H., Oyama, Y., & Takeda, Y. (1998). Synthesis of (+) cassumunins A and B, new cucuminoids antioxidants having protective activity on the living cell against oxi-dative damage. Journal of Natural Products, 61, 609–613.
Mathew, A. G., Krishnamurthy, N., Nambudiri, E. S., & Lewis, Y. S. (1973). Oil Ginger. Flavour Industry, 4(5), 226–229.
Meireles, M. A. A., & Nikolov, Z. I. (1994). Extraction and fractionation of essential oils with liquid carbon dioxide (LCO2). In G. Charlambous (Ed.), Spices, herbs and edible fungi (Vol. 34, pp. 171–199). Amsterdam: Elsevier Science.
Meyer-Warnod, B. (1984). Natural essential oils. Perfumer and Flavour, 9, 93.
Mitra, C. R. (1975). Important Indian spices III. Ginger (Zingiberaceae). Rechst Aromen Koerperpflegem, 25(6), 170.
Molyneux, F. (1971). Ginger—A natural flavor essence. Australian Chemical and Process Engineering, 24(3), 29. 31, 33–34.
Mosandhl, A. (1992). Capillary gas chromatography in quality assessment of flavours and fragrances. Journal of Chromatography, 624, 267–292.
Moyler, D. A., Browning, R. M., & Stephens, M. A. (1994). Carbon dioxide extraction of essential oils. In G. Charlambous (Ed.), Spices, herbs and edible fungi (Vol. 34, pp. 145–170). Amsterdam: Elsevier Science.
Murakami, A., Nakamura, Y., Ohto, Y., Tanaka, T., Makita Koshimizu, K., & Ohigashi, H. (1999). Cancer preventive phytochemicals from tropical Zingiberaceae. In H. R. Whitaker (Ed.), Food for health in Pacific rim (pp. 125–133). International conference on food, science and technology. Turnbull: Food & Nutrition Press. 1997.
Nakatani, N. (1995). Chemistry and properties of pungent compounds. Koryo, 185, 59–64.
Nakatani, N., & Kikuzaki, H. (2002). Antioxidants in ginger family. ACS Symposium Series Quality Management of Nutraeceuticals, 803, 230–240.
Nakazawa, T., & Ohsawa, K. (2002). Metabolism of (6)-gingerol in rats. Life Sciences, 70(18), 2165–2175.
Narayanan, C. S., & Mathew, A. G. (1985). Chemical investigation on spice oils. Indian Perfumer, 29(1–2), 15–22.
Natarajan, C. P., Bai, R. P., Krishnamurthy, M. N., Raghavan, B., Shankaracharya, N. B., Kuppuswamy, S., et al. (1972). Chemical composition of ginger varieties and dehydration studies on ginger. Journal of Food Science and Technology, 9(3), 120–124.
Ney, K. H. (1990). Aromagrams of spices. Alimenta 29(5), 91–93, 95–100.
Ni, M., Chen, Z., & Yan, B. (1988). Synthesis of optically active sesquiterpenes and exploration of their anti-fertility effect. Huadong Huagong Xueyuan, 14, 675–679.
Nigam, I. C., & Levi, L. (1963). Column- and gas-chromatographic analysis of the oil of wild ginger. Identification and estimation of some new constituents. Canadian Journal of Chemistry, 41(7), 1726–1730.
Nigam, M. C., Nigam, I. C., Levi, L., & Handa, K. L. (1964). Essential oils and their constituents XXII. Detection of new trace components in oil of ginger. Canadian Journal of Chemistry, 42(11), 2610–2615.
Nishimura, O. (2001). Enantiomer separation of the characteristic odorants in Japanese fresh rhizomes of Zingiber officinale roscoe (ginger) using multi-dimensional GC system and confirmation of the odor character of each enantiomer by GC-olfactometry. Flavour and Fragrance Journal, 16(1), 13–18.
Nomura, H., & Tsurami, S. (1926). Structure of shogaol. Proceedings of Imperial Academy Tokyo, 2, 229.
Ohkubo, K., Tagaki, Y., Takatoku, H., Hori, K., Kumoku, H., & Shibuya, Y. (2000). Ceramide production-accelerating agent. European Patent Applications. EP 993,822 (CL. AK61K7/48) 19 Apr 2000 JP Appl. 1999/122,402 28 Apr 1999.
Okwu, D. E. (2001). Evaluation of the chemical composition of indigenous spices and flavoring agents. Global Journal of Pure and Applied Sciences, 7(3), 455–459.
Onyenekwe, P. C., & Hashimoto, S. (1999). The composition of the essential oil of dried Nigerian ginger (Zingiber officinale). Z. Lebensm. Unters Forsch. Food Research and Technology, 209(6), 407–410.
Paquette, L. A., & Kinney, W. A. (1982). A new synthon for the regiospecific y-alkylation of 2-cyclohexenones. Application to the synthesis of zingiberenol and oxygenated bicyclo (3.3.1) nonanes. Tetrahedron Letters, 23(2), 131–134.
Pellerin, P. (1991). Supercritical fluid extraction of natural raw materials for the flavor and perfume industry. Perfumer Flavor, 16(4), 37–39.
Pliva, J., Horak, M., Herout, V., & Sorm, F. (1960). T.I. Sesquiterpene, S10–S11 Sammlung der Spectrum und Physikalischen Konstanten. Berlin: Akademie Verlag.
Prachi, S., Tilak, R., & Singh, B. M. (2002). Salicylic acid induced insensitivity to culture filtrate of Fusarium oxysporum f. sp. Zingiberi in the calli of Zingiber officinale roscoe. European Journal of Plant Pathology, 108(1), 31–39.
Purseglove, J. W., Brown, G. G., Green, C. L., & Robbins, S. R. J. (1981). Spices, vols I and II. New York: Longman.
Rani, K. (1999). Cyclization of farnesyl pyrophosphate into sesquiterpenoids in ginger rhizomes (Zingiber officinale). Fitoterapia, 70(6), 568–574.
Rogacheva, S., Kuntcheva, M., Obretenov, T., & Vernin, G. (1998). Formation and structure of melanoidins in foods and model systems. In J. O’Brien, E. E. Nurstsen, M. J. C. Crabbe, & J. M. Ames (Eds.), The Maillard reaction in foods and medicine (pp. 89–93). Cambridge: Royal Society of Chemistry.
Rosella, M.A., de Pfirter, G.B., Mandrile, E.L., 1996. Ginger (Zingiber officinale roscoe Zingiberaceae): ethnopharmacognosy, cultivation, chemical composition and pharmacology. Acta Pharmaceutical Bonaerense 15 (1), 35–42.
Roy, B. C., Goro, M., & Hirose, T. (1996). Extraction of ginger oil with supercritical carbon dioxide experiments and modeling. Industrial and Engineering Chemistry Research, 35, 607–612.
Sadtler Research Laboratories. (1985). The Sadtler standard gas chromatography retention index library. Philadelphia: Sadtler Research Laboratories Division of Bio-Rad Laboratories.
Sane, R. T., Phadke, M., Hijli, P. S., Shah, M., & Patel, P. H. (1998). Geographical variation study on gingerol (a pungent principle from Zingiber officinale) and ginger oil, using HPTLC technique and accelerated stability study on gingerol from Zingiber officinale using HPTLC method. Indian Drugs, 35(1), 37–44.
Sharma, R. K., Misra, B. P., Sarma, T. C., Bordoloi, A. K., Pathak, M. G., & Leclercq, P. A. (1997). Essential oils of Curcuma longa L. from Bhutan. Journal of Essential Oil Research, 9, 589–592.
Tanabe, T., Kami, T., & Hayashi. (1992). Volatile separated compounds obtained by SIM technique. Phytochemistry, 12, 3388–3390.
Taveira, et al. (1997). Chemistry of the essential oil and oleoresin of ginger (Zingiber officinale). Flavor Industry, 10, 677–693.
Thomson, E. H., Wolf, I. D., & Allen, C. E. (1974). Ginger rhizome: A new source of proteolytic enzyme. Journal of Food Science, 38, 652–655.
Toofanian, F., & Stegeman, H. (1988). Comparative effect of ethylene oxide and gamma irradiation of the chemical, sensory and microbial quality of ginger, cinnamon, fennel and fenugreek. Acta Alimentaria, 17(4), 271–281.
Vahira-Lechat, I., Menut, C., Lamaty, G., & Bessiere, J. M. (1996). Huiles essentielles de Polynesie Francaise Rivista Ital. EPPOS, (Special Edition), pp. 627–638.
Van Beek, T. A. (1991). Special methods for the essential oil of ginger. In H. F. Linkens & J. F. Jackson (Eds.), Modern methods of plant analysis: Essential oils and wax (Vol. 12, pp. 79–97). Berlin/Heidelberg: Springer.
Van Beek, T. A., Posthumus Lelyveld, G. P., Hoang, V. P., & Yen, B. T. (1987). Investigation of the essential oil of Vietnamese ginger. Phytochemistry, 26(11), 3005–3010.
Van den Dool, H., & Kratz, P. D. (1963). A generalization of the retention index system including linear temperature programmed gas–liquid partition chromatography. Journal of Chromatography, 11, 463–471.
Variyar, P. S., Gholap, A. S., & Thomas, P. (2000). Estimation of pungency in fresh ginger: A new fluorimetric assay. Journal of Food Composition and Analysis, 13(3), 219–225.
Varma, K. R., Jain, T. C., & Bhattacharya, S. C. (1962). Terpenoids. XXXIV. Structure and stereo chemistry of zingiberol and juniper camphor. Tetrahedron, 18, 974–984.
Verma, S. K., Singh, J., Khamesra, R., & Bordia, A. (1993). Effect of ginger on platelet aggregation in man. The Indian Journal of Medical Research, 98, 240–242.
Vernin, G. (1970). La Chromatographie en Couche Mince. Techniques et Applications en Chimie Organique. Dunod, Paris, Hungarian translation, originally published in 1970 as Vekonyreteg-Kromatographia: A Serves Kemiaban, Muskaki Konyvkiado, Budapest.
Vernin, G. (Ed.). (1982). The chemistry of heterocyclic flavouring and aroma compounds. Chichester: Ellis Horwood.
Vernin, G., & Parkanyi, C. (1994). Ginger oil (Zingiber officinale roscoe). In G. Charalambous (Ed.), Spices, herbs and edible fungi (Vol. 34, pp. 579–594). Amsterdam: Elsevier Science.
Vernin, G., & Petitjean, M. (1982). Mass spectrometry of heterocyclic compounds used for flavourings. The chemistry of heterocyclic flavouring and aroma compounds (pp. 305–342). Chichester: Ellis Horwood.
Vernin, G., Debrauwer, L., Vernin, G. M. F., Zamkostian, R. M., Metzger, J., Larice, J. L., et al. (1992). Heterocycles by thermal degradation of some Amadori intermediates. In G. Charalambous (Ed.), Off-flavours in foods and beverages (pp. 567–624). Amsterdam: Elsevier Science.
Wang, W. (2001). Antioxidant properties of four vegetables with sharp flavor. Shipin Yu Fajiao Gomgye, 27, 28–31.
Wen, Z., Yu, D., & Lu, Q. (2001). Study on antioxidation of ginger oil in concentrated fish oil. Zbongguo Youzhi, 26(4), 58–60.
Wenninger, J. A., Yates, R. L., & Dolinsky, M. (1967). High resolution infrared spectra of some naturally occurring sesquiterpene hydrocarbons. Journal of Association and Analytical Chemistry, 50(6), 1313–1335.
Yamahara, J., Matsuda, H., Yamaguchi, S., Shimoda, H., Murakami, N., & Yoshikawa, M. (1995). Pharmacological study on ginger processing I. Antiallergic activity and cardiotonic action of gingerols and shogaols. Nature Medicine Tokyo, 49(1), 76–83.
Zaidi, V. H., Variyar, P. S., & Gholap, A. S. (1992). Estimation of inorganic elements in trace amounts in ginger. Journal of Food Composition and Analysis, 9, 220–229.
Zhu, L. F., Li, Y. H., Li, B. L., Ju, B. Y., & Zhang, W. L. (1995). Aromatic plants and essential constituents (Supplement I). South China Institute of Botany Chinese Academy of Sciences Hai Feng Publishing. Distributed by Peace Book Ltd., Hong Kong.
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer Nature Switzerland AG
About this chapter
Cite this chapter
Nair, K.P. (2019). The Chemistry of Ginger. In: Turmeric (Curcuma longa L.) and Ginger (Zingiber officinale Rosc.) - World's Invaluable Medicinal Spices. Springer, Cham. https://doi.org/10.1007/978-3-030-29189-1_16
Download citation
DOI: https://doi.org/10.1007/978-3-030-29189-1_16
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-29188-4
Online ISBN: 978-3-030-29189-1
eBook Packages: Biomedical and Life SciencesBiomedical and Life Sciences (R0)