Abstract
In the present work, the effect of TiO2 on the viscosity and the free running temperature of the CaO–SiO2–Al2O3–MgO–TiO2 slag system were studied. At fixed CaO/SiO2 ratio of 1.1, 14 mass pct Al2O3 and 8 mass pct MgO, the viscosity decreases with an increase in TiO2 content between 20 and 30 mass pct due to depolymerization of slag structure , which means that TiO2 behaves as a network modifier. The free running temperature decreases with the increase of TiO2 content. The change of the apparent activation energy is in accordance with the change of viscosity . Five different viscosity models and FactSage software were employed to predict the viscosity . Yan’s model agrees well with experimental data.
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References
Zhang G, Chou K, Zhang J (2014) Influence of TiO2 on viscosity of aluminosilicate melts. Ironmaking Steelmaking 41(1):47–50
Zhang S, Zhang X, Bai C, Wen L, Lv X (2013) Effect of TiO2 content on the structure of CaO–SiO2–TiO2 system by molecular dynamics simulation. Isij Int 53(7):1131–1137
Sohn I, Wang W, Matsuura H, Tsukihashi F, Min DJ (2012) Influence of TiO2 on the viscous behavior of calcium silicate melts containing 17 mass% Al2O3 and 10 mass% MgO. ISIJ Int 52(1):2012
Ohno A, Ross H (1963) Can Metall Q 2:259
Park H, Park JY, Kim GH, Sohn I (2012) Steel Res Int 83:150
Liao JL, Li J, Wang XD, Zhang ZT (2012) Ironmaking Steelmaking 39:133
Sohn I, Wang W, Matsuura H, Tsukihashi F, Min DJ (2012) ISIJ Int 52:158
Yan Z, Lv X, He W, Xu J (2017) ISIJ Int 57(1):31–36
Yan Z, Lv X, Liang D, Zhang J, Bai C (2017) Transition of blast furnace slag from silicates-based to aluminates-based: viscosity. Metall Mater Trans B 48(2):1092–1099
Colf JVD, Howat DD (1979) J S Afr Inst Min Metall 79:255–263
Shankar A, Gornerup M, Lahiri AK, Seetharaman S (2007) Ironmaking Steelmaking 34:477–481
Nakamura T, Morinaga K, Yanagase T (1977) Nippon Kinzoku Gakkaishi 4:1300–1304
Qiao R, Du H (1988) Influence of TiO2 on the viscosity and free running temperature of the slag containing fluorine. J Iron Steel Res 10:1–4
Liang L, Hao Z, Wen D, Jia X, Deng Y (2017) Study on viscosity and melting temperature of no. 7 blast furnace slag from Baotou steel. Hunan Nonferrous Metals
Joo Hyun Park (2013) Structure-property relationship of CaO–MgO–SiO2, slag: quantitative analysis of raman spectra. Metall Mater Trans B 44(4):938–947
Riboud PV, Roux Y, Lucas LD, Gaye H (1981) Fachber Hut-tenpraxis Metall 19:859–869
Urbain G, Cambier F, Deletter M, Anseau MR (1981) Trans J Br Ceram Soc 80:139–141
Zhang G, Kuochih C (2012) Modelling viscosities of CaO–MgO–Al2O3–SiO2 molten slags. ISIJ Int 52(3):355–362
Mills K (2011) The estimation of slag properties. Southern African Pyrometallurgy
Yan Z, Reddy RG, Lv X, Pang Z, He W (2018) Structure-based viscosity model development for titania aluminosilicate slags. Ironmaking Steelmaking: 1–7
Acknowledgements
This study was supported by the Fundamental Research Funds for the Central Universities (Grant No. 2018CDQYCL0026) and the Fundamental Research Funds for the Central Universities (2018CDPTCG0001/32).
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Pang, Z., Jiang, Y., Lv, X., Yan, Z., He, W. (2019). Effect of TiO2 on the Viscous Behaviour of the CaO–SiO2–14 Mass% Al2O3–8 Mass% MgO–TiO2 Slag. In: Jiang, T., et al. 10th International Symposium on High-Temperature Metallurgical Processing. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-05955-2_50
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DOI: https://doi.org/10.1007/978-3-030-05955-2_50
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