Abstract
The off-resonance rotating frame spin-lattice relaxation experiment represents a class of magnetic resonance techniques in which a low-power, continuous-wave radiofrequency (RF) field is applied off-resonance from a selected resonance. Application of such an irradiation field establishes nuclear spin polarization along an effective field inclined at an angle Θ away from the z axis of the rotating frame. In its original form, this approach was employed for the determination of the rotational correlation time, i.e., the rotational diffusion characteristics of a reorienting macromolecule (James et al., 1978; Schleich et al., 1989). More generally, the off-resonance rotating frame spin-lattice relaxation experiment can be thought of as a form of off-resonance saturation, in which a selected resonance is either completely or partially saturated. Viewed in these terms, the off-resonance rotating frame spin-lattice relaxation formalism, modified to include magnetization transfer phenomena, may be used to obtain chemical exchange kinetic and magnetic cross-relaxation information.
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Schleich, T., Caines, G.H., Rydzewski, J.M. (1992). Off-Resonance Rotating Frame Spin—Lattice Relaxation. In: Berliner, L.J., Reuben, J. (eds) In Vivo Spectroscopy. Biological Magnetic Resonance, vol 11. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9477-9_2
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