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La Chimie Macromoléculaire—4 / Macromolecular Chemistry—4 pp 369–387Cite as

Infrared Spectroscopy and Polymer Structure

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Abstract

The power of infrared spectroscopy as a tool in studying the structure of small molecules is well known. This insight into structure results largely from our ability to analyse the spectrum theoretically by means of a normal coordinate analysis. This technique consists of calculating the normal vibration frequencies of a molecule from information on its structure and internal force field. From such a calculation we obtain the values of the frequencies and the forms of the vibrations of the molecule which can be observed in infrared absorption and in Raman scattering. By comparing such calculated frequencies with the observed spectrum it is possible to evaluate our assumptions concerning the structure and force field of the molecule.

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  1. Harrison M. Randall Laboratory of Physics, University of Michigan, Ann Arbor, Michigan, USA

    S. Krimm

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Krimm, S. (1968). Infrared Spectroscopy and Polymer Structure. In: La Chimie Macromoléculaire—4 / Macromolecular Chemistry—4. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-6407-6_8

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  • DOI: https://doi.org/10.1007/978-1-4899-6407-6_8

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-6201-0

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