Abstract
Sandalwood (Santalum album) oil is an important export commodity in many countries. It is important for the industry to have a capacity for rapid and accurate determination of oil content and quality for commercial samples. The effect of extraction methods (i.e., steam-distillation, hydro-distillation, subcritical CO2 extraction and solvent extraction) on the oil yield and concentration of major components in a commercial sample was reported. The highest oil yield was obtained from subcritical CO2 (3.83 g/L) extraction followed by the solvent extraction (2.45–3.7 g/L), hydrodistillations (1.86–2.68 g/L) and steam distillation (1.60 g/L). The highest levels of α- and β-santalol were found in the oils extracted with subcritical CO2 (83%), ethyl alcohol (84%) and steam distillation (84%). Organoleptic properties were remarkable in case of subcritical CO2. FTIR analysis has shown the sharp peaks for santalol and santalene in the oil extracted by subcritical CO2. Three of the four solvent-extracted sandalwood oils were recorded as ‘less pleasant’ indicating the generally inferior note of oil derived from these methods. Given the highest yield, the highest level of santalols, it could be concluded that subcritical CO2 is the best technology for sandalwood oil extraction.
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References
Alpha, T., Raharivelomanana, P., Bianchini, J. P., Faure, R., Cambon, A., & Joncheray, L. (1996). PF0807_Lawrence_fcx.indd 44 06/2/08 9:38:44 AM 47 Santalenes from Santalum austrocaledonicum. Phytochemistry, 41, 829–832.
Alpha, T., Raharivelomanana, P., Bianchini, J. P., Faure, R., & Cambon, A. (1997a). Sesquiterpenoid from Santalum austrocaledonicum. Phytochemistry, 46, 1237–1239.
Alpha, T., Raharivelomanana, T. P., Bianchini, J.P., Faure, R., & Cambon, A. (1997b). Identification de deux derives dihydoxyles du bisabolane a partir de Santals oceaniens. Rivista Ital. EPPOS, (Numero Speciale), 84–91.
Alpha, T., Raharivelomanana, T. P., Bianchini, J. P., Faure, R., & Cambon, A. (1997c). Identification de deux derives dihydoxyles du bisabolane a partir de Santals oceaniens. Rivista Ital. EPPOS, (Numero Speciale), 84–91.
Anon. (2006). Market overview the Australian Sandalwood Industry. Australian Agribusiness Group.
Anonis. (1998). Sandalwood and sandalwood compounds. Perfumer Flavorist, 23, 19.
Arctander, S. (1960a). Perfume and flavor materials of natural origin.
Arctander, S. (1960b). Sandalwood oil in East India. In Perfume and flavor materials of natural origin (pp. 574). Denmark. 12 D. P.
Askinson, G. (1915). Perfumes and cosmetics. London: Hodder & Stoughton.
AVONGRO. (2006). Wheatbelt tree cropping incorporated economic development and sustainable production. Sandalwood economics.
Brand, J. E., Fox, J. E. D., Pronk, G., & Cornwell, C. (2007). Comparison of oil concentration and oil quality from Santalum spicatum and S. album plantations, 8-25 years old, with those from mature S. spicatum natural stands. Australian Forestry, 70(4), 235–241.
Braun, N. A., et al. (2003). Isolation and chiral GC analysis of β-bisabolols-trace constituents from the essential oil of Santalum album L. Journal of Essential Oil Research, 15(2), 63–65.
Braun, N., Meier, M., & Hammer Schmidt, F. J. (2005). New Caledonium sandalwood oil-a substitute for East Indian sandalwood oil? Journal of Essential Oil Research, 17, 477–480. 150.
British Pharmaceutical Codex. (1949) (p. 612). The British Pharmaceutical Codex 1949. London: The Pharmaceutical Society.
Broadhurst, L., & Coates, D. (2002). Genetic diversity within and divergence between rare and geographically widespread taxa of the Acacia acuminata Benth. (Mimosaceae) complex. Heredity, 88, 250–257.
Brunke, E. J., Vollhardt, J., & Schmaus, G. (1995). Cyclosantalal and epicyclosantalal–new sesquiterpene aldehydes from East Indian sandalwood oil. Flavour and Fragrance Journal, 10, 211–219.
Brunke, E.J., Falbusch, K.G., Schmaus, G., & Volhardt, J. (1997). The chemistry of sandalwood fragrance—a review of the last 10 years. Rivista Ital. EPPOS, (Numero Speciale), 48–83.
Bryne, M., Macdonald, B., Broadhurst, L., & Brand, J. (2003a). Regional genetic differentiation in Western Australian sandalwood (Santalum spicatum) as revealed by nuclear RFLP analysis. Theoretical and Applied Genetics, 107, 1208–1214.
Bryne, M., Macdonald, B., & Brand, J. (2003b). Phylogeography and divergence in the chloroplast genome of Western Australian Sandalwood (Santalum spicatum). Heredity, 91, 389–395.
Burdock, G. A., & Carabin, I. G. (2008). Safety assessment of sandalwood oil (Santalum album L.). Food and Chemical Toxicology, 46(2), 421–432. https://doi.org/10.1016/j.fct.2007.09.092.
Chana, J. S. (1994). Sandalwood production. International Journal of Aromatherapy, 6(4), 11–13.
Chemat, F., Sahraoui, N., Abert-Vian, M., Bornard, I., & Boutekdjiret, C. (2008). Improved microwave steam distillation apparatus for isolation of essential oils comparison with conventional steam distillation. Journal of Chromatography A, 1210, 229–233.
Chen, Z. X., & Lin, L. (2001). Influences of various extraction methods on content and chemical components of volatile oil of Santalum album. Guangzhou Zhongyiyao Daxue Xuebao, 18(2), 174–177.
Coakley, T. (2006). Market update by Wescorp International. Avon Sandalwooder, Autumn 2006.
Coombs, A. J. (1995). Dictionary of plant names. Oregon: Timber Press.
Coppen, J. J. W. (1995). Sandalwood oil. In Non-wood forest products 1. Flavours and fragrances of plant origin (pp. 53–60). Rome: Food and Agricultural Organization of the United Nations.
Deite, D. C. (1892). A practical treatise on the manufacture of perfumery. Philadelphia: Henry Carey Baird & Co..
Ferhat, M. A., Chemat, F., Meklati, B. Y., & Smadja, J. (2006). An improved microwave Clevenger apparatus for distillation of essential oils from orange peel. Journal of Chromatography A, 1112, 21–126.
Food Chemicals Codex. (1981). 3rd edn, (p. 268). Washington DC: National Academy Press.
Forest Products Commission. (2007). Annual report 2006/07.
Gowda, V.S.V. (2013). Essential oil production under public sector, private partnership model, Essential oil http://www.ffdcindia.org/essential_oil_24july13.pdf.
Guenther, E. (1952). Oil of sandalwood East Indian. In The essential oils (Vol. 5, pp. 173–187). New York: Van Nostrand Co..
http://sandalwoodoilspecialist.com/sandalwood-oil/adulteration/.
http://www.fpc.wa.gov.au/. Preliminary oil results from a 14-year-old Indian Sandalwood (Santalum album) plantation at Kununurra, WA.
Hamilton, L Conrad, CE (Tech. Coords.) (1990) Proceedings of Symposium on Sandalwood in the Pacific, Honolulu, Hawaii, 9–11 April, 1990. USDA Forest Service, Pacific Southwest Research Station, General Technical Report PSW-122. 84 pp. Berkeley: USDA, PSRS.
Harman, A. (2015). Harvest to hydrosol. Fruitland: IAG Botanics.
Hettiarachchi, D. S. (2008). Volatile oil content determination in the Australian sandalwood industry: Towards a standardized method. Sandalwood Research Newsletter, 23, 1–4.
Hettiarachchi, D. S., Gamage, M., & Subasinghe, U. (2010). Oil content analysis of sandalwood: A novel approach for core sample analysis. Sandalwood Research Newsletter, 25, 1–4.
International Organization for Standardisation (1976) Oil of Sandalwood (Santalum album L.) ISO 3793.
International Organization for Standardisation. (1979). Oil of sandalwood (Santalum album Linnaeus) International Standard ISO 3518-1979 (E). 1st edn, 2 pp. International Organization for Standardization.
International Organization for Standardisation (2002) Oil of Sandalwood (Santalum album L). 2nd edn, ISO 3518.
Jaramillo, B. E., & Martinez, J. R. (2004). Comparison of different extraction methods for the analysis of volatile secondary metabolites of Lippia Alba (Mill.) N.E. Brown, Grown in Colombia, and evaluation of its in vitro antioxidant activity. Journal of Chromatography A, 1025, 93–103.
Jones, P. (2002). Estimating returns on plantation grown Sandalwood (Santalum spicatum). Sandalwood Information Sheet Issue 3. Forest Products Commission.
Jones, C. G., Plummer, J. A., & Barbour, E. L. (2007). Non-destructive sampling of Indian sandalwood (Santalum album L.) for oil content and composition. Journal of Essential Oil Research, 19(2), 157–164. https://doi.org/10.1080/10412905.2007.9699250.
Krotz, A., & Helmchen, G. (1994). Total syntheses, optical rotations and fragrance properties of sandalwood constituents: (-)-(Z) - and (-)-(E)-β-Santalol and their enantiomers, ent-β-Santalene. Liebigs Annalen der Chemie, 1994(6), 601–609. https://doi.org/10.1002/jlac.199419940610.
Kuriakoje, S., Thankappan, X., & Venkatraman, V. (2010). Detection and quantification of adulteration in sandalwood oil through near infrared spectroscopy. The Analysts Journal, 135(10), 2676–2681. https://doi.org/10.1039/c0an00261e.
Kusuma, H. S., & Mahfud, M. (2016). Kinetic studies on extraction of essential oil from sandalwood (Santalum album) by microwave air-hydro distillation method. AIP Conference Proceedings, 1755, 050001-1–050001-6. https://doi.org/10.1063/1.4958484.
Kusuma, H. S., & Mahfud, M. (2017). Kinetic studies on extraction of essential oil from sandalwood (Santalum album) by microwave air-hydro distillation method. Alexandria Engineering Journal. https://doi.org/10.1016/j.aej.2017.02.007, in press.
Lawrence, B. M. (1991). Sandalwood oil in progress in essential oils. Perfumer & Flavorist, 1(1), 5(1976); 1(5), 14(1976); 6(5), 32–34(1981); 16(6), 50–52.
Lawrence, B. M. (2009). A preliminary report on the world production of some selected essential oils and countries. Perfumer and Flavorist, 34(1), 38–44. Sandalwood Essential Oil, http://scienceofacne.com/sandalwood-essential-oil/.
Marongiu, B., Piras, A., Porcedda, S., & Tuveri, E. (2006). Extraction of Santalum album and Boswellia carterii Birdw volatile oil by supercritical carbon dioxide: Influence of some process parameters. Flavour and Fragance Journal, 21(4), 718–724.
McKinnell, F. H. (Ed.). (1993). Proceedings of symposium on sandalwood in the Pacific region held at XVII Pacific science congress, Honolulu, Hawaii, 2 June, 1991 (ACIAR Proceedings No. 49. 43 pp). Canberra: ACIAR.
McKinnell, F. H. (2008). WA sandalwood industry development plan 2008–2020. Perth: Forest Products Commission.
Mookherjee, B. D., Trenkle, R. W., & Wilson, R. A. (1992). New insights in the three most important natural fragrance products: Wood, amber and musk. In H. Woidich & G. Buchbauer (Eds.), Proceedings of the 12th International Congress of Flavours, Fragrances and Essential Oils, Oct 4-8 1992 (pp. 234–262). Vienna: Austrian Assoc. Flav. Frag. Industry.
Moretta, P., Ghisalbert, E. L., Piggott, M. J., & Trengove, R. D. (1998a). Extraction of oil from Santalum spicatum by supercritical fluid extraction. ACIAR Proceedings Series, 84, 83–85.
Moretta, P., Ghisalbert, E. L., Piggott, M. J., & Trengove, R. D. (1998b). ACIAR Proceedings Series, 84, 83.
Nautiyal, O. H. (2010). Oil extraction methods in Santalum album. Sandalwood Research Newsletter, 25, 5–7.
Nautiyal, O. H. (2011). Analytical and Fourier transform infra red spectroscopy evaluation of sandalwood oil extracted with various process techniques. Journal of Natural Products, 4(2011), 150–157.
Nautiyal, O. H. (2014). Process optimization of sandalwood (Santalum album) oil extraction by subcritical carbon dioxide and conventional technique. Indian Journal of Chemical Technology, 21, 290–297.
Nayar, R. (1988). Cultivation, improvement, exploitation and protection of Santalum album Linn. Advances in Forestry Research in India, 2, 117–151.
Nicolas, B., Céline, D., & Daniel, J. (2011). Phytochemistry of the heartwood from fragrant Santalum species: A review. Flavour and Fragrance Journal, 26(1), 7–26.
Nikiforov, A. L. J., Buchbauer, G., & Raverdino, V. (1988). GC-FTIR and GC-MS in odour analysis of essential oils. Mikrochimica Acta (Vienna), 11, 193–198.
Ochi, T., Shibata, H., Higuti, T., Kodama, K. H., Kusumi, T., & Takaishi, Y. (2005). Anti-Helicobacter pylori compounds from Santalum album. Journal of Natural Products, 68(6), 819–824. https://doi.org/10.1021/np040188q.
Paulpandi, M., Kannan, S., Thangam, R., Kaver, K., Gunasekaran, P., & Rejeeth, C. (2012). In vitro anti-viral effect of β-santalol against influenza viral replication. Phytomedicine, 19(3–4), 231–235. https://doi.org/10.1016/j.phymed.2011.11.006.
Rozzi, N. L., & Singh, R. K. (2002). Comprehensive Reviews in Food Science and Food Safety, 1, 33.
Schnitzler, P., Koch, C., & Reichling, J. (2007). Susceptibility of drug-resistant clinical herpes simplex virus type 1 strains to essential oils of ginger, thyme, hyssop, and sandalwood. Antimicrobial Agents and Chemotherapy, 51(5), 1859–1862. https://doi.org/10.1128/AAC.00426-06.
Sen-Sarma, P. K. (1982). Sandalwood – its cultivation and utilization. In C. K. Atal & B. M. Kapur (Eds.),. 815 pp Cultivation and utilization of aromatic plants (pp. 395–405). Jammu: Regional Research Laboratory, CSIR.
Shankarnarayana, K. H., & Parthsarathi, K. (1984). Compositional differences in sandal oils from young and mature trees and in the sandal oils undergoing colour change on standing. Indian Perfumer, 28(3/4), 138–141.
Shukla, B. V., Mohod, R., Shukla, S. V., Lehri, A., & Singh, D. P. (1999). Quality assessment of sandalwood oil using gas chromatograph. FAFAI Journal, 1(3), 41–43.
Skerget, M., & Knez, Z. (1997). Journal of Agricultural and Food Chemistry, 45, 2066.
Statham, P. (1990). The sandalwood industry in Australia: a history. In Proceedings of Symposium on Sandalwood in the Pacific, Honolulu, Hawaii, 9–11 April, 1990. USDA Forest Service, Pacific Southwest Research Station, General Technical Report PSW-122 (pp. 26–38). Berkeley: USDA, PSRS.
Suriamihardja, S. (1978). [Problems on sandalwood (Santalum album Linn.) silviculture and improving its production]. In Proceedings of the Third Seminar on Volatile Oils, Bogor, Indonesia, July, 1978 (pp. 115–125) Bogor: Balai Penelitian Kimia.
U.S. Dispensatory (1955) sanadalwood oil is a volatile oil obtained by steam distillation. Lippincott, Philadephia 25th edn, p. 1836.
Venkatesha Gowda, V. S., Patil, K. B., & Perumal, I. R. (2006). Forest based essential oils viz sandalwood oil production and future scenario. Indian Perfum, 50, 45–50; PAFAI, 8(1), 63–70.
Verghese, J., Sunny, T. P., & Balkrishanan, K. V. (1990). (+)-α-santalol and (−)-β-santalol (Z) concentration, a new quality determinant of East Indian sandalwood oil. Flavour and Fragrance Journal, 5, 223–226.
Warnke, P. H., Becker, S. T., Podschun, R., Sivananthan, S., Springer, I. N., Russo, P. A. J., Wiltfang, J., Fickenscher, H., & Sherry, E. (2009). The battle against multi-resistant strains: Renaissance of antimicrobial essential oils as a promising force to fight hospital-acquired infections. Journal of Carnio Maxillo Facial Surgery, 37(7), 392–397. https://doi.org/10.1016/j.jcms.2009.03.017.
Wei, M., Lin, L., Qiu, J. Y., Cai, Y. W., Lu, A., Yuan, L., Liao, H. F., & Xiao, S. G. (2000). Wind damage effects on quality of hardwood of Lignum santal; albi. Zhongguo Zhongyao Zazhi, 25, 710–713.
Wood, A. (2008). Pathogen of the month – January 2008. South Africa: Australasian Plant Pathology Society (APPS).
Yadav, V. G. (1993). Sandalwood: Its origin, synthetic substitutes and structure-odour relationship. PAFAI Journal, 15(4), 21–54.
Zhu, L. F., Li, Y. H., Li, B. L., Lu, B. Y., & Xia, N. H. (1993). Aromatic plants and essential constituents (p. 60). Hong Kong: South China Institute of Botany, Chinese Academy of Sciences, Hai Feng Publish.. distributed by Peace Book Co. Ltd..
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Nautiyal, O.H. (2019). Sandalwood (Santalum album) Oil. In: Ramadan, M. (eds) Fruit Oils: Chemistry and Functionality. Springer, Cham. https://doi.org/10.1007/978-3-030-12473-1_38
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