Abstract
The dispersion of the capacitance and conductance of a specimen with frequency, arising from the presence of interfaces between regions of differing dielectric properties, can be used to study the geometry and electrical properties of the more conducting regions. The measurement and interpretation of these interfacial polarization effects are discussed, with particular emphasis on their application to studies of surface effects in single crystals. The results of experimental studies of the variation in electrical properties of relatively thick (approximately 10μ) surface layers in sapphire produced by the adsorption and desorption of gases, incomplete equilibration of composition in various oxygen partial pressures, and the presence of impurities and preliminary results of interfacial polarization studies in sodium chloride crystals are presented.
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References
J.C. Maxwell, Electricity and Magnetism, Vol. 1, Clarendon Press, (Oxford), 1892, p. 452.
K. W. Wagner, “Erklarung der dielektrischen Nachwirkungsvorgange auf Grund Maxwellscher Vorstellungen,” Arch. Elektrotechnik 2(9):371–387 (1914).
R. W. Sillars, “The Properties of a Dielectric Containing Semiconducting Particles of Various Shapes,” J. Inst. Elec. Engrs. (London) 80(484):378–394 (1937).
H. Fricke, “The Maxwell-Wagner Dispersion in a Suspension of Ellipsoids,” J. Phys. Chem. 57(9): 934–937 (1953).
J. Volger, “Dielectric Properties of Solids in Relation to Imperfections,” in: A. F. Gibson (ed.), Progress in Semiconductors, Vol. 4, John Wiley and Sons, (New York), 1960, pp. 206–236.
N. M. Tallan H.C. Graham, and R. W. Vest, “Origin of Apparent Negative Impedance in Three-Terminal Measurements,” Rev. Sci. Instr. 33(10): 1087–1088 (1962).
W. Hartmann, “Electrische Untersuchungen an Oxydischen Halbleitern,” Z. Physik. 102(11): 709–733 (1936).
N. M. Tallan and D. P. Detwiler, “An Anomalous Dissipation Factor Maximum in Sapphire,” J. Appl. Phys. 34(6): 1650–1656 (1963).
I.I. Frenkel, Kinetic Theory of Liquids, Clarendon Press, (Oxford), 1946, pp. 36–40.
K. Lehovec, “Space-Charge Layer and Distribution of Lattice Defects at the Surface of Ionic Crystals,” J. Chem. Phys. 21(7): 1123–1128 (1953).
G. Parravano and C. A. Domenicali, “Thermoelectric Behavior of Solid Particulate Systems; Nickel Oxide,” J. Chem. Phys. 26(2): 359–366 (1957).
Y. Oishi and W. D. Kingery, “Self-Diffusion of Oxygen in Single-Crystal and Polycrystalline Aluminum Oxide,” J. Chem. Phys. 33(2): 480–486 (1960).
P.J. Harrop and R.H. Creamer, “The High-Temperature Electrical Conductivity of Single-Crystal Alumina,” Brit. J. Appl. Phys. 14(6): 335–359 (1963).
R. W. Dreyfus and A.S. Nowick, “Ionic Conductivity of Doped NaCl Crystals,” Phys. Rev. 126(4): 1367–1377 (1962).
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© 1966 Springer Science+Business Media New York
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Tallan, N.M., Graham, H.C., Wimmer, J.M. (1966). Interfacial Polarization Effects Associated with Surfaces and Interfaces. In: Kriegel, W.W., Palmour, H. (eds) The Role of Grain Boundaries and Surfaces in Ceramics. Materials Science Research. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-6311-6_8
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DOI: https://doi.org/10.1007/978-1-4899-6311-6_8
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