Abstract
The effects of La addition on the inclusions, microstructures, and high-temperature mechanical properties of as-cast FeCrAl alloys were investigated by using scanning electron microscope (SEM), energy disperse spectroscopy (EDS), and hot tensile tests. The characteristics of inclusions were examined, and further discussions focused on the analysis of thermodynamic calculations. The results showed that after La addition , AlN inclusions were likely to have cores of La-containing particles. Under the conditions of this study, La2O2S and La2O3 inclusions were the main La-containing precipitates and could act as the nucleus for the heterogeneous nucleation of δ-Fe to refine grains. The microstructure comparison of the two studied alloy ingots indicated that both the columnar and the equiaxed grains were refined after La addition . A series of tensile tests were carried out at temperatures from 973 to 1673 K under a constant strain rate of 1 × 10−3 s−1 to investigate the high-temperature mechanical properties . Both the tensile stress and the hot ductility were improved at the studied temperatures after La addition .
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References
He Y, Liu JH, Qiu ST, Deng ZQ, Yang YD, McLean A (2018) Interfacial morphology evolution in directional solidified FeCrAl alloys. Mater Charact 139:303–310
Kim DH, Yu BY, Cha PR, Yoon WY, Byun JY, Kim SH (2012) A study on FeCrAl foam as effective catalyst support under thermal and mechanical stresses. Surf Coat Technol 209:169–176
Han Z, Liu J, He Y, Li K, Ji Y, Liu J (2015) Determination of the liquidus and solidus temperatures of FeCrAl stainless steel. Int J Miner Metall Master 22(11):1141–1148
He Y, Liu JH, Qiu ST, Deng ZQ, Yang YD, McLean A (2018) Microstructure and high temperature mechanical properties of as-cast FeCrAl alloys. Mater Sci Eng A Struct 726:56–63
Smirnov LA, Rovnushkin VA, Oryshchenko AS, Kalinin GY, Milyuts VG (2016) Modification of steel and alloys with rare-earth elements. Part 2. Metallurgist 60(1–2):38–46
Ozawa M, Araki KI (2015) Effect of La modification on the stability of coating alumina layer on FeCrAl alloy substrate. Surf Coat Tech 271:80–86
Buscail H, Nguyen CT, Cueff R, Issartel C, Riffard F, Perrier S (2009) Effect of the La2O3 sol-gel coating on the alumina scale adherence on a model Fe-20Cr-5Al alloy at 1100 °C. J Mater Sci 44(15):3968–3974
Yue K, Du T (1989) Thermodynamical study on Fe–Ce–N–O, Fe–Y–N–S solutions. J Chin Rare Earth Soc 1:12–15
Vahed A, Kay DAR (1976) Thermodynamics of rare earths in steelmaking. Metall Trans B 78:375–383
Wilson WG, Kay DAR, Vahed A (1974) The use of thermodynamics and phase equilibria to predict the behavior of the rare earth elements in steel. JOM 26(5):14–23
Wang LM, Du T (1986) [La]–[S]–[O] equilibrium in liquid iron. Chin Rare Earth 2:27–34
Bramfitt BL (1970) The effect of carbide and nitride additions on the heterogeneous nucleation behavior of liquid iron. Metall Trans 1(7):1987–1995
Wang AQ, Li M, Ma DQ, Wu QJ, Xie JP (2016) Effect of lanthanum on microstructures and properties of ASTM A216 steel. Kem Ind 65(1–2):11–16
Wang LM, Ting D, Lu XL, Li ZB, Gai YC (2003) Thermodynamics and application of rare earth elements in steel. J Chin Rare Earth Soc 21(3):251–254
Acknowledgements
The authors gratefully acknowledge the financial support of this research by the National Science Foundation of China (Grant No 51374023).
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He, Y., Liu, J., Yang, Y., McLean, A. (2019). Effect of La Addition on Inclusions, Microstructures, and High-Temperature Mechanical Properties of As-Cast FeCrAl Alloys. In: Jiang, T., et al. 10th International Symposium on High-Temperature Metallurgical Processing. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-05955-2_40
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DOI: https://doi.org/10.1007/978-3-030-05955-2_40
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