Skip to main content

A Novel Method of Surface Tension Test for Melt Slags Based on Hot Thermocouple Technique

  • Conference paper
  • First Online:

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

Abstract

Currently, the sessile drop method and the maximum bubble method are widely used to measure the surface tension of melt slags. For the above methods, the slow heating rate of furnace decreases the test efficiency. The hot thermocouple technique is widely used in the measurement of the high-temperature performance of molten slags. The slag will form droplets on the thermocouple due to the capillarity, and based on the rapid heating-up and Young’s equation, this study used the Single Hot Thermocouple Technique (SHTT) for the test of CaO–SiO2–Al2O3 (CSA) and the CaO–SiO2–Al2O3–MgO (CSAM) slag systems. The results show that the interfacial tension between the CSA, CSAM slags and the thermocouple is 2117.76–2131.89 mN/m at 1500 °C. The surface tension of the CSA, CSAM slags can be obtained by Young’s equation. Compared with the surface tension measured by the standard test, the SHTT surface tension test error is within 5%.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD   169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

References

  1. Boni RE, Derge G (1956) Surface tensions of silicates. JOM 8:53–59

    Article  CAS  Google Scholar 

  2. Quincke G (1869) Ann Phys 138:141

    Article  Google Scholar 

  3. Fujii H et al (2006) Surface tension of molten silicon measured by microgravity oscillating drop method and improved sessile drop method. Acta Mater 54:1221–1225

    Article  CAS  Google Scholar 

  4. Bashforth F, Adams J (1883) An attempt to test the theories of capillary action. University Press, Cambridge, England

    Google Scholar 

  5. Kashiwaya Y et al (1998) Development of double and single hot thermocouple technique for in situ observation and measurement of mold slag crystallization. ISIJ Int 38:348–356

    Article  CAS  Google Scholar 

  6. Zhou L et al (2012) A kinetic study of the effect of basicity on the mold fluxes crystallization. Metall Mater Trans B 43:354–362

    Article  CAS  Google Scholar 

  7. Welch JH (1954) A simple microscope attachment for observing high-temperature phenomena. J Sci Instrum 31:458

    Article  Google Scholar 

  8. Kashiwaya Y, Cicutti CE, Cramb AW (1998) An investigation of the crystallization of a continuous casting mold slag using the single hot thermocouple technique. ISIJ Int 38:357–365

    Article  CAS  Google Scholar 

  9. Ordway F (1952) Techniques for growing and mounting small single crystals of refractory compounds. National Bureau of Standards

    Google Scholar 

  10. Wang W et al (2018) High-temperature properties of mold flux observed and measured in situ by single/double hot-thermocouple technique. JOM 70:1248–1255

    Article  Google Scholar 

  11. Zhou L et al (2018) Effect of Li2O on the behavior of melting, crystallization, and structure for CaO–Al2O3-based mold fluxes. Metall Mater Trans B 49:2232–2240

    Google Scholar 

  12. Zhou L et al (2013) Computational modeling of temperature, flow, and crystallization of mold slag during double hot thermocouple technique experiments. Metall Mater Trans B 44:1264–1279

    Article  CAS  Google Scholar 

  13. Cramb AW, Jimbo I (1989) Calculation of the interfacial properties of liquid steel–slag systems. Steel Res 60:157–165

    Article  CAS  Google Scholar 

  14. Jung EJ, Min DJ (2012) Effect of Al2O3 and MgO on interfacial tension between calcium silicate‐based melts and a solid steel substrate. Steel Res Int 83:705–711

    Article  CAS  Google Scholar 

  15. Li Y et al (2011) Determination and calculation for the surface tension of CaO–Al2O3–SiO2 melts. Male, Maldives

    Google Scholar 

  16. Allibert M et al (1995) Slag Atlas, 2nd edn. Verlag Stahleisen GmbH, Düsseldorf, p 446

    Google Scholar 

  17. Tran R et al (2016) Surface energies of elemental crystals. Sci Data 3:160080

    Article  CAS  Google Scholar 

  18. Butt HJ, Graf K, Kappl M (2006) Physics and chemistry of interfaces. Wiley

    Google Scholar 

Download references

Acknowledgements

The authors greatly appreciate the funding from the National Natural Science Foundation of China (Grant No. 51574050).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Guanghua Wen .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 The Minerals, Metals & Materials Society

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Wang, Z., Wen, G., Tang, P., Hou, Z. (2019). A Novel Method of Surface Tension Test for Melt Slags Based on Hot Thermocouple Technique. In: Nakano, J., et al. Advanced Real Time Imaging II. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-06143-2_1

Download citation

Publish with us

Policies and ethics