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Part of the book series: Mathematical and Computational Chemistry ((MACC))

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Abstract

For the solutions of the Schrödinger equations the expectation value (quantum mechanical average value) of the energy is equal to the eigenvalue of the Hamiltonian Ĥ. In fact, the exact solutions are “energy eigenstates”:

$$\hat H\Psi = E\Psi $$
(2.1)

.

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© 2003 Springer Science+Business Media New York

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Mayer, I. (2003). General Theorems and Principles. In: Simple Theorems, Proofs, and Derivations in Quantum Chemistry. Mathematical and Computational Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-6519-9_2

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  • DOI: https://doi.org/10.1007/978-1-4757-6519-9_2

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4419-3389-8

  • Online ISBN: 978-1-4757-6519-9

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