Abstract
Excessive growth and rapid development put a huge burden on the environment and the large fraction of water bodies getting polluted through industries. Though one third part of the earth contain water, but still there is a crises of water for drinking and other purposes. These water contaminants, contain many harmful and toxic metals, dyes, drugs, pesticides etc. Polluted water can be treated by numerous methods to make it fit for the drinking purpose. Chitosan being the most abundant biodegradable and cationic polymer can be effectively used for the treatment of wastewater for the removal of toxic and hazardous contaminants, heavy metals and other impurities present in water. Chitosan with characteristic functional groups such as amino and hydroxyl group can also be useful for the treatment of water as an adsorbent. Chitosan being the environmental friendly, cost effective and non toxic in nature is also applied for the purpose of treatment of water through adsorption, chelation, precipitation, ion exchange techniques etc. Nanoparticle doped with chitosan in the form of bionanocomposites has been a very successful tool for the removal of pollutants from the water. Wastewater contains different types of metal ions, toxic substance,and different pH i.e. alkaline as well as acidic nature. Chitosan in the acidic media is very helpful as the amino functional group can easily be protonated in acidic media to bind with the anionic part of the organic pollutants.
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References
Adewuyi S, Jacob JM, Olaleye O, Abdulraheem TO, Tayo JA, Oladoyinbo F (2016) Chitosan-bound pyridinedicarboxylate Ni(II) and Fe(III) complex biopolymer films as waste water decyanidation agents. Carbohydr Polym 151:1235–1239
Ali I (2012) New generation adsorbents for water treatment. Chem Rev 112:5073–5091
Ali I, Gupta VK (2007) Advances in water treatment by adsorption technology. Nat Protoc 1:2661–2667
Amin MT, Alazba AA, Manzoor U (2014) A review of removal of pollutants from water/wastewater using different types of nanomaterials. Adv Mater Sci Eng 2014:1–24
Assaad E, Azzouz A, Nistor D, Ursu AV, Sajin T, Miron DN (2007) Metal removal through synergic coagulation–flocculation using an optimised chitosan-montmorillonite system. Appl Clay Sci 37:258–274
Bhatnagar A, Sillanpaa A (2009) Applications of chitin- and chitosan-derivatives for the detoxification of water and wastewater – a short review. Adv Colloid Interface Sci 152(2009):26–38
Bingbing L, Zhou F, Huang K, Wang Y, Mei S, Zhou Y, Jing T (2017) Environmentally friendly chitosan/PEI-grafted magnetic gelatin for the highly effective removal of heavy metals from drinking water. Sci Rep 7:43082
Bratskaya SY, Avramenko VA, Sukhoverkhov SV, Schwarz S (2002) Flocculation of humic substances and their derivatives with chitosan. Colloid J 64:756–761
Chen X, Sun HL, Pan JH (2006) Decolorization of dyeing wastewater with use of chitosan materials. Ocean Sci J 41:221–226
Cheng WP, Chi FH, Yu RF, Lee YC (2005) Using chitosan as a coagulant in recovery of organic matters from the mash and lauter wastewater of brewery. J Polym Environ 13:383–388
Chiou MS, Kuo WS, Li HY (2003) Removal of reactive dye from waste water by adsorption using ECH cross-linked Chitosan beads as medium. J Hazard Mater A 38:2621–2631
Chivrac F, Pollet E, Averous L (2009) Progress in nano-biocomposites based on polysaccharides and nanoclays. Mater Sci Eng R 67:1–17
Crini G, Badot PM (2008) Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: a review of recent literature. Prog Polym Sci 33:399–447
Dashairya L, Sharma M, Basu S, Saha P (2018) Enhanced dye degradation using hydrothermally synthesized nanostructured Sb2S3/rGO under visible light irradiation. J Alloys Compd 735:234–245
Dhanavel S, Manivannan N, Gupta VK, Narayanan V, Stephen A (2018) Preparation and characterization of cross-linked chitosan/palladium nanocomposites for catalytic and antibacterial activity. J Mol Liq 257:32–41
Divakaran R, Pillai VNS (2001) Flocculation of kaolinite suspensions in water by chitosan. Water Res 35:3904–3908
Duong HV, Chau L, Dang N, Vanterpool F, Sanchez MS, Lizundia E, Tran HT, Nguyen VL, Nguyen TD (2018) Biocompatible chitosan-functionalized upconverting nanocomposites. ACS Omega 3:86–95
Farzana M, Meenakshi H, Sankaran V (2015) Facile synthesis of Chitosan/ZnO composite for the photodegradation of Rhodamine B dye. J Chitin Chitosan Sci 3:21–31
Fenglian F, Wang Q (2011) Removal of heavy metal ions from wastewater. J Environ Mang 92:407–418
Gamage A, Shahidi F (2007) Use of chitosan for the removal of metal ion contaminants and proteins from water. Food Chem 104:989–996
Gerente C, Lee VKC, Le Cloirec P, McKay G (2007) Application of Chitosan for the removal of metals from wastewaters by adsorption – mechanisms and model review. Crit Rev Environ Sci Technol 37:41–127
Gogoi P, Ashim J, Rashmi T, Devi R, Das B, Maji TK (2016) A comparative study on sorption of arsenate ions from water by crosslinked chitosan and crosslinked chitosan/MMT nanocomposite. J Environ Chem Eng 4(4):4248–4257
Gokila S, Gomathi T, Sudha PN, Anil S (2017) Removal of the heavy metal ion chromiuim(VI) using Chitosan and Alginate nanocomposites. Int J Biol Macromol 104:1459–1468
Guibal E (2004) Interactions of metal ions with chitosan-based sorbents: a review. Sep Purif Technol 38:43–74
Guibal E, Roussy J (2007) Coagulation and flocculation of dye-containing solutions using a biopolymer (chitosan). React Funct Polym 67:33–42
Gupta VK et al (2017) Degradation of azo dyes under different wavelengths of UV light with chitosan-SnO2 nanocomposites. J Mol Liq 232:423–430
Hadwiger LA, Kendra D, Fristensky BW, Wagoner W (2016) Chitosan both activates genes in plants and inhibits RNA synthesis in fungi. In: Chitin in nature and technology. Springer, Boston, pp 209–214
Haritma C, Ruhi G (2016) Eco friendly chitosan: an efficient material for water purification. Pharma Innovation J 5(1):92–95
Hosseinzadeh H, Ramin S (2018) Effective removal of copper from aqueous solutions by modified magnetic chitosan/graphene oxide nanocomposites. Int J Biol Macromol 113(1):859–868
Huang C, Chen Y (1996) Coagulation of colloidal particles in water by chitosan. J Chem Technol Biotechnol 66:227–232
Kim CY, Choi HM, Cho HT (1997) Effect of deacetylation on sorption of dyes and chromium on chitin. J Appl Polym Sci 63:725–736
Krajewska B (2005) Membrane-based processes performed with use of chitin/chitosan materials. Sep Purif Technol 41:305–312
Kumar R, Oves M, Almeelbi T, Al-Makishah NH, Barakat MA (2017) Hybrid chitosan/polyaniline-polypyrrole biomaterial for enhanced adsorption and antimicrobial activity. J Colloid Interface Sci 490:488–496
Kurita K (2006) Chitin and chitosan: functional biopolymers from marine crustaceans. Mar Biotechnol 8:203–206
Lefebvre O, Moletta R (2006) Treatment of organic pollution in industrial saline wastewater: a literature review. Water Res 40:3671–3682
Mahdavinia GR, Mosallanezhad A (2016) Facile and green rout to prepare magnetic and chitosan-crosslinked κ-carrageenan bionanocomposites for removal of methylene blue. J Water Pro Eng 10:143–155
Masheane M, Nthunya N, Malinga S, Nxumalo E, Barnard T, Mhlanga S (2016) Antimicrobial properties of chitosan-alumina/f-MWCNT nanocomposites. J Nanotechnol 2016:1–8
Miquel R, Souad A, Lara D, Javier G, Joan R, Jordi B (2007) Interaction of uranium with in situ anoxically generated magnetite on steel. J Hazard Mater 147:726–731
Mondal S (2008) Methods of dye removal from dye house effluent – an overview. Environ Eng Sci 25:383–396
Moussout H et al (2018) Performances of local chitosan and its nanocomposite 5%Bentonite/Chitosan in the removal of chromium ions Cr(VI) from wastewater. Int J Biol Macromol 108:1063–1073
Nafees A, Saima S, Ameer A, Suhail S, Mohammad ZK (2017) Novel bio-nanocomposite materials for enhanced biodegradability and photocatalytic activity. New J Chem 41:10198
Neeta P, Shukla SK, Singh NB (2017) Water purification by polymer nanocomposites: an overview. Nanocomposites 3(2):47–66
Nithya JK, Prabhu S, Jeganathan K (2014) Chitosan based nanocomposite materials as photocatalyst – a review. Mater Sci Forum 781:79–94
No HK, Lee K, Meyers SP (2000) Correlation between physical chemical characters binding capacity of Chitosan products. J Food Sci 65:1134–1137
Olivera S, Basavarajaiah H, Krishna M, Vijay V, Guna K, Gopalakrishna K, Kumar Y (2016) Potential applications of cellulose and chitosan nanoparticles/composites in wastewater treatment: a review. Carbohydr Polym 153:600–618
Ozer D, Ozer A (2004) The adsorption of copper (II) ions on to dehydrated wheat bran (DWB): determination of the equilibrium and thermodynamic parameters. Process Biochem 39:2183–2191
Portes E, Gardrat C, Castellan A, Coma V (2009) Environmentally friendly films based on chitosan and tetrahydrocurcuminoid derivatives exhibiting antibacterial and antioxidative properties. Carbohydr Polym 76:578–584
Qin C, Li H, Xiao Q, Liu Y, Zhu J, Du Y (2006) Watersolubility of chitosan and its antimicrobial activity. Carbohydr Polym 63:367–374
Qin Y, Cai L, Feng D, Shi B, Liu J, Zhang W, Shen Y (2007) Combined use of chitosan and alginate in the treatment of wastewater. J Appl Polym Sci 104(6):3581–3587
Rania EM, Alsabagh AM, Nasr SA, Zaki MM (2017) Multifunctional nanocomposites of chitosan, silver nanoparticles, copper nanoparticles and carbon nanotubes for water treatment: antimicrobial characteristics. Int J Biol Macromol 97:264–269
Renault F, Sancey B, Badot PM, Crini G (2009) Chitosan for coagulation/flocculation processes – an eco-friendly approach. Eur Polym J 45:1337–1348
Rinaudo M (2006) Chitin and chitosan: properties and applications. Prog Polym Sci 31:603–632
Rodrigues AC, Boroski M, Shimada NS, Garcia JC, Nozaki J, Hioka N (2008) Treatment of paper pulp mill wastewater by coagulation – flocculation followed by heterogenous photocatalysis. J Photochem Photobiol A Chem 194:1–10
Roussy J, Vooren VM, Guibal E (2004) Chitosan for the coagulation and flocculation of mineral colloids. J Dispers Sci Technol 25:663–677
Roussy J, Vooren VM, Dempsey BA, Guibal E (2005) Influence of chitosan characteristics on the coagulation and the flocculation of bentonite suspensions. Water Res 39:3247–3258
Saad AHA, Azzam A, El-Wakeel ST, Mostafa B, El-Latif MB (2018) Removal of toxic metal ions from wastewater using ZnO@Chitosan core-shell nanocomposite. Environ Nanotechnol Monit Manag 9:67–75
Saha P, Datta S, Sanyal SK (2008) Study on the effect of different metals on soil liner medium. Indian Sci Cruiser 22:50–56
Saito T, Isogai A (2005) Ion-exchange behavior and carboxylate groups in fibrous cellulose oxidized by TEMPO-mediated system. Carbohydr Polym 61:183–190
Saldias C et al (2018) In situ preparation of film and hydrogel bio-nanocomposites of chitosan/fluorescein-copper with catalytic activity. Carbohydr Polym 180:200–208
Seong HS, Kim JP, Ko SW (1999) Preparing chito-oligosaccharides as antimicrobial agents for cotton. Text Res J 69(7):483–488
Shahidi F, Arachchi JKV, Jeon YJ (1999) Food applications of chitin and chitosans. Trends Food Sci Technol 10:37–51
Strand SP, Vandvik MS, Vårum KM, Ostgaard K (2001) Screening of chitosan and conditions for bacterial flocculation. Biomacromolecules 2:121–133
Sultana S, Ahmad N, Faisal SM, Owais M, Sabir S (2007) IET Nanobiotechnol 2017:1–8
Swami D, Buddhi D (2006) Removal of contaminants from industrial wastewater through various non-conventional technologies: a review. Int J Environ Pollut 27:324–346
Teimouri A et al (2016) Chitosan/Zeolite Y/Nano ZrO2 nanocomposite as an adsorbent for the removal of nitrate from the aqueous solution. Int J Biol Macromol 93:254–266
Tripathi S, Mehrotrap GK, Dutta PK (2011) Preparation and antimicrobial activity of chitosan-silver oxide nanocomposite film via solution casting method. Bull Mater Sci 34:29–35
Vanamudan A, Padmaja MS, Pamidimukkala S (2018) Nanostructured zirconium tungstate and its bionanocomposite with chitosan: wet peroxide photocatalytic degradation of dyes. J Taiwan Inst Chem Eng 85:74–82
Varma AJ, Deshpande SV, Kennedy JF (2004) Metal complexation by chitosan and its derivatives. Carbohydr Polym 55:77–93
Veera MB, Krishnaiah A, Jonathan LT, Edgar DS (2003) Removal of hexavalent chromium from wastewater using a new composite chitosan biosorbent. Environ Sci Technol 37:4449–4456
Veera MB, Krishnaiah A, Ann JR, Edgar DS (2008a) Removal of copper (II) and nickel (II) ions from aqueous solutions by a composite chitosan biosorbent. Sep Sci Technol 43:1365–1381
Veera MB, Krishnaiah A, Jonathan LT, Edgar DS, Richard H (2008b) Removal of arsenic (III) and arsenic (V) from aqueous medium using chitosan-coated biosorbent. Water Res 42:633–642
Wada S, Ichikawa H, Tatsumi K (1995) Removal of phenols and aromatic amines from wastewater by a combination treatment with tyrosinase and a coagulant. Biotechnol Bioeng 45:304–309
Wan MW, Kan CC, Lin CH, Buenda DR, Wu CH (2007) Adsorption of copper (II) by chitosan immobilized on sand. Chia-Nan Annu Bull 33:96–106
Wang JP, Chen YZ, Ge XW, Yu HQ (2007) Optimization of coagulation– flocculation process for a paper-recycling wastewater treatment using response surface methodology. Colloids Surf A Physicochem Eng Aspects 302:204–210
Wu FC, Tseng RL, Juang RS (2001) Enhanced abilities of highly swollen chitosan beads for color removal and tyrosinase immobilization. J Hazard Mater B81:167
Wu ZB, Ni WM, Guan BH (2008) Application of chitosan as flocculant for coprecipitation of Mn(II) and suspended solids from dual-alkali FGD regenerating process. J Hazard Mater 152:757–764
Xie W, Xu P, Wang W, Liu Q (2002) Preparation and antibacterial activity of a water-soluble chitosan derivative. Carbohydr Polym 50:35–40
Zemmouria H, Drouiche M, Sayeh A, Lounici H, Mameri N (2013) Chitosan application for treatment of beni-amrane’s water Dam. Energy Procedia 36:558–564
Zheng C, Beach ES, Anastas PT (2011) Modification of chitosan films with environmentally benign reagents for increased water resistance. Taylor Francis 4:35–40
Acknowledgements
Authors are thankful to all those who have already worked in the field treatment of waste water using chitosan based nanocomposites and also thankful to those who have been working in this field. Authors acknowledge Department of Chemistry, Aligarh Muslim University, Aligarh for providing necessary facilities. SS also thanked UPCST for providing Young Scientist fellowship.
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Ahmad, N., Sultana, S., Khan, M.Z., Sabir, S. (2020). Chitosan Based Nanocomposites as Efficient Adsorbents for Water Treatment. In: Oves, M., Ansari, M., Zain Khan, M., Shahadat, M., M.I. Ismail, I. (eds) Modern Age Waste Water Problems . Springer, Cham. https://doi.org/10.1007/978-3-030-08283-3_4
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