Skip to main content
SpringerLink
Log in

Intercalation in oxides from 2D to 3D intercalation

  • Chapter
Chemical Physics of Intercalation

Part of the book series: NATO ASI Series ((NSSB,volume 172))

Abstract

The intercalation properties of graphite, transition metal dichalcogenides (TMDC) and clays have been intensively studied for at least twenty years. Till the eighties, stoichiometric AMO2 (A: alkali ion, M: transition element) sheet oxides have been mainly studied from a crystal chemistry point of view while only few works were devoted to Ax MO2 layer oxides1–6. During the last few years, numerous new results have been reported in this chemical field, stimulated by the potential interest of some of these compounds as positive electrode for high energy density batteries. This lack of interest in oxides as intercalation compounds arises certainly from the non existence of the fully deintercalated form MO2 with sheet structure. As it will be discussed in the following this property comes from the large electronegativity difference between the oxygen and the M element.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. J.P. Parant, R. Olazcuaga, M. Devalette, C. Fouassier and P. Hagenmuller, J. Solid State Chem., 3:1 (1971).

    Article  ADS  Google Scholar 

  2. C. Li, A.F. Reid and S. Saunders, J. Solid State Chem., 3:614 (1971).

    Article  ADS  Google Scholar 

  3. C. Fouassier, G. Matejka, J.M. Réau and P. Hagenmuller, J. Solid State Chem., 6:532 (1973).

    Article  ADS  Google Scholar 

  4. M. Jansen and R. Hoppe, Z. anorg. allg. Chem., 408:97 (1974)

    Article  Google Scholar 

  5. C. Delmas, C. Fouassier and P. Hagenmuller, J. Solid State Chem., 13:165 (1975).

    Article  ADS  Google Scholar 

  6. C. Delmas, M. Devalette, C. Fouassier and P. Hagenmuller, Mat. Res. Bull., 10:393 (1975).

    Article  Google Scholar 

  7. R. Hoppe, Bull. Soc. Chim. Fr., 1165 (1965).

    Google Scholar 

  8. R. Clos, M. Devalette, P. Hagenmuller, R. Hoppe and E. Paletta, C.R. Acad. Sc. F., 265:801 (1967).

    Google Scholar 

  9. R. Scholder and H. Glaser, Z. anorg. allg. Chem., 364:113 (1969).

    Article  Google Scholar 

  10. J. Hauck, Z. Naturforsch., 24b:252 (1969).

    Google Scholar 

  11. F. Stenner and R. Hoppe, Z. anorg. allg. Chem., 374:239 (1970).

    Article  Google Scholar 

  12. C. Delmas, C. Fouassier and P. Hagenmuller, Mat. Res. Bull., 11:1483 (1976).

    Article  Google Scholar 

  13. A. Leblanc-Soreau, M. Danot, L. Trichet and J. Rouxel, Mat. Res. Bull. 9:191 (1974).

    Article  Google Scholar 

  14. R. Hoppe and H. Sabrowsky, Z. anorg. allg. Chem., 339:144 (1965).

    Article  Google Scholar 

  15. R. Hoppe and H. Brunn, Rev. Chim. Min., 13:41 (1976).

    Google Scholar 

  16. C. Delmas, C. Fouassier and P. Hagenmuller, Mat. Res. Bull., 13:165 (1975).

    Google Scholar 

  17. P. Colombet, M. Danot and J. Rouxel, Mat. Res. Bull., 14:813 (1979).

    Article  Google Scholar 

  18. C. Delmas, J.J. Braconnier and P. Hagenmuller, Mat. Res. Bull., 17:117 (1982).

    Article  Google Scholar 

  19. A. Mendiboure, C. Delmas and P. Hagenmuller, Mat. Res. Bull., 19:1383 (1984).

    Article  Google Scholar 

  20. J. Rouxel, J. Solid State Chem., 17:223 (1976).

    Article  ADS  Google Scholar 

  21. R.D. Shannon, D.B. Rogers and C.T. Prewitt, Inorg. Chem., 10:713 (1971).

    Article  Google Scholar 

  22. C.T. Prewitt, R.D. Shannon and D.B. Rogers, Inorg. Chem., 10:719 (1971).

    Article  Google Scholar 

  23. D.B. Rogers, R.D. Shannon, C.T. Prewitt and J.L. Gillson, Inorg. Chem., 10:723 (1971).

    Article  Google Scholar 

  24. J.P. Doumerc, A. Ammar, A. Wichainchai, M. Pouchard and P. Hagenmuller J. Phys. Chem. Solids, 48:37 (1987).

    Article  ADS  Google Scholar 

  25. D.B. Rogers, R.J. Arnott, A. Wold and J.B. Goodenough, J. Phys. Chem. Solids, 24:347 (1963).

    Article  ADS  Google Scholar 

  26. C. Fouassier, C. Delmas and P. Hagenmuller, Mat. Res. Bull., 10:443 (1975).

    Article  Google Scholar 

  27. P.F. Bongers and U. Enz, J. Solid State Comm., 4:153 (1966).

    Article  ADS  MATH  Google Scholar 

  28. G.S. Rushbrooke and P.J. Wood, Molec. Phys., 6:409 (1963).

    Article  ADS  Google Scholar 

  29. C. Delmas, G. Le Flem, C. Fouassier and P. Hagenmuller, J. Phys. Chem. Solids, 39:55 (1978).

    Article  ADS  Google Scholar 

  30. J.L. Soubeyroux, D. Fruchart, J.C. Marmeggi, W.J. Fitzerald, C. Delmas and G. Le Flem, Phys. Status Sol., 67:633 (1981).

    Article  ADS  Google Scholar 

  31. J.P. Doumerc, A. Wichainchai, A. Ammar, M. Pouchard and P. Hagenmuller Mat. Res. Bull., 21:745 (1986).

    Article  Google Scholar 

  32. C. Delmas, A. Maazaz, C. Fouassier, J.M. Réau and P. Hagenmuller in “Fast Ion Transport in Solids”, ed. P. Vashista, C.N. Mundy and G.K. Shenoy, North Holland, New York (1979).

    Google Scholar 

  33. A. Maazaz, C. Delmas, C. Fouassier, J.M. Réau and P. Hagenmuller, Mat. Res. Bull., 14:329 (1979).

    Article  Google Scholar 

  34. L. Trichet and J. Rouxel, Mat. Res. Bull., 12:345 (1977).

    Article  Google Scholar 

  35. J. Rouxel, Mat. Res. Bull., 13:1425 (1978).

    Article  Google Scholar 

  36. T.A. Hewston and B.L. Chamberland, J. Phys. Chem. Solids, 48:97 (1987).

    Article  ADS  Google Scholar 

  37. P. Hagenmuller, A. Le Cerf and M. Onillon, C.R. Acad. Sci., 255:928 (1962).

    Google Scholar 

  38. A. Maazaz, C. Delmas and P. Hagenmuller, J. Incl. Phenom., 1:45 (1983).

    Article  Google Scholar 

  39. C. Delmas and C. Fouassier, Z. anorg. allg. Chem., 420:184 (1976).

    Article  Google Scholar 

  40. D.W. Murphy and P.A. Christian, Science, 205:651 (1979).

    Article  ADS  Google Scholar 

  41. S. Miyazaki, S. Kikkawa and M. Koizumi, Rev. Chim. Min., 19:301 (1982).

    Google Scholar 

  42. S. Miyazaki, S. Kikkawa and M. Koizumi, Synth. Met., 6:211 (1983).

    Article  Google Scholar 

  43. S. Kikkawa, S. Miyazaki and M. Koizumi, Mat. Res. Bull., 20:373 (1985).

    Article  Google Scholar 

  44. S. Kikkawa, S. Miyazaki and M. Koizumi, J. Solid State Chem., 62:35 (1986).

    Article  ADS  Google Scholar 

  45. K. Vidyasagar and J. Gopalakrishnan, J. Solid State Chem., 42:217 (1982).

    Article  ADS  Google Scholar 

  46. L.A. de Picciotto and M.M. Thackeray, Mat. Res. Bull., 19:1497 (1984).

    Article  Google Scholar 

  47. M.S. Whittingham, Prog. Solid State Chem., 12:1 (1978).

    Article  Google Scholar 

  48. “Intercalation Chemistry”, Ed. M.S. Whittingham and A.J. Jacobson, Academic Press, New York (1982).

    Google Scholar 

  49. K. Mizushima, P.C. Jones, P.J. Wiseman and J.B. Goodenough, Mat. Res. Bull., 15:783 (1980).

    Article  Google Scholar 

  50. L.A. de Picciotto and M.M. Thackeray, Solid State Ionics, 18/19:773 (1986).

    Article  Google Scholar 

  51. L.A. de Picciotto and M.M. Thackeray, Mat. Res. Bull., 20:1409 (1985).

    Article  Google Scholar 

  52. W.A. England, J.E. Birkett, J.B. Goodenough and P.J. Wiseman, J. Solid State Chem., 49:300 (1983).

    Article  ADS  Google Scholar 

  53. W.A. England, J.B. Goodenough and P.J. Wiseman, J. Solid State Chem., 49:289 (1983).

    Article  ADS  Google Scholar 

  54. C. Delmas, J.J. Braconnier and P. Hagenmuller, Mat. Res. Bull., 17:117 (1982).

    Article  Google Scholar 

  55. J.J. Braconnier, C. Delmas, C. Fouassier and P. Hagenmuller, Mat. Res. Bull., 15:1797 (1980).

    Article  Google Scholar 

  56. M.G. Thomas, W.I. David, J.B. Goodenough and P. Groves, Mat. Res. Bull., 20:1137 (1985).

    Article  Google Scholar 

  57. M.G. Thomas, P.G. Bruce and J.B. Goodenough, J. Electrochem. Soc., 132(7): 1521 (1985).

    Article  Google Scholar 

  58. M.G. Thomas, P.G. Bruce and J.B. Goodenough, Solid State Ionics, 17:13 (1985).

    Article  Google Scholar 

  59. C. Delmas and P.E. Werner, Acta Chem. Scand., A 32:329 (1978).

    Article  Google Scholar 

  60. A. Mendiboure, C. Delmas and P. Hagenmuller, Mat. Res. Bull., 19:1383 (1984).

    Article  Google Scholar 

  61. A. Maazaz and C. Delmas, C.R. Acad. Sci., 295:759 (1982).

    Google Scholar 

  62. J.J. Braconnier, C. Delmas and P. Hagenmuller, Mat. Res. Bull., 17:993 (1982).

    Article  Google Scholar 

  63. C. Delmas, J.J. Braconnier, C. Fouassier and P. Hagenmuller, Mat. Res. Bull., 3/4:165 (1981).

    Google Scholar 

  64. A. Mendiboure, C. Delmas and P. Hagenmuller, J. Solid State Chem., 57:323 (1985).

    Article  ADS  Google Scholar 

  65. J. Rouxel, M. Danot and J. Pichon, Bull. Soc. Chim. Fr., 3390 (1971).

    Google Scholar 

  66. J. Rouxel in “Intercalated Layered Materials”, Ed. by F.A. Levy, D. Reidel Publ. Comp. Dordrecht (1979).

    Google Scholar 

  67. J. Molenda, C. Delmas and P. Hagenmuller, Solid State Ionics, 9/10:431 (1983).

    Article  Google Scholar 

  68. J. Molenda, C. Delmas, P. Dordor and A. Stoklosa, Solid State Ionics, 12:473 (1984).

    Article  Google Scholar 

  69. J.M. Tarascon and G.W. Hull, Solid State Ionics, 22:85 (1986).

    Article  Google Scholar 

  70. A. Maazaz, thesis, University of Bordeaux, France (1982).

    Google Scholar 

  71. L.A. de Picciotto and M.M. Thackeray, Mat. Res. Bull., 20:187 (1985).

    Article  Google Scholar 

  72. P. Deniard, P. Chevalier, L. Trichet and J. Rouxel, Synth. Met., 5:141 (1983).

    Article  Google Scholar 

  73. M.M. Thackeray, P.J. Johnson, L.A. de Picciotto, P.G. Bruce and J.B. Goodenough, Mat. Res. Bull., 19:179 (1984).

    Article  Google Scholar 

  74. J.B. Goodenough, M.M. Thackeray, W.I. David and P.G. Bruce, Rev. Chim. Min., 21:435 (1984).

    Google Scholar 

  75. A. Mosbah, A. Verbaere and M. Tournoux, Mat. Res. Bull., 18:1375 (1983).

    Article  Google Scholar 

  76. R.J. Cava, D.W. Murphy, S. Zahurak, A. Santoro and R.S. Roth, J. Solid State Chem., 53:64 (1984).

    Article  ADS  Google Scholar 

  77. D.W. Murphy, F.J. Di Salvo, J.N. Carides and J.V. Waszczak, Mat. Res. Bull., 13:1395 (1978).

    Article  Google Scholar 

  78. D.E. Cox, R.J. Cava, D.B. Mc Whan and D.W. Murphy, J. Phys. Chem. Solids, 43:657 (1982).

    Article  ADS  Google Scholar 

  79. W.I. David, M.M. Thackeray, P.G. Bruce and J.B. Goodenough, Mat. Res. Bull., 19:99 (1984).

    Article  Google Scholar 

  80. H. Bode, K. Dehmelt and J. Witte, Electrochim. Acta, 11:1079 (1966).

    Article  Google Scholar 

  81. J.J. Braconnier, C. Delmas, C. Fouassier, M. Figlarz, B. Beaudouin and P. Hagenmuller, Rev. Chim. Min., 21:496 (1984).

    Google Scholar 

  82. J.J. Braconnier, Thesis University of Bordeaux (1983).

    Google Scholar 

  83. C. Delmas, J.J. Braconnier, Y. Borthomieu and P. Hagenmuller, Mat. Res. Bull., 1987 (in press).

    Google Scholar 

  84. A. Mendiboure and R. Schöllhorn, Rev. Chim. Min., 23:819 (1986).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Chimie du Solide du CNRS, Université de Bordeaux I, 351, cours de la Libération, 33405, Talence CEDEX, France

    Claude Delmas

Authors
  1. Claude Delmas
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. ESPCI, Paris, France

    A. P. Legrand

  2. Domaine Universitaire, Talence, France

    S. Flandrois

Rights and permissions

Reprints and permissions

Copyright information

© 1987 Springer Science+Business Media New York

About this chapter

Cite this chapter

Delmas, C. (1987). Intercalation in oxides from 2D to 3D intercalation. In: Legrand, A.P., Flandrois, S. (eds) Chemical Physics of Intercalation. NATO ASI Series, vol 172. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9649-0_11

Download citation

  • DOI: https://doi.org/10.1007/978-1-4757-9649-0_11

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-9651-3

  • Online ISBN: 978-1-4757-9649-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation