Abstract
Several slag compositions of differing reactivity were designed as a potential measure for reducing erosion on submergence entry nozzle during continuous casting of high-Mn high-Al steel . Reactivities were determined according to the SiO2 content of the slag considering the reaction between [Al] and (SiO2) at the steel –slag interface. The erosion rate was evaluated by means of the rotating cylinder method; a ZrO2-C rod was immersed in the 1673 K slag sample for two hours, and the erosion rate was evaluated according to the reduction of rod diameter. The effect of slag components Na2O, Li2O, CaF2 and B2O3 on the erosion rate was investigated. The main results indicate that slag with low SiO2 content was more effective in decreasing the erosion rate than conventional high-SiO2 slag. Listed in decreasing order of intensity, the effects of the individual components on the erosion rate are Na2O, CaF2, Li2O and B2O3. The ultimate aim of the mould slag optimization effort is stabilizing the operation by extending the submergence entry nozzle service life.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Dick AF et al (1997) Attack of submerged entry nozzles by mould flux and dissolution of refractory oxides in the flux. ISIJ Int 37(2):102–108
Imaoka T, Iwamoto Y (2012) Effect of mold powder properties on corrosion rate of SEN ZrO2-C material. Shinagawa Tech Rep 55:21–30
Nakamura Y, Ando T, Kurata K (1986) Effect of chemical composition of mold powder on the erosion of submerged nozzles for continuous casting of steel. Trans. ISIJ 26:1052–1058
Bui A-H, Park S-C, Chung I-S (2006) Dissolution behavior of zirconia-refractories during continuous casting of steel. Met Mater Int 12(5):435–440
Cirilli F, Donato AD, Martini U (2008) Corrosion mechanisms of zirconia/carbon based refractory materials by slag in presence of steel La. Metallurgia Italiana 10:43–50
Suk MO, Park JH (2009) Corrosion behaviors of zirconia refractory by CaO–SiO2–MgO–CaF2 Slag. Am Ceramic Soc 92(3):717–723
Acknowledgements
This work was supported by the Key Program of National Science Foundation of China (No. U1660204).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 The Minerals, Metals & Materials Society
About this paper
Cite this paper
Wang, XS., Wang, Q., Zeng, CP., Yuan, HZ. (2019). Influence of Mould Slag Compositions with Different Reactivity on the Erosion Rate of ZrO2-C Bearing Submergence Entry Nozzle. In: Jiang, T., et al. 10th International Symposium on High-Temperature Metallurgical Processing. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-05955-2_13
Download citation
DOI: https://doi.org/10.1007/978-3-030-05955-2_13
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-05954-5
Online ISBN: 978-3-030-05955-2
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)