Abstract
Organic materials that mimic the mammalian skeleton muscles are of great interest in artificial actuators for applications such as robot legs, surgical instruments and Braille displays. These ionic polymer metal composite (IPMC) actuators are compact, lightweight, silent, strong and reliable. In this regard, conjugated or conducting polymeric materials are attractive as these offer the desired properties and their actuator operations are similar to biological muscles. This chapter focuses on four types of conjugated polymers: polyaniline, polypyrrole, polythiophene and poly(3,4-ethylenedioxythiophene): polystyrene sulfonate as active materials in IMPC actuators. First, their chemical or electrochemical synthesis is described. Then, their actuators characteristics and performances are discussed and compared. In sum, this chapter aims to give the reader a good overview of the pros and cons in respect of each type of materials as well as their uses in actuators.
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References
Alici, G., Spinks, G., Huynh, N.N., Sarmadi, L., Minato, R.: Establishment of a biomimetic device based on tri-layer polymer actuators–propulsion fin. Bioinspir. Biomim. 2, 18–30 (2007)
Chen, D., Pei, Q.: Electronic muscles and skins: a review of soft sensors and actuators. Chem. Rev. 117, 11239–11268 (2017)
Bar-Cohen, Y.: Electroactive Polymer (EAP) Actuators as Artificial Muscles: Reality, Potential, and Challenges, 2nd edn. SPIE Publications (2004)
Bhandari, B., Lee, G.-Y., Ahn, S.-H.: A review on IPMC material as actuators and sensors: fabrications, characteristics and applications. Int. J. Precis. Eng. Manuf. 13, 141–163 (2012)
Bar-Cohen, Y., Zhang, Q.: Electroactive polymer actuators and sensors. MRS Bull. 33, 173–177 (2008)
Eisenberg, A., King, M.: Ion-containing Polymers: Physical Properties and Structures. Academic Press (1977)
Kim, O., Kim, S.J., Park, M.J.: Low-voltage-driven soft actuators. Chem. Commun. 54, 4895–4904 (2018)
Kim, K.J., Shahinpoor, M.: Ionic polymer–metal composites: II Manufacturing techniques. Smart Mater. Struct. 12, 65–79 (2003)
Shahinpoor, M., Kim, K.J.: Novel ionic polymer–metal composites equipped with physically loaded particulate electrodes as biomimetic sensors, actuators and artificial muscles. Sens. Actuator A-Phys. 96, 125–132 (2002)
Kim, B.K., Kim, B.M., Ryu, J.W., Oh, I.-H., Lee, S.-K., Cha, S.-E., Pak, J.-H.: Analysis of mechanical characteristics of the ionic polymer metal composite (IPMC) actuator using cast ion-exchange film. Proc. SPIE 5051, 486–495 (2003)
Lee, S.J., Han, M.J., Kim, S.J., Jho, J.Y., Lee, H.Y., Kim, Y.H.: A new fabrication method for IPMC actuators and application to artificial fingers. Smart Mater. Struct. 15, 1217–1224 (2006)
Takeneka, H., Torikai, E., Kawami, Y., Wakabayashi, N.: Solid polymer electrolyte water electrolysis. Int. J. Hydrog. Energy 7, 397–403 (1982)
Shahinpoor, M., Kim, K.J.: Ionic polymer-metal composites: III Modeling and simulation as biomimetic sensors, actuators, transducers, and artificial muscles. Smart Mater. Struct. 13, 1362–1388 (2004)
Otero,T.F., Angulo, E., Rodriguez, J., Santamaria, C.: Electrochemomechanical properties from a bilayer: polypyrrole/non-conducting and flexible material—artificial muscle. J. Electroanal. Chem. 341, 369–375 (1992)
Shirakawa, H., Louis, E.J., MacDiarmid, A.G., Chiang, C.K., Heeger, A.J.: Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH)x. J. Chem. Soc. Chem. Commun. 578–580 (1977)
Chiang, C.K., Fincher, C.R., Park, Y.W., Heeger, A.J., Shirakawa, H., Louis, E.J., Gau, S.C., MacDiarmid, A.G.: Electrical conductivity in doped polyacetylene. Phys. Rev. Lett. 39, 1098 (1977)
van Mullekom, H.A.M., Vekemans, J.A.J.M., Havinga, E.E., Meijer, E.W.: Developments in the chemistry and band gap engineering of donor-acceptor substituted conjugated polymers. Mater. Sci. Eng. R Rep. R32, 1 (2001)
Moliton, A., Hiorns, R.C.: Review of electronic and optical properties of semiconducting π-conjugated polymers: applications in optoelectronics. Polym. Int. 53, 1397–1412 (2004)
Patil, A.O., Heeger, A.J., Wudl, F.: Optical properties of conducting polymers. Chem. Rev. 183–200 (1988)
Morita, S., Zakhidov, A.A., Yoshino, K.: Doping effect of buckminsterfullerene in conducting polymer: change of absorption spectrum and quenching of luminescene. Solid State Commun. 82, 29–252 (1992)
Lüssem, B., Keum, C.-M., Kasemann, D., Naab, B., Bao, Z., Leo, K.: Doped organic transistors. Chem. Rev. 116, 13714–13751 (2016)
Kaneto, K., Kaneko, M., Min, Y., MacDiarmid, A.G.: “Artificial muscle”: electromechanical actuators using polyaniline films. Synth. Met. 71, 2211–2212 (1995)
Mondal, S.K., Prasad, K.R., Munichandraiah, N.: Analysis of electrochemical impedance of polyaniline films prepared by galvanostatic, potentiostatic and potentiodynamic methods. Synth. Met. 148, 275–286 (2005)
Boeva, Z.A., Sergeyev, V.G.: Polyaniline: synthesis, properties, and application. Polym. Sci. Ser. C 56, 144–153 (2014)
Li, C., Bai, H., Shi, G.: Conducting polymer nanomaterials: electrosynthesis and applications. Chem. Soc. Rev. 38, 2397–2409 (2009)
Heinze, J., Frontana-Uribe, B.A., Ludwigs, S.: Electrochemistry of conducting polymers—persistent models and new concepts. Chem. Rev. 110, 4724–4771 (2010)
Stejskal, J., Gilbert, R.G.: Polyaniline. Preparation of a conducting polymer (IUPAC Technical Report). Pure Appl. Chem. 74, 857–867 (2002)
Kim, J., Yun, S.-R., Deshpande, S.D.: Synthesis, characterization and actuation behavior of polyaniline-coated electroactive paper actuators. Polym. Int. 56, 1530–1536 (2007)
Sansinena, J.-M., Gao, J., Wang, H.-L.: High-performance, monolithic polyaniline electrochemical actuators. Adv. Funct. Mater. 13, 703–709 (2003)
Wang, H.L., Gao, J.B., Sansinena, J.M., McCarthy, P.: Fabrication and characterization of polyaniline monolithic actuators based on a novel configuration: integrally skinned asymmetric membrane. Chem. Mater. 14, 2546–2552 (2002)
Liu, Q., Liu, L., Xie, K., Meng, Y., Wu, H., Wang, G., Dai, Z., Wei, Z., Zhang, Z.: Synergistic effect of a r-GO/PANI nanocomposite electrode based air working ionic actuator with a large actuation stroke and long-term durability. J. Mater. Chem. A 3, 8380–8388 (2015)
Baughman, R.H., Cui, C., Zakhidov, A.A., Iqbal, Z., Barisci, J.N., Spinks, G.M., Wallace, G.G., Mazzoldi, A., Rossi, D.D., Rinzler, A.G., Jashinski, O., Roth, S., Kertesz, M.: Carbon nanotubes actuators. Science 284, 1340–1344 (1999)
Fukushima, T., Asaka, K., Kosaka, A., Aida, T.: Fully plastic actuator through layer-by-layer casting with ionic-liquid-based bucky gel. Angew. Chem. Int. Ed. 44, 2410–2413 (2005)
Xu, J., Wang, K., Zu, S., Han, B., Wei, Z.: Hierarchical nanocomposites of polyaniline nanowire arrays on graphene oxide sheets with synergistic effect for energy storage. ACS Nano 4, 5019–5026 (2010)
Vernitskaya, T.V., Efimov, O.N.: Polypyrrole: a conducting polymer; its synthesis, properties and applications. Russ. Chem. Rev. 66, 443–457 (1997)
Alici, G., Punning, A., Shea, H.R.: Enhancement of actuation ability of ionic-type conducting polymer actuators using metal ion implantation. Sens. Actuator B Chem. 157, 72–84 (2011)
Ding, J., Zhou, D., Spinks, G., Wallace, G., Forsyth, S., Forsyth, M., MacFarlane, D.: Use of ionic liquids as electrolytes in electromechanical actuator systems based on inherently conducting polymers. Chem. Mater. 15, 2392–2398 (2003)
Scharifker, B.R., Garcia-Pastoriza, E., Marino, W.: The growth of polypyrrole films on electrodes. J. Electroanal. Chem. 300, 85–98 (1991)
Zemel, P.S.A., Zinger, B.: Characterization of polypyrrole based heterojunction. Synth. Met. 41, 443 (1991)
Pei, Q., Inganas, O.: Conjugated polymers and the bending cantilever method: electrical muscles and smart devices. Adv. Mater. 4, 277–278 (1992)
Chiarelli, P., Della Santa, A., DeRossi, D., Mazzoldi, A.: Actuation propeties of electrochemically driven polypyrrole free-standing films. In: Proceedings of 2nd International Conference on Intelligent Materials, p. 352. Technomic Pub. Co. (1994)
Gandhi, M.R., Murray, P., Spinks, G.M., Wallace, G.G.: Mechanism of electromechanical actuation in polypyrrole. Synth. Met. 73, 247–256 (1995)
Temmer, R., Must, I., Kaasik, F., Aabloo, A., Tamm, T.: Combined chemical and electrochemical synthesis methods for metal-free polypyrrole actuators Sens. Actuator B-Chem. 166–167, 411–418 (2012)
Madden, J.D., Cush, R.A., Kanigan, T.S., Hunter, I.W.: Fast contracting polypyrrole actuators. Synth. Met. 113, 185–192 (2000)
Alici, G., Devaud, V., Renaud, P., Spinks, G.: Conducting polymer microactuators operating in air. J. Micromech. Microeng. 19, 025017 (2009)
Yan, B., Wu, Y., Gao, L.: Recent advances on polypyrrole electroactuators. Polymers 9, 446–466 (2017)
Tadesse, Y., Grange, R.W., Priyam, S.: Synthesis and cyclic force characterization of helical polypyrrole actuators for artificial facial muscles. Smart Mater. Struct. 18, 085008 (2009)
Aguilar-Hernandez, J., Potje-Kamloth, K.: Evaluation of the electrical conductivity of polypyrrole polymer composites. J. Appl. Phys. 34, 1700–1711 (2001)
Wu, Y., Alici, G., Spinks, G.M., Wallace, G.G.: Fast trilayer polypyrrole bending actuators for high speed applications. Synth. Met. 156, 1017–1022 (2006)
Ding, J., Liu, L., Spinks, G.M., Zhou, D., Wallace, G.G., Gillespie, J.: High performance conducting polymer actuators utilising a tubular geometry and helical wire interconnects. Synth. Met. 138, 391–398 (2003)
Osaka, L., McCullough, R.D.: Advances in molecular design and synthesis of regioregular polythiophenes. Acc. Chem. Res. 41, 1202–1214 (2008)
McCullough, R.D., Lowe, R.D.: Enhanced electrical conductivity in regioselectively synthesized poly(3-alkylthiophenes). J. Chem. Soc. Chem. Commun. 1, 70–72 (1992)
Loewe, R.S., Khersonsky, S.M., McCullough, R.D.: A simple method to prepare head-to-tail coupled, regioregular Poly(3-alkylthiophenes) using grignard metathesis. Adv. Mater. 11, 250–253 (1999)
Chen, T.A., Rieke, R.D.: The first regioregular head-to-tail poly(3-hexylthiophene-2,5-diyl) and a regiorandom isopolymer: nickel versus palladium catalysis of 2(5)-bromo-5(2)-(bromozincio)-3-hexylthiophene polymerization. J. Am. Chem. Soc. 114, 10087–10088 (1992)
Fuchiwaki, M., Takashima, W., Kaneto, K.: Soft actuators based on Poly(3-alkyl thiophene) films upon electrochemical oxidation and reduction. Mol. Cryst. Liq. Cryst. 374, 513–520 (2002)
Xi, B., Truong, V.T., Whitten, P.G., Ding, J., Spinks, G., Wallace, G.G.: Poly(3-methylthiophene) electrochemical actuators showing increased strain and work per cycle at higher operating stresses. Polymers 47, 7720–7725 (2006)
Thongbor, S., Pattavarakorn, D.: Electromechanical properties of electroactive polythiophene/elastomer blend. In: TIChE International Conference ms007 (2001)
Tttavarakorn, D., Youngta, P., Jaesrichai, S., Thongbor, S., Chaimongkol, P.: Electroactive performances of conductive polythiophene/hydrogel hybrid artificial muscle. Energy Procedia 34, 673–681 (2013)
Okuzaki, H., Suzuki, H., Ito, T.: Electrically driven PEDOT/PSS actuators. Synth. Met. 159, 2233–2236 (2009)
Okuzaki, H., Hosaka, K., Suzuki, H., Ito, T.: Effect of temperature on humido-sensitive conducting polymer actuators. Sens. Actuator A-Phys. 157, 96–99 (2010)
Ikushima, K., John, S., Ono, A., Nagamitsu, S.: PEDOT/PSS bending actuators for autofocus micro lens applications. Synth. Met. 160, 1877–1883 (2010)
Cho, M.S., Seo, H.J., Nam, J.D., Choi, H.R., Koo, J.C., Song, K.G., Lee, Y.: A solid state actuator based on the PEDOT/NBR system. Sens. Actuator B-Chem. 119, 621–624 (2006)
Farajollahi, M., Woehling, V., Plesse, C., Nguyen, G.T.M., Vidal, F., Sassani, F., Yang, V.X.D., Madden, J.D.W.: Self-contained tubular bending actuator driven by conducting polymers. Sens. Actuator A-Phys. 249, 45–56 (2016)
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Gendron, D. (2019). Conducting Polymer Based Ionic Polymer Metal Composite Actuators. In: Inamuddin, Asiri, A. (eds) Ionic Polymer Metal Composites for Sensors and Actuators. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-030-13728-1_3
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