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Abstract

Thermally aged nickel based Alloy 600 was investigated to evaluate the effects of long-term thermal aging and triaxial stress on primary water stress corrosion crack initiation behavior. Long-term thermal aging was simulated by heat treatment at 400 °C, a temperature that does not cause excessive formation of second phases that cannot form in nuclear power plant service conditions. Triaxial stress was applied by a round notch in the gauge length of some test specimen; other specimens were smooth. Slow strain rate tests (SSRT) monitored by the direct current potential drop method were conducted to evaluate stress corrosion crack initiation susceptibility of the thermally aged specimens in the primary water environment. For smooth specimens (which experience uniaxial stress), the susceptibility of those thermally aged for the equivalent of 10-years was the highest, while the susceptibility of the as-received specimens was the lowest. However, for the notched specimens (which experience triaxial stress), the specimens thermally aged for the equivalent of 20-years showed the highest susceptibility, while the as-received specimens showed the lowest.

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References

  1. P. Scott, An overview of internal oxidation as a possible explanation of intergranular stress corrosion cracking of alloy 600 in PWRs. Paper presented at 9th international symposium on environmental degradation of materials in nuclear power systems-water reactors, pp. 3–14 (1999)

    Google Scholar 

  2. M.J.O.M.B. Toloczko, D.K. Schreiber, S.M. Bruemmer, Corrosion and stress corrosion crack initiation of cold-worked alloy 690 in PWR primary water. Technical Milestone Report (2013)

    Google Scholar 

  3. P. Scott, An overview of materials degradation by stress corrosion in PWRs, (2004)

    Google Scholar 

  4. J. Kai, G. Yu, C. Tsai, M. Liu, S. Yao, The effects of heat treatment on the chromium depletion, precipitate evolution, and corrosion resistance of Inconel alloy 690. Metall. Trans. A 20, 2057–2067 (1989)

    Article  Google Scholar 

  5. R. Celin, F. Tehovnik, Degradation of a Ni–Cr–Fe alloy in a pressurised-water nuclear power plant. Mater. Tehnol. 45, 151–157 (2011)

    CAS  Google Scholar 

  6. Y.S. Lim, H.P. Kim, S.S. Hwang, Microstructural characterization on intergranular stress corrosion cracking of Alloy 600 in PWR primary water environment. J. Nucl. Mater. 440, 46–54 (2013)

    Article  CAS  Google Scholar 

  7. K.J. Choi, J.J. Kim, B.H. Lee, C.B. Bahn, J.H. Kim, Effects of thermal aging on microstructures of low alloy steel–Ni base alloy dissimilar metal weld interfaces. J. Nucl. Mater. 441, 493–502 (2013)

    Article  CAS  Google Scholar 

  8. J. Boursier, F. Vaillant, B. Yrieix, Weldability, thermal aging and PWSCC behavior of nickel weld metals containing 15 to 30% chromium. Paper presented at ASME/JSME 2004 pressure vessels and piping conference, pp. 109–121 (2004)

    Google Scholar 

  9. T. Shoji, Z. Lu, H. Murakami, Formulating stress corrosion cracking growth rates by combination of crack tip mechanics and crack tip oxidation kinetics. Corros. Sci. 52, 769–779 (2010)

    Article  CAS  Google Scholar 

  10. S.C. Yoo, K.J. Choi, T. Kim, S.H. Kim, J.Y. Kim, J.H. Kim, Microstructural evolution and stress-corrosion-cracking behavior of thermally aged Ni–Cr–Fe alloy. Corros. Sci. 111, 39–51 (2016)

    Article  CAS  Google Scholar 

  11. Q. Peng, J. Hou, K. Sakaguchi, Y. Takeda, T. Shoji, Effect of dissolved hydrogen on corrosion of Inconel Alloy 600 in high temperature hydrogenated water. Electrochim. Acta 56, 8375–8386 (2011)

    Article  CAS  Google Scholar 

  12. K. Mo, G. Lovicu, X. Chen, H.-M. Tung, J.B. Hansen, J.F. Stubbins, Mechanism of plastic deformation of a Ni-based superalloy for VHTR applications. J. Nucl. Mater. 441, 695–703 (2013)

    Article  CAS  Google Scholar 

  13. J. Pardal, S. Tavares, V. Terra, M. Da Silva, D. Dos Santos, Modeling of precipitation hardening during the aging and overaging of 18Ni–Co–Mo–Ti maraging 300 steel. J. Alloy. Compd. 393, 109–113 (2005)

    Article  CAS  Google Scholar 

  14. B. Alexandreanu, B. Capell, G.S. Was, Combined effect of special grain boundaries and grain boundary carbides on IGSCC of Ni–16Cr–9Fe–Xc alloys. Mater. Sci. Eng. A-Struct. Mater Prop. Microstruc. Process. 300, 94–104 (2001)

    Article  Google Scholar 

  15. D. Kirkwood, Precipitate number density in a Ni Al alloy at early stages of ageing. Acta Metall. 18, 563–570 (1970)

    Article  CAS  Google Scholar 

  16. G.S. Was, Grain-boundary chemistry and intergranular fracture in austenitic nickel-base alloys—A review. Corrosion 46, 319–330 (1990)

    Article  CAS  Google Scholar 

  17. J.R. Crum, K.A. Heck, T.M. Angeliu, Effect of different thermal treatments on the corrosion resistance of alloy 690 tubing. Paper presented at 4th environmental degradation of materials in nuclear power systems-water reactors, pp. 293 (1990)

    Google Scholar 

  18. Z. Guo, W. Sha, Quantification of precipitation hardening and evolution of precipitates. Mater. Trans. 43, 1273–1282 (2002)

    Article  CAS  Google Scholar 

  19. V. Mohles, D. Rönnpagel, E. Nembach, Simulation of dislocation glide in precipitation hardened materials. Comput. Mater. Sci. 16, 144–150 (1999)

    Article  CAS  Google Scholar 

  20. R. Hayes, W. Hayes, On the mechanism of delayed discontinuous plastic flow in an age-hardened nickel alloy. Acta Metall. 30, 1295–1301 (1982)

    Article  Google Scholar 

Download references

Acknowledgements

This work was financially supported by the Nuclear Safety Research Program through the Korea Foundation of Nuclear Safety (KOFONS), granted financial resource from the Nuclear Safety and Security Commission (NSSC), Republic of Korea (No. 1403006) and by the Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Korea Government Ministry of Trade Industry and Energy (MOTIE) (No. 20174030201430).

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Correspondence to Seung Chang Yoo .

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Yoo, S.C. et al. (2019). PWSCC Initiation of Alloy 600: Effect of Long-Term Thermal Aging and Triaxial Stress. In: Jackson, J., Paraventi, D., Wright, M. (eds) Proceedings of the 18th International Conference on Environmental Degradation of Materials in Nuclear Power Systems – Water Reactors. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-04639-2_18

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