Abstract
Polypyrrole doped with Toluene-p-sulfonate (PPy (TOS)) has been prepared electrochemically at different current densities. It was found that, electrical conductivity (a) has a great dependence on the current density i.e., (σ = 0.17 and 50 S/cm at j= 0.5 and 7.5 mA/cm2 respectively), conductivity has been fitted according to Mott’s equation in a wide range of temperature from 18 K to 200 K with a good agreement in 3D-system. In addition, it was observed that, polypyrrole samples have a strong positive magnetoresistance at very low temperatures and it has a quadratic behavior at small magnetic fields, up to H= 5T.
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References
T. A. Skotheim, “Handbook of Conducting Polymers” (Marcel Dekker, N. Y 1986).
K. Kanazawa, A.F. Diaz, P.M. Grant, G.B. Street, G.P. Gardini and J.F. Kwak, “Polypyrrole: an Electrochemically Synthesized Conducting Organic Polymer”, Synth. Met., 1, 329 (1979/1980).
G.B. Street, J. Clarke, M. Kronubi, V. Lee, P. Pfluger, J. Scott and G. Weiser, “Preparation and Characterization of Neutral and Oxidized Polypyrrole Films”, Mol. Cryst. Liq. Cryst. 83, 1253 (1982).
N.F. Mott and E.A. Davis, “Electronic Processes in Non-Cryst. Mater.” Clarendon, Oxford 1979.
K. Sato, M. Yamaura, T. Hagiwara, K. Murata and M. Tokumoto, “Study on the Electrical Conduction Mechanism of Polypyrrole Films”, synth. Met. 40, 35 (1991).
M. Satoh, K. Kaneto and Y. Yoshino, “Dependence of Electrical and Mechanical Properties of Conducting Polypyrrole films on Conditions of Electrochemical Polymerization in an Aqueous Medium”, Synth. Met. 14, 289 (1986).
T.F. Abou-Elazab, M.D. Migahed, H. Park, Y. Park, P. MacNeillis, T. Rabenau and S. Roth, “Magnetoresistance of Polypyrrole and Polyacetylene”, Synth. Met. 76, 281 (1996).
M. Reghu, Y. Cao, D. Moses, and A.J. Heeger, “Counterion-induced processibility of polyaniline: Transport at the metal-insulator boundary”, Phys Rev. B47, 1758, 1993.
A.K. Meikap, A. Das, S. Chatterjee, M. Digar and S.N. Bhattachargya, “Electrical Transport in Doped Polypyrrole Films at low Temperature”, Phys. Rev. B47, 340 (1993).
A. Kurobe and H. Kamimura, “Correlation Effects on Variable Range Hopping Conduction and the Magnetoresistance”, J. Phys. Soc. Jpn. 51, 1904 (1982).
B.I. Shklovskii and A.L. Efros “Electr. Proper, of Doped Semicond.”, (Springer-Verlag Berlin, 1984) p.212.
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Migahed, M.D., Fahmy, T., Roth, S. (1998). Electrical Transport and Magnetoconductivity in Doped Polypyrrole. In: Prasad, P.N., Mark, J.E., Kandil, S.H., Kafafi, Z.H. (eds) Science and Technology of Polymers and Advanced Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0112-5_36
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DOI: https://doi.org/10.1007/978-1-4899-0112-5_36
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