Abstract
The chemical modification of oxidized bitumen BND 70/100 by formaldehyde, or rather its aqueous solution, formalin, was carried out for use in hot asphalt pavement technologies. The chemical modification conditions of bituminous binder by formaldehyde are given. There is shown considerably increases of the heat capacity (softening point) and adhesion properties (adhesion to glass) in the chemical modification process of oxidized bitumen by formaldehyde. The adhesion determining methods of binder with granite crushed stone and glass plates as variants of adhesive ability estimation of bitumen are given. It has been established that the modification by formalin in the amount of 10% by weight dramatically reduces the bitumen viscosity, so it showed necessary to carefully monitor the source bitumen and formalin ratio content during the modification. A hot dense fine-grained asphalt mix was selected. The influence of modified bitumen on physical and mechanical properties of asphalt concrete, such as water saturation, border compressive strength at 20 and 50 °C and the long-term water resistance coefficient after 15 days.
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References
Pyshyev S, Grytsenko Y, Solodkyy S, Sidun I, Vollis O (2015) Using bitumen emulsions based on oxidated, distillation and modified oxidated bitumens for slurry seal production. Chem Chem Technol 9(3):359–366
Nykypanchuk M, Hrynchuk Y, Pyshyev S, Gunka V, Grytsenko Y, Bratychak M (2016) Polymer modified bitumen: review. Chem Chem Technol 10(4):631–636
Pyshyev S, Gunka V, Grytsenko Y, Shved M, Kochubei V (2017) Oil and gas processing products to obtain polymers modified bitumen. Int J Pavement Res Technol 10(4):289–296. https://doi.org/10.1016/j.ijprt.2017.05.001
Zhu J, Birgisson B, Kringos N (2014) Polymer modification of bitumen: Adv Challenges Eur Polym J 54:18–38. https://doi.org/10.1016/j.eurpolymj.2014.02.005
Nykypanchuk M, Hrynchuk Y, Olchovyk M (2013) Effect of modified bitumen on physico-mechanical properties of asphalt concrete. Chem Chem Technol 7(4):467–470. https://doi.org/10.23939/chcht07.04.467
Demchuk Y, Sidun I, Gunka V, Pyshyev S, Solodkyy S (2018) Effect of phenol-cresol-formaldehyde resin on adhesive and physico-mechanical properties of road bitumen. Chem Chem Technol 12(4):456–461. https://doi.org/10.23939/chcht12.04.456
Çubuk, M, Gürü, M, Çubuk, MК, Arslan, D (2014): Rheological properties and performance evaluation of phenol formaldehyde modified bitumen. J Mater Civ Eng, 26 (6). https://doi.org/10.1155/2018/7913527
Saha, SK, Suman, SK. (2017). Characterization of bakelite-modified bitumen. Innovative Infrastructure Solutions, 2(3). https://doi.org/10.1007/s41062-017-0052-0
Pyshyev S, Demchuk Y, Gunka V, Sidun I, Shved M, Bilushchak H, Obshta A (2019) Development of mathematical model and identification of optimal conditions to obtain phe-nol-cresol-formaldehyde resin. Chem Chem Technol 13(2):212–217. https://doi.org/10.23939/chcht13.02.212
Moshchinskaya, NK (1969): Polimernye matermly na osnove aromatlcheskikh uglevodorodov i formal’degida (Polymeric Materials Based on Aromatic Hydrocarbons and Formaldehyde), Kyiv, p. 266
Higashihara, G, Okoshi, A (2014): Aromatic hydrocarbon formaldehyde resin, modified aromatic hydrocarbon formaldehyde resin, and epoxy resin, and method for producing said resins, European Patent EP3012275A1
EN 1427-2015. European Standard. Bitumen and bituminous binders. Determination of the softening point. Ring and Ball method
EN 1426-2015. European Standard. Bitumen and bituminous binders. Methods of tests for petroleum and its products. Determination of needle penetration
EN 13587:2016. Bitumen and bituminous binders. Determination of the tensile properties of bituminous binders by the tensile test method)
EN 14023:2010. Bitumen and bituminous binders. Specification framework for polymer modified bitumens
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Gunka, V., Sidun, I., Solodkyy, S., Vytrykush, N. (2020). Hot Asphalt Concrete with Application of Formaldehyde Modified Bitumen. In: Blikharskyy, Z., Koszelnik, P., Mesaros, P. (eds) Proceedings of CEE 2019. CEE 2019. Lecture Notes in Civil Engineering , vol 47. Springer, Cham. https://doi.org/10.1007/978-3-030-27011-7_14
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DOI: https://doi.org/10.1007/978-3-030-27011-7_14
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