Skip to main content

Electrical Transport and Magnetoconductivity in Doped Polypyrrole

  • Chapter
Book cover Science and Technology of Polymers and Advanced Materials

Abstract

Polypyrrole doped with Toluene-p-sulfonate (PPy (TOS)) has been prepared electrochemically at different current densities. It was found that, electrical conductivity (a) has a great dependence on the current density i.e., (σ = 0.17 and 50 S/cm at j= 0.5 and 7.5 mA/cm2 respectively), conductivity has been fitted according to Mott’s equation in a wide range of temperature from 18 K to 200 K with a good agreement in 3D-system. In addition, it was observed that, polypyrrole samples have a strong positive magnetoresistance at very low temperatures and it has a quadratic behavior at small magnetic fields, up to H= 5T.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. T. A. Skotheim, “Handbook of Conducting Polymers” (Marcel Dekker, N. Y 1986).

    Google Scholar 

  2. K. Kanazawa, A.F. Diaz, P.M. Grant, G.B. Street, G.P. Gardini and J.F. Kwak, “Polypyrrole: an Electrochemically Synthesized Conducting Organic Polymer”, Synth. Met., 1, 329 (1979/1980).

    Google Scholar 

  3. G.B. Street, J. Clarke, M. Kronubi, V. Lee, P. Pfluger, J. Scott and G. Weiser, “Preparation and Characterization of Neutral and Oxidized Polypyrrole Films”, Mol. Cryst. Liq. Cryst. 83, 1253 (1982).

    Article  Google Scholar 

  4. N.F. Mott and E.A. Davis, “Electronic Processes in Non-Cryst. Mater.” Clarendon, Oxford 1979.

    Google Scholar 

  5. K. Sato, M. Yamaura, T. Hagiwara, K. Murata and M. Tokumoto, “Study on the Electrical Conduction Mechanism of Polypyrrole Films”, synth. Met. 40, 35 (1991).

    Article  CAS  Google Scholar 

  6. M. Satoh, K. Kaneto and Y. Yoshino, “Dependence of Electrical and Mechanical Properties of Conducting Polypyrrole films on Conditions of Electrochemical Polymerization in an Aqueous Medium”, Synth. Met. 14, 289 (1986).

    Article  CAS  Google Scholar 

  7. T.F. Abou-Elazab, M.D. Migahed, H. Park, Y. Park, P. MacNeillis, T. Rabenau and S. Roth, “Magnetoresistance of Polypyrrole and Polyacetylene”, Synth. Met. 76, 281 (1996).

    Article  CAS  Google Scholar 

  8. M. Reghu, Y. Cao, D. Moses, and A.J. Heeger, “Counterion-induced processibility of polyaniline: Transport at the metal-insulator boundary”, Phys Rev. B47, 1758, 1993.

    Google Scholar 

  9. A.K. Meikap, A. Das, S. Chatterjee, M. Digar and S.N. Bhattachargya, “Electrical Transport in Doped Polypyrrole Films at low Temperature”, Phys. Rev. B47, 340 (1993).

    Google Scholar 

  10. A. Kurobe and H. Kamimura, “Correlation Effects on Variable Range Hopping Conduction and the Magnetoresistance”, J. Phys. Soc. Jpn. 51, 1904 (1982).

    Article  CAS  Google Scholar 

  11. B.I. Shklovskii and A.L. Efros “Electr. Proper, of Doped Semicond.”, (Springer-Verlag Berlin, 1984) p.212.

    Book  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1998 Springer Science+Business Media New York

About this chapter

Cite this chapter

Migahed, M.D., Fahmy, T., Roth, S. (1998). Electrical Transport and Magnetoconductivity in Doped Polypyrrole. In: Prasad, P.N., Mark, J.E., Kandil, S.H., Kafafi, Z.H. (eds) Science and Technology of Polymers and Advanced Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0112-5_36

Download citation

  • DOI: https://doi.org/10.1007/978-1-4899-0112-5_36

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-0114-9

  • Online ISBN: 978-1-4899-0112-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics