Abstract
Several main healing agents currently used in self-healing nanotextured materials are discussed in this section. These include dicyclopentadiene (DCPD) and Grubbs’ catalyst (Sect. 2.1) and dimethyl siloxane (DMS , a resin monomer ) and dimethyl-methyl hydrogen -siloxane (curing agent ) polymerized as poly(dimethyl siloxane) (PDMS, Sect. 2.2). Several other elastomers used for self-healing are discussed in Sect. 2.3. Self-healing agents can also comprise epoxy -hardener systems (Sect. 2.4), and gels (Sect. 2.5).
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Abdul Khalil HPS, Saurabh CK, Adnan AS, Nurul Fazita MR, Syakir MI, Davoudpour Y, Rafatullah M, Abdullah CK, Haafiz MKM, Dungani R (2016) A review on chitosan-cellulose blends and nanocellulose reinforced chitosan biocomposites: properties and their applications. Carbohydr Polym 150:216–226
An S, Liou M, Song KY, Jo HS, Lee MW, Al-Deyab SS, Yarin AL, Yoon SS (2015) Highly flexible transparent self-healing composite based on electrospun core–shell nanofibers produced by coaxial electrospinning for anti-corrosion and electrical insulation. Nanoscale 7:17778–17785
Bai J, Li H, Shi Z, Yin J (2018) An eco-friendly scheme for the cross-linked polybutadiene elastomer via thiolene and Diels-Alder click chemistry. Macromolecules 48:3539–3549
Blaiszik BJ, Caruso MM, McIlroy DA, Moore JS, White SR, Sottos NR (2009) Microcapsules filled with reactive solutions for self-healing materials. Polymer 50:990–997
Brown EN, White SR, Sottos NR (2004) Microcapsule induced toughening in a self-healing polymer composite. J Mater Sci 39:1703–1710
Campbell DJ, Beckman KJ, Calderon CE, Doolan PW, Ottosen RM, Ellis AB, Lisensky GC (1999) Replication and compression of bulk and surface structures with polydimethylsiloxane elastomer. J Chem Educ 75:537–541
Chen C, Peters K, Li Y (2013) Self-healing sandwich structures incorporating an interfacial layer with vascular network. Smart Mater Struct 22:025031
Chen L, Chen H, Yao X, Ma X, Tian H (2015a) A hybrid supramolecular polymeric hydrogel with rapid self-healing property. Chem Asian J 10:2352–2355
Chen S, Mo F, Yang Y, Stadler FJ, Chen S, Yang H, Ge Z, Zhuo H (2015b) Development of zwitterionic polyurethanes with multi-shape memory effects and self-healing properties. J Mater Chem A 3:2924–2933
Chen Y, Guan Z (2015) Self-healing thermoplastic elastomer brush copolymers having a glassy polymethylmethacrylate backbone and rubbery polyacrylate-amide brushes. Polymer 69:249–254
Cho SH, Andersson HM, White SR, Sottos NR, Braun PV (2006) Polydimethylsiloxane-based self-healing materials. Adv Mater 18:997–1000
Das A, Sallat A, Bohme F, Suckow M, Basu D, Wießner S, Stöckelhuber KW, Voit B, Heinrich G (2015) Ionic modification turns commercial rubber into a self-healing material. ACS Appl Mater Interfaces 7:20623–20630
Denq BL, Hu YS, Chen LW, Chiu WY, Wu TR (1999) The curing reaction and physical properties of DGEBA/DETA epoxy resin blended with propyl ester phosphazene. J Appl Polym Sci 74:229–237
Faghihnejad A, Feldman KE, Yu J, Tirrell MV, Israelachvili JN, Hawker CJ, Kramer EJ, Zeng HB (2014) Adhesion and surface interactions of a self-healing polymer with multiple hydrogen-bonding groups. Adv Funct Mater 24:2322–2333
Fan F, Szpunar J (2015) The self-healing mechanism of an industrial acrylic elastomer. J Appl Polym Sci 132:42135
Farquharson S, Smith W, Rose J, Shaw M (2002) Correlations between molecular (Raman) and macroscopic (rheology) data for process monitoring of thermoset composite. J Process Anal Chem 7:45–53
Flint S, Markle T, Thompson S, Wallace E (2012) Bisphenol A exposure, effects, and policy: a wildlife perspective. J Environ Manage 104:19–34
Garcia FG, Soares BG, Pita VJRR, Sanchez R, Rieumont J (2007) Mechanical properties of epoxy networks based on DGEBA and aliphatic amines. J Appl Polym Sci 106:2047–2055
Gold BJ, Hovelmann CH, Weiss C, Radulescu A, Allgaier J, Pyckhout-Hintzen W, Wischnewski A, Richter D (2016) Sacrificial bonds enhance toughness of dual polybutadiene networks. Polymer 87:123–128
Goosey MT (1985) Epoxide resins and their formulation. In: Goosey MT (ed) Plastics for electronics. Springer, Netherlands, Dordrecht, pp 99–136
Harmon JP, Bass R (2014) Self-healing polycarbonate containing polyurethane nanotube composite. University of South Florida; US Patent 8,846,801 B1, Sep. 30
Huang M, Yang J (2011) Facile microencapsulation of HDI for self-healing anticorrosion coatings. J Mater Chem 21:11123
Jasra R, Maiti M, Srivastava V. (2015) Reliance Industries Limited, US Patent 20150045496, Feb. 12
Jolley ST, Williams MK, Gibson TL, Smith TM, Caraccio AJ, Li W (2012) Self-healing polymer materials for wire insulation, polyimides, flat surfaces, and inflatable structures. National Aeronautics and Space Administration (NASA); Dec. 20
Jones AR, Watkins CA, White SR, Sottos NR (2015) Self-healing thermoplastic-toughened epoxy. Polymer 74:254–261
Keller MW, Hampton K, McLaury B (2013) Self-healing of erosion damage in a polymer coating. Wear 307:218–225
Keller MW, White SR, Sottos NR (2007) A self-healing poly(dimethyl siloxane) elastomer. Adv Mater 17:2399–2404
Lee MW, An S, Jo HS, Yoon SS, Yarin AL (2015a) Self-healing nanofiber-reinforced polymer composites: 1. Tensile testing and recovery of mechanical properties. ACS Appl Mater Interfaces 7:19546–19554
Lee MW, An S, Jo HS, Yoon SS, Yarin AL (2015b) Self-healing nanofiber-reinforced polymer composites: 2. Delamination/debonding, and adhesive and cohesive properties. ACS Appl Mater Interfaces 7:19555–19561
Lee MW, An S, Kim YI, Yoon SS, Yarin AL (2018) Self-healing three-dimensional bulk materials based on core-shell nanofibers. Chem Eng J 334:1093–1100
Lee MW, An S, Lee C, Liou M, Yarin AL, Yoon SS (2014a) Self-healing transparent core–shell nanofiber coatings for anti-corrosive protection. J Mater Chem A 2:7045–7053
Lee MW, An S, Lee C, Liou M, Yarin AL, Yoon SS (2014b) Hybrid self-healing matrix using core−shell nanofibers and capsuleless microdroplets. ACS Appl Mater Interfaces 6:10461–10468
Lee MW, Jo HS, Yoon SS, Yarin AL (2017a) Thermally driven self-healing using copper nanofiber heater. Appl Phys Lett 111:011902
Lee MW, Sett S, An S, Yoon SS, Yarin AL (2017b) Self-healing nano-textured vascular-like materials: Mode I crack propagation. ACS Appl Mater Interfaces 9:27223–27231
Lee MW, Sett S, Yoon SS, Yarin AL (2016a) Fatigue of self-healing nanofiber-based composites: static test and subcritical crack propagation. ACS Appl Mater Interfaces 8:18462–18470
Lee MW, Sett S, Yoon SS, Yarin AL (2016b) Self-healing of nanofiber-based composites in the course of stretching. Polymer 103:180–188
Lee MW, Yoon SS, Yarin AL (2016c) Solution-blown core−shell self-healing nano- and microfibers. ACS Appl Mater Interfaces 8:4955–4962
Lenhardt JM, Kim SH, Nelson AJ, Singhal P, Baumann TF, Satcher JH (2013) Increasing the oxidative stability of poly(dicyclopentadiene) aerogels by hydrogenation. Polymer 54:542–547
Li G, Ajisafe O, Meng H (2013) Effect of strain hardening of shape memory polymer fibers on healing efficiency of thermosetting polymer composites. Polymer 54:920–928
Lutz A, van der Berg O, Damme JV, Verheyen K, Bauters E, Graeve ID, Du Prez FE, Terryn H (2015) A shape-recovery polymer coating for the corrosion protection of metallic surfaces. ACS Appl Mater Interfaces 7:175–183
Mauldin TC, Rule JD, Sottos NR, White SR, Moore JS (2007) Self-healing kinetics and the stereoisomers of dicyclopentadiene. J R Soc Interface 4:389–393
Neisiany RE, Khorasani SN, Lee JKY, Ramakrishna S (2016) Encapsulation of epoxy and amine curing agent in PAN nanofibers by coaxial electrospinning for self-healing purposes. RSC Adv 6:70056–70063
Ou R, Eberts K, Skandan G (2015) Phase separated self-healing polymer coatings. NEI Corporation, US Patent 8,987,352 B1, Mar. 24
Park JH, Braun PV (2010) Coaxial electrospinning of self-healing coatings. Adv Mater 22:496–499
Patrick JF, Hart KR, Krull BP, Diesendruck CE, Moore JS, White SR, Sottos NR (2014) Continuous self-healing life cycle in vascularized structural composites. Adv Mater 26:4302–4308
Perring M, Long TR, Bowden NB (2010) Epoxidation of the surface of polydicyclopentadiene for the self-assembly of organic monolayers. J Mater Chem 20:8679–8685
Rahman MA, Sartore L, Bignotti F, Landro LD (2013) Autonomic self-healing in epoxidized natural rubber. ACS Appl Mater Interfaces 5:1494–1502
Raquez JM, Deleglisea M, Lacrampea MF, Krawczak P (2010) Thermosetting (bio)materials derived from renewable resources: a critical review. Prog Polym Sci 35:487–509
Saeed MU, Li BB, Chen ZF, Cui S (2016) Self-healing of low-velocity impact and mode-I delamination damage in polymer composites via microchannels. Express Polymer Letters 10:337–348
Shahabudin N, Yahy R, Gan SN (2016) Microcapsules of poly(urea-formaldehyde) (PUF) containing alkyd from palm oil. Mater Today Proc 3:S88–S95
Sinha-Ray S, Pelot DD, Zhou ZP, Rahman A, Wu X-F, Yarin AL (2012) Encapsulation of self-healing materials by coelectrospinning, emulsion electrospinning, solution blowing and intercalation. J Mater Chem 22:9138–9146
Spoljaric S, Salminen A, Luong ND, Seppälä J (2014) Stable, self-healing hydrogels from nanofibrillated cellulose, poly(vinyl alcohol) and borax via reversible crosslinking. Eur Polym J 56:105–117
Turkenburg DH, Hv B, Funke B, Schmider M, Janke D, Fischer HR (2015) Polyurethane adhesives containing Diels–Alder-based thermoreversible bonds. J Appl Polym Sci 132:41944
Urban MW, Ghosh B (2015) Self-repairing cyclic oxide-substituted chitosan polyurethane networks. University of Southern Mississippi. US Patent 9,200,089
Vahedi V, Pasbakhsh P, Piao CS, Seng CE (2015) A facile method for preparation of self-healing epoxy composites: using electrospun nanofibers as microchannels. J Mater Chem A 3:16005–16012
van der Zwaag S (ed) (2007) Self healing materials: an alternative approach to 20 centuries of materials science. Springer, Heidelberg
Wang W, Xu L, Li X, Yang Y, An E (2014) Self-healing properties of protective coatings containing isophorone diisocyanate microcapsules on carbon steel surfaces. Corros Sci 80:528–535
White SR, Moore JS, Sottos NR, Krull BP, Cruz WAS, Gergely RCR (2014) Restoration of large damage volumes in polymers. Science 344:620–623
White SR, Sottos NR, Geubelle PH, Moore JS, Kessler MR, Sriram SR, Brown EN, Viswanathan S (2001) Autonomic healing of polymer composites. Nature 409:794–797
Willocq B, Bose RK, Khelifa F, Garcia SJ, Dubois P, Raquez JM (2016) Healing by the Joule effect of electrically conductive poly(ester-urethane)/carbon nanotube nanocomposites. J Mater Chem A 4:4089–4097
Wu X-F, Rahman A, Zhou Z, Pelot DD, Sinha-Ray S, Chen B, Payne S, Yarin AL (2013) Electrospinning core-shell nanofibers for interfacial toughening and self-healing of carbon-fiber/epoxy composites. J Appl Polym Sci 129:1383–1393
Wypych G (2017) Self-healing materials: principles and technology. ChemTec Publishing, Toronto
Xiao Y, Huang H, Peng X (2017) Synthesis of self-healing waterborne polyurethanes containing sulphonate groups. RSC Adv 7:20093
Yang J, Keller MW, Moore JS, White SR, Sottos NR (2008) Microencapsulation of isocyanates for self-healing polymers. Macromol Rapid Commun 41:9650–9655
Yerro O, Radojevic V, Radovic I, Petrovic M, Uskokovic PS, Stojanovic DB, Aleksic R (2016) Thermoplastic acrylic resin with self-healing properties. Polym Eng Sci 56:251–257
Zhang H, Wang P, Yang J (2014a) Self-healing epoxy via epoxy–amine chemistry in dual hollow glass bubbles. Compos Sci Technol 94:23–29
Zhang H, Yang J (2014) Development of self-healing polymers via amine–epoxy chemistry: I. Properties of healing agent carriers and the modelling of a two-part self-healing system. Smart Mater Struct 23:065003
Zhang P, Li G (2015) Healing-on-demand composites based on polymer artificial muscle. Polymer 64:29–38
Zhang X-C, Ji H-W, Qiao Z-X (2014b) Residual stress in self-healing microcapsule-loaded epoxy. Mater Lett 137:9–12
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Yarin, A.L., Lee, M.W., An, S., Yoon, S.S. (2019). Healing Agents Used for Mechanical Recovery in Nanotextured Systems. In: Self-Healing Nanotextured Vascular Engineering Materials. Advanced Structured Materials, vol 105. Springer, Cham. https://doi.org/10.1007/978-3-030-05267-6_2
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