Abstract
The release of alkalis (sodium and potassium) and five ash matrix elements (silicon, aluminium, iron, calcium and magnesium) during the pyrolysis of Polish coal, Pittsburgh #8 coal, peat and two wood chips was studied with a heated grid reactor using heating conditions relevant to fluidised bed combustion and gasification. Mineral particles or any other super micron fragments were found not to be released from any of the fuels during the pyrolysis. Less than 5 % of any of the elements studied were released from the fuels, with an exception of iron from wood chips. Some iron may have been released from the wood chips (less than 14 % from whole tree chips and less than 8 % from wood chips fuel fraction). Less than 1 % of iron was released from coals and peat.
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References
Anthony, D.B., Howard, J.B., Meissuer, H.P. and Hottel, H.C. (1974). Rev. Sci. Instrum., 45, 992–996.
Berner, A. (1984). “Design Principles of AERAS Low Pressure Impactor.” In Liu, B.Y.H., Pui, D.Y.H., Fissan H.J. (Eds.), Aerosols: Science, Technology and Industrial Applications of Airborne Particles. New York: Elsevier.
Helble, J.J., Bool, L.E., Sarofim, A.F., Zeng, T., Peterson T.W., Gallien, D., Huffman, G.P., Huggins, F.E. and Shah. N. (1994). Fundamental Study of Ash Formation and Deposition: Effect of Reducing Stoichiometry. Quarterly Report No. 3. U.S. Department of Energy, DOE Contract No. DE-AC22–93PC92190.
Hillamo, R.E. and Kauppinen, E.I. (1991). “On the Performance of the Berner Low Pressure Impactor.” Aerosol Sci. Technol. 14, 33–47.
Kahata-Pendias, A. and Pendias, H. (1984). Trace elements in soils and plants. CRC Press, Inc., Boca Raton, Florida.
Kurkela, E., Stiihlberg, P., Laatikainen, J. and Simell, P. (1993). “Development of simplified IGCC processes for hiofuels–supporting gasification research at VTT.” Bioresource Technology 46, 37–48.
Kurki, M. (1982). “Main chemical characteristics of peat soils. Peatlands and their utilization in Finland.” Finnish Peatland Society–Finnish National Committee of the International Peat Society, Helsinki, 37–41.
Lind, T., Kauppinen, E., Jokiniemi, J.K., Maenhaut, W. and Pakkanen T. (1994). “Alkali metal behaviour in atmospheric circulating fluidised bed coal combustion.” In J. Williamson and F. Wigley (Eds.) “The Impact of Ash Deposition on Coal Fired Plants” Proceedings of the Engineering Foundation Conference, Taylor and Francis, 77–88.
Lind, T., Kauppinen, E., Maenhaut, W., Shah, A., and Huggins, F. (1995). “Ash vaporization in circulating fluidized bed coal combustion.” Accepted for publication in Aerosol Science and Technology.
Manzoori, A. R. and Agarwal, P. K. (1992). “The fate of organically bound inorganic elements and sodium chloride during fluidized bed combustion of high sodium, high sulphur low rank coals.” Fuel 71, 513–522.
McKeough, P., Pyykkönen, M. and Arpiainen, V. (1995). “Rapid Pyrolysis of Kraft Black Liquor. Part 2. Release of Sodium.” Paperi ja Puu-Paper and Timber 77, 39: 44.
Mengel, K. and Kirkby, E. A. (1987). Principles of plant nutrition. 4th Ed., International Potash Institute, Bern.
Patashnick, H. and Rupprecht, G. (1991). “Continuous PM-10 Measurements Using the Tapered Element Oscillating Microbalance.” Journal of Air Waste Management Association 4l, 1079–1083.
Raask, E. (1985). Mineral Impurities in Coal Combustion. Washington: Hemisphere Publishing Corporation.
Solomon, P.R., Fletcher, T.H. and Pugmire, R.J. (1993). “Progress in coal pyrolysis.” Fuel 72, 587–597.
Solomon, P.R., Serio, M.A. and Suuberg, E.M. (1992). “Coal Pyrolysis: Experiments, Kinetic Rates and Mechanisms.” Prog. Energy Combust. 18, 133–220.
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Valmari, T., Kauppinen, E.I., Lind, T., Kurkela, M., Moilanen, A., Zilliacus, R. (1996). Studies on Ash Species Release during the Pyrolysis of Solid Fuels with a Heated Grid Reactor. In: Baxter, L., DeSollar, R. (eds) Applications of Advanced Technology to Ash-Related Problems in Boilers. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9223-2_17
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DOI: https://doi.org/10.1007/978-1-4757-9223-2_17
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