Abstract
Nanoscale composite materials have played a significant role in sensing of gases, owing to their high surface area, higher mechanical strength with efficient chemical activity as well as cost effective nature. The present chapter deals with synthesis and characterization of Polyaniline (PANI) based nanocomposites ion-exchanger and nanomaterials in addition to their sensing applications in various fields. These nanomaterials have been explored on the basis of advanced techniques of characterizations. Besides the sensing materials, on the basis of ion uptake capacity, these nanocomposite ion-exchange materials can also be used for the treatment of meal ions from industrial wastewaters. This chapter mainly focuses on the synthesis of PANI based nanocomposites and their applications as gas sensors and biosensors. The PANI nanomaterials demonstrated impressive results and outstanding sensing behaviour. It has been found that PANI based nanocomposite materials are not only used for the detection of toxic gases, but, these materials also facilitated immobilization of bioreceptors (e.g., enzymes, antigen–antibodies, and nucleic acids, etc.) for the exposure of biological agents through a combination of biochemical and electrochemical reactions. In future, PANI based nanocomposite materials are expected to open new approaches for demonstrating their outstanding applications in diverse fields.
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References
Abdulla S, Mathew TL, Pullithadathil B (2015) Highly sensitive, room temperature gas sensor based on polyaniline-multiwalled carbon nanotubes (PANI/MWCNTs) nanocomposite for trace-level ammonia detection. Sensors Actuators B Chem 221:1523–1534
Adams P et al (1996) Low temperature synthesis of high molecular weight polyaniline. Polymer 37(15):3411–3417
Ampuero S, Bosset J (2003) The electronic nose applied to dairy products: a review. Sensors Actuators B Chem 94(1):1–12
Ansari MO, Mohammad F (2011) Thermal stability, electrical conductivity and ammonia sensing studies on p-toluenesulfonic acid doped polyaniline: titanium dioxide (pTSA/Pani: TiO2) nanocomposites. Sensors Actuators B Chem 157(1):122–129
Ansari MO et al (2013) Thermal stability in terms of DC electrical conductivity retention and the efficacy of mixing technique in the preparation of nanocomposites of graphene/polyaniline over the carbon nanotubes/polyaniline. Compos Part B 47:155–161
Ansari MO et al (2014) Ammonia vapor sensing and electrical properties of fibrous multi-walled carbon nanotube/polyaniline nanocomposites prepared in presence of cetyl-trimethylammonium bromide. J Ind Eng Chem 20(4):2010–2017
Arrad O, Sasson Y (1989) Commercial ion exchange resins as catalysts in solid-solid-liquid reactions. J Org Chem 54(21):4993–4998
Arsat R et al (2011) Hydrogen gas sensor based on highly ordered polyaniline/multiwall carbon nanotubes composite. Sens Lett 9(2):940–943
Athawale AA, Kulkarni MV (2000) Polyaniline and its substituted derivatives as sensor for aliphatic alcohols. Sensors Actuators B Chem 67(1):173–177
Athawale AA, Bhagwat S, Katre PP (2006) Nanocomposite of Pd–polyaniline as a selective methanol sensor. Sensors Actuators B Chem 114(1):263–267
Ayad MM, El-Hefnawey G, Torad NL (2009) A sensor of alcohol vapours based on thin polyaniline base film and quartz crystal microbalance. J Hazard Mater 168(1):85–88
Azim-Araghi M, Jafari M (2010) Electrical and gas sensing properties of polyaniline-chloroaluminium phthalocyanine composite thin films. Eur Phys J Appl Phys 52(01):10402
Baraton M-I (2008) Sensors for environment, health and security: advanced materials and technologies. Springer, Dordrecht
Bo Y et al (2011) A novel electrochemical DNA biosensor based on graphene and polyaniline nanowires. Electrochim Acta 56(6):2676–2681
Bushra R et al (2014) Synthesis, characterization, antimicrobial activity and applications of polyanilineTi (IV) arsenophosphate adsorbent for the analysis of organic and inorganic pollutants. J Hazard Mater 264:481–489
Castro M et al (2009) Carbon nanotubes/poly (ε-caprolactone) composite vapour sensors. Carbon 47(8):1930–1942
Cavallo P et al (2015) Understanding the sensing mechanism of polyaniline resistive sensors. Effect of humidity on sensing of organic volatiles. Sensors Actuators B Chem 210:574–580
Chaudhary V, Kaur A (2015) Enhanced room temperature sulfur dioxide sensing behaviour of in situ polymerized polyaniline–tungsten oxide nanocomposite possessing honeycomb morphology. RSC Adv 5(90):73535–73544
Choudhury A (2009) Polyaniline/silver nanocomposites: dielectric properties and ethanol vapour sensitivity. Sensors Actuators B Chem 138(1):318–325
Clark LC, Lyons C (1962) Electrode systems for continuous monitoring in cardiovascular surgery. Ann N Y Acad Sci 102(1):29–45
Conn C et al (1998) A polyaniline-based selective hydrogen sensor. Electroanalysis 10(16):1137–1141
Crowley K et al (2010) Fabrication of polyaniline-based gas sensors using piezoelectric inkjet and screen printing for the detection of hydrogen sulfide. Sens J IEEE 10(9):1419–1426
Deshpande N et al (2009) Studies on tin oxide-intercalated polyaniline nanocomposite for ammonia gas sensing applications. Sensors Actuators B Chem 138(1):76–84
Dey A et al (2012) Mediator free highly sensitive polyaniline–gold hybrid nanocomposite based immunosensor for prostate-specific antigen (PSA) detection. J Mater Chem 22(29):14763–14772
Dhand C et al (2011) Recent advances in polyaniline based biosensors. Biosens Bioelectron 26(6):2811–2821
Dhawale D et al (2008) Room temperature liquefied petroleum gas (LPG) sensor based on p-polyaniline/n-TiO2 heterojunction. Sensors Actuators B Chem 134(2):988–992
Dhawale D et al (2010a) Room temperature LPG sensor based on n-CdS/p-polyaniline heterojunction. Sensors Actuators B Chem 145(1):205–210
Dhawale D et al (2010b) Room temperature liquefied petroleum gas (LPG) sensor. Sensors Actuators B Chem 147(2):488–494
Dhingra M et al (2013) Impact of interfacial interactions on optical and ammonia sensing in zinc oxide/polyaniline structures. Bull Mater Sci 36(4):647–652
Di W, Ivaska A (2006) Electrochemical biosensors based on polyaniline. Chem Anal 51(6):839–852
Diggikar RS et al (2013) Formation of multifunctional nanocomposites with ultrathin layers of polyaniline (PANI) on silver vanadium oxide (SVO) nanospheres by in situ polymerization. J Mater Chem A 1(12):3992–4001
Dimitriev O (2003) Interaction of polyaniline and transition metal salts: formation of macromolecular complexes. Polym Bull 50(1–2):83–90
Docquier N, Candel S (2002) Combustion control and sensors: a review. Prog Energy Combust Sci 28(2):107–150
Du M et al (2012) Fabrication of DNA/graphene/polyaniline nanocomplex for label-free voltammetric detection of DNA hybridization. Talanta 88:439–444
Dubbe A (2003) Fundamentals of solid state ionic micro gas sensors. Sensors Actuators B Chem 88(2):138–148
Feng J, MacDiarmid A (1999) Sensors using octaaniline for volatile organic compounds. Synth Met 102(1):1304–1305
Fu L, Yu A (2014) Carbon nanotubes based thin films: fabrication, characterization and applications. Rev Adv Mater Sci 36:40–61
Fuke MV et al (2008) Evaluation of co-polyaniline nanocomposite thin films as humidity sensor. Talanta 76(5):1035–1040
Fuke MV et al (2009) Ag-polyaniline nanocomposite cladded planar optical waveguide based humidity sensor. J Mater Sci Mater Electron 20(8):695–703
Gangopadhyay R, De A (2000) Conducting polymer nanocomposites: a brief overview. Chem Mater 12(3):608–622
Genies E et al (1990) Polyaniline: a historical survey. Synth Met 36(2):139–182
Gopalan AI et al (2009) An electrochemical glucose biosensor exploiting a polyaniline grafted multiwalled carbon nanotube/perfluorosulfonate ionomer–silica nanocomposite. Biomaterials 30(30):5999–6005
Hasan M et al (2015) Ammonia sensing and DC electrical conductivity studies of p-toluene sulfonic acid doped cetyltrimethylammonium bromide assisted V2O5@ polyaniline composite nanofibers. J Ind Eng Chem 22:147–152
Hoa D et al (1992) A biosensor based on conducting polymers. Anal Chem 64(21):2645–2646
Hsu YF et al (2008) Undoped p-type ZnO Nanorods synthesized by a hydrothermal method. Adv Funct Mater 18(7):1020–1030
Hu H et al (2002) Adsorption kinetics of optochemical NH 3 gas sensing with semiconductor polyaniline films. Sensors Actuators B Chem 82(1):14–23
Huang W-S, Humphrey BD, MacDiarmid AG (1986) Polyaniline, a novel conducting polymer. Morphology and chemistry of its oxidation and reduction in aqueous electrolytes. J Chem Soc Faraday Trans 82(8):2385–2400
Huang J et al (2011) Electrochemical immunosensor based on polyaniline/poly (acrylic acid) and Au-hybrid graphene nanocomposite for sensitivity enhanced detection of salbutamol. Food Res Int 44(1):92–97
Imisides M, John R, Wallace G (1996) Microsensors based on conducting polymers. ChemTech 26(5):19–25
Jain S et al (2003) Humidity sensing with weak acid-doped polyaniline and its composites. Sensors Actuators B Chem 96(1):124–129
Joshi S, Lokhande C, Han S-H (2007) A room temperature liquefied petroleum gas sensor based on all-electrodeposited n-CdSe/p-polyaniline junction. Sensors Actuators B Chem 123(1):240–245
Kaur B, Srivastava R (2015) Simultaneous determination of epinephrine, paracetamol, and folic acid using transition metal ion-exchanged polyaniline–zeolite organic–inorganic hybrid materials. Sensors Actuators B Chem 211:476–488
Khan AA (2006) Applications of Hg (II) sensitive polyaniline Sn (IV) phosphate composite cation-exchange material in determination of Hg2+ from aqueous solutions and in making ion-selective membrane electrode. Sensors Actuators B Chem 120(1):10–18
Khan AA, Baig U (2013a) Electrical conductivity and ammonia sensing studies on in situ polymerized poly (3-methythiophene)–titanium (IV) molybdophosphate cation exchange nanocomposite. Sensors Actuators B Chem 177:1089–1097
Khan AA, Baig U (2013b) Electrical conductivity and humidity sensing studies on synthetic organic–inorganic poly-o-toluidine–titanium (IV) phosphate cation exchange nanocomposite. Solid State Sci 15:47–52
Khan AA, Khalid M, Niwas R (2010a) Humidity and ammonia vapor sensing applications of polyaniline–polyacrylonitrile composite films. Sci Adv Mater 2(4):474–480
Khan AA, Khalid M, Baig U (2010b) Synthesis and characterization of polyaniline–titanium (IV) phosphate cation exchange composite: methanol sensor and isothermal stability in terms of DC electrical conductivity. React Funct Polym 70(10):849–855
Khan AA, Baig U, Khalid M (2011) Ammonia vapor sensing properties of polyaniline–titanium (IV) phosphate cation exchange nanocomposite. J Hazard Mater 186(2):2037–2042
Khan AA, Baig U, Khalid M (2013a) Electrically conductive polyaniline-titanium (IV) molybdophosphate cation exchange nanocomposite: synthesis, characterization and alcohol vapour sensing properties. J Ind Eng Chem 19(4):1226–1233
Khan AA et al (2013b) Ion-exchange and humidity sensing properties of poly-o-anisidine sn (IV) arsenophosphate nano-composite cation-exchanger. J Environ Chem Eng 1(3):310–319
Khuspe G et al (2013) Ammonia gas sensing properties of CSA doped PANi-SnO2 nanohybrid thin films. Synth Met 185:1–8
Kim I et al (2010) Gas sensor for CO and NH 3 using polyaniline/CNTs composite at room temperature. In: Nanotechnology (IEEE-NANO), 10th IEEE conference on 2010, IEEE
Koul S, Chandra R (2005) Mixed dopant conducting polyaniline reusable blend for the detection of aqueous ammonia. Sensors Actuators B Chem 104(1):57–67
Le TH et al (2013) Electrosynthesis of polyaniline–mutilwalled carbon nanotube nanocomposite films in the presence of sodium dodecyl sulfate for glucose biosensing. Adv Nat Sci Nanosci Nanotechnol 4(2):025014
Li Z-F et al (2013a) Understanding the response of nanostructured polyaniline gas sensors. Sensors Actuators B Chem 183:419–427
Li J et al (2013b) Electrochemical immunosensor based on graphene–polyaniline composites and carboxylated graphene oxide for estradiol detection. Sensors Actuators B Chem 188:99–105
Lin M et al (2012) Electrochemical immunoassay of benzo [a] pyrene based on dual amplification strategy of electron-accelerated Fe3O4/polyaniline platform and multi-enzyme-functionalized carbon sphere label. Anal Chim Acta 722:100–106
Liu P-Z et al (2013) Electrochemiluminescence immunosensor based on graphene oxide nanosheets/polyaniline nanowires/CdSe quantum dots nanocomposites for ultrasensitive determination of human interleukin-6. Electrochim Acta 113:176–180
Lowe CR (1984) Biosensors. Trends Biotechnol 2(3):59–65
Malinauskas A et al (2004) Electrochemical response of ascorbic acid at conducting and electrogenerated polymer modified electrodes for electroanalytical applications: a review. Talanta 64(1):121–129
Matsuguchi M et al (2002) Effect of NH 3 gas on the electrical conductivity of polyaniline blend films. Synth Met 128(1):15–19
Muhammad-Tahir Z, Alocilja EC (2003) A conductometric biosensor for biosecurity. Biosens Bioelectron 18(5):813–819
Nabi S et al (2010) Development of composite ion-exchange adsorbent for pollutants removal from environmental wastes. Chem Eng J 165(2):405–412
Nabi S et al (2011a) Synthesis and characterization of nano-composite ion-exchanger; its adsorption behavior. Colloids Surf B: Biointerfaces 87(1):122–128
Nabi S et al (2011b) Heavy-metals separation from industrial effluent, natural water as well as from synthetic mixture using synthesized novel composite adsorbent. Chem Eng J 175:8–16
Nabi S et al (2011c) Synthesis and characterization of polyanilineZr (IV) sulphosalicylate composite and its applications (1) electrical conductivity, and (2) antimicrobial activity studies. Chem Eng J 173(3):706–714
Navale S et al (2014) Camphor sulfonic acid doped PPy/α-Fe2O3 hybrid nanocomposites as NO2 sensors. RSC Adv 4(53):27998–28004
Novák P et al (1997) Electrochemically active polymers for rechargeable batteries. Chem Rev 97(1):207–282
Ozdemir C et al (2010) Electrochemical glucose biosensing by pyranose oxidase immobilized in gold nanoparticle-polyaniline/AgCl/gelatin nanocomposite matrix. Food Chem 119(1):380–385
Parvatikar N et al (2006) Electrical and humidity sensing properties of polyaniline/WO3 composites. Sensors Actuators B Chem 114(2):599–603
Patil S et al (2011) Fabrication of polyaniline-ZnO nanocomposite gas sensor. Sens Transducer 134(11):120
Pawar S et al (2011) Fabrication of polyaniline/TiO2 nanocomposite ammonia vapor sensor. J Nano Electron Phys 3(1):1056
Prabhakar N et al (2008) Improved electrochemical nucleic acid biosensor based on polyaniline-polyvinyl sulphonate. Electrochim Acta 53(12):4344–4350
Prathap MA, Srivastava R, Satpati B (2013) Simultaneous detection of guanine, adenine, thymine, and cytosine at polyaniline/MnO2 modified electrode. Electrochim Acta 114:285–295
Radhakrishnan S et al (2013) Polypyrrole nanotubes–polyaniline composite for DNA detection using methylene blue as intercalator. Anal Methods 5(4):1010–1015
Raj AD et al (2010) Self assembled V2O5 nanorods for gas sensors. Curr Appl Phys 10(2):531–537
Ram MK, Yavuz O, Aldissi M (2005a) NO2 gas sensing based on ordered ultrathin films of conducting polymer and its nanocomposite. Synth Met 151(1):77–84
Ram MK et al (2005b) CO gas sensing from ultrathin nano-composite conducting polymer film. Sensors Actuators B Chem 106(2):750–757
Raman NK, Anderson MT, Brinker CJ (1996) Template-based approaches to the preparation of amorphous, nanoporous silicas. Chem Mater 8(8):1682–1701
Raut B et al (2012) Novel method for fabrication of polyaniline–CdS sensor for H2S gas detection. Measurement 45(1):94–100
Riegel J, Neumann H, Wiedenmann H-M (2002) Exhaust gas sensors for automotive emission control. Solid State Ionics 152:783–800
Rujisamphan N et al (2016) Co-sputtered metal and polymer nanocomposite films and their electrical responses for gas sensing application. Appl Surf Sci 368:114–121
Sadek A et al (2006) A layered surface acoustic wave gas sensor based on a polyaniline/In2O3 nanofibre composite. Nanotechnology 17(17):4488
Sadek A et al (2008) A polyaniline/WO3 nanofiber composite-based ZnO/64 YX LiNbO3 SAW hydrogen gas sensor. Synth Met 158(1):29–32
Sajjan K et al (2013) Humidity sensing property of polyaniline-cromium oxide nanocomposites. In: Proceeding of international conference on recent trends in applied physics and material science: RAM 2013, AIP Publishing
Santhanam K, Gupta N (1993) Conducting-polymer electrodes in batteries. TRIP 1:284–289
Sarfraz J et al (2013) Printed hydrogen sulfide gas sensor on paper substrate based on polyaniline composite. Thin Solid Films 534:621–628
Sen T et al (2014) Polyaniline/γ-Fe2O3 nanocomposite for room temperature LPG sensing. Sensors Actuators B Chem 190:120–126
Shahadat M et al (2012) Synthesis, characterization, photolytic degradation, electrical conductivity and applications of a nanocomposite adsorbent for the treatment of pollutants. RSC Adv 2(18):7207–7220
Shahadat M et al (2015) Titanium-based nanocomposite materials: a review of recent advances and perspectives. Colloids Surf B: Biointerfaces 126:121–137
Shahadat M et al (2017) A critical review on the prospect of polyaniline-grafted biodegradable nanocomposite. Adv Colloid Interf Sci 249:2–16
Sharma S et al (2002) Chloroform vapour sensor based on copper/polyaniline nanocomposite. Sensors Actuators B Chem 85(1):131–136
Shirsat MD et al (2009) Polyaniline nanowires-gold nanoparticles hybrid network based chemiresistive hydrogen sulfide sensor. Appl Phys Lett 94(8):083502
Shukla S et al (2012) Fabrication of electro-chemical humidity sensor based on zinc oxide/polyaniline nanocomposites. Adv Mater Lett 3(5):421–425
Singh V et al (2008) Synthesis and characterization of polyaniline–carboxylated PVC composites: application in development of ammonia sensor. Sensors Actuators B Chem 132(1):99–106
Singla M, Awasthi S, Srivastava A (2007) Humidity sensing; using polyaniline/Mn3O4 composite doped with organic/inorganic acids. Sensors Actuators B Chem 127(2):580–585
Spain E et al (2011) High sensitivity DNA detection using gold nanoparticle functionalised polyaniline nanofibres. Biosens Bioelectron 26(5):2613–2618
Spain E, Keyes TE, Forster RJ (2013) Vapour phase polymerised polyaniline–gold nanoparticle composites for DNA detection. J Electroanal Chem 711:38–44
Srivastava S et al (2010) TiO2/PANI And MWNT/PANI composites thin films For hydrogen gas sensing. In: AIP conference proceedings
Sun X, Qiao L, Wang X (2013) A novel immunosensor based on Au nanoparticles and polyaniline/multiwall carbon nanotubes/chitosan nanocomposite film functionalized interface. Nano-Micro Lett 5(3):191–201
Sutar D et al (2007) Preparation of nanofibrous polyaniline films and their application as ammonia gas sensor. Sensors Actuators B Chem 128(1):286–292
Syed AA, Dinesan MK (1991) Review: polyaniline – a novel polymeric material. Talanta 38(8):815–837
Tai H et al (2007) Fabrication and gas sensitivity of polyaniline–titanium dioxide nanocomposite thin film. Sensors Actuators B Chem 125(2):644–650
Tovide O et al (2014) Graphenated polyaniline-doped tungsten oxide nanocomposite sensor for real time determination of phenanthrene. Electrochim Acta 128:138–148
Vatutsina O et al (2007) A new hybrid (polymer/inorganic) fibrous sorbent for arsenic removal from drinking water. React Funct Polym 67(3):184–201
Verma SK et al (2015) Poly (m-aminophenol)/functionalized multi-walled carbon nanotube nanocomposite based alcohol sensors. Sensors Actuators B Chem 219:199–208
Vijayan A et al (2008) Optical fibre based humidity sensor using co-polyaniline clad. Sensors Actuators B Chem 129(1):106–112
Wang X et al (2012) Synthesis of nestlike ZnO hierarchically porous structures and analysis of their gas sensing properties. ACS Appl Mater Interfaces 4(2):817–825
Wang L et al (2014) Graphene sheets, polyaniline and AuNPs based DNA sensor for electrochemical determination of BCR/ABL fusion gene with functional hairpin probe. Biosens Bioelectron 51:201–207
Wilson J et al (2012) Polypyrrole–polyaniline–Au (PPy–PANi–Au) nano composite films for label-free electrochemical DNA sensing. Sensors Actuators B Chem 171:216–222
Wu J et al (2005) A biosensor monitoring DNA hybridization based on polyaniline intercalated graphite oxide nanocomposite. Sensors Actuators B Chem 104(1):43–49
Xian Y et al (2006) Glucose biosensor based on Au nanoparticles–conductive polyaniline nanocomposite. Biosens Bioelectron 21(10):1996–2000
Xu D-M et al (2013a) Multilayer films of layered double hydroxide/polyaniline and their ammonia sensing behavior. J Hazard Mater 262:64–70
Xu H et al (2013b) NO 2 gas sensing with SnO 2–ZnO/PANI composite thick film fabricated from porous nanosolid. Sensors Actuators B Chem 176:166–173
Yan X et al (2009) Preparation and characterization of polyaniline/indium (III) oxide (PANi/In2O3) nanocomposite thin film. In: 4th international symposium on advanced optical manufacturing and testing technologies: advanced optical manufacturing technologies. International Society for Optics and Photonics
Yang T et al (2009) Synergistically improved sensitivity for the detection of specific DNA sequences using polyaniline nanofibers and multi-walled carbon nanotubes composites. Biosens Bioelectron 24(7):2165–2170
Yang J, Wang X, Shi H (2012) An electrochemical DNA biosensor for highly sensitive detection of phosphinothricin acetyltransferase gene sequence based on polyaniline-(mesoporous nanozirconia)/poly-tyrosine film. Sensors Actuators B Chem 162(1):178–183
Yun J, Jeon S, Kim H-I (2013) Improvement of NO gas sensing properties of polyaniline/MWCNT composite by photocatalytic effect of TiO2. J Nanomater 2013:3
Zhang H-D et al (2014) High-sensitivity gas sensors based on arranged polyaniline/PMMA composite fibers. Sensors Actuators A Phys 219:123–127
Zhihua L et al (2016) Fast response ammonia sensor based on porous thin film of polyaniline/sulfonated nickel phthalocyanine composites. Sensors Actuators B Chem 226:553–562
Zhong H et al (2011) In situ chemo-synthesized multi-wall carbon nanotube-conductive polyaniline nanocomposites: characterization and application for a glucose amperometric biosensor. Talanta 85(1):104–111
Zhu J et al (2015) Preparation of polyaniline–TiO2 nanotube composite for the development of electrochemical biosensors. Sensors Actuators B Chem 221:450–457
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The authors would like to express their appreciations to Science and Engineering Research Board (DST) fast tract young scientist scheme (SB/FT/CS-122/2014) for providing Postdoctoral Fellowship to Mohammad Shahadat.
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Shahadat, M., Oves, M., Shalla, A.H., Ahammad, S.Z., Wazed Ali, S., Sreekrishnan, T.R. (2020). Fabrication of Polyaniline Supported Nanocomposites and Their Sensing Application for Detection of Environmental Pollutants. In: Oves, M., Ansari, M., Zain Khan, M., Shahadat, M., M.I. Ismail, I. (eds) Modern Age Waste Water Problems . Springer, Cham. https://doi.org/10.1007/978-3-030-08283-3_6
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