Abstract
Using the fluorescence properties of several naphthalene derivatives in the presence and absence of quenchers, it was possible to characterize DAP- and AOT-micelles in cyclohexane. Based on simple fluorescence lifetime measurements, it is proposed that the aggregation mechanisms for both systems are identical. The meaning of the CMC is also discussed. The use of fluorescence quenching to obtain information on e.g. the mean aggregation number and on the solubilizate exchange between colliding micelles is discussed.
In all cases, the total quencher concentration, and not the quencher concentration in the waterpool, must be used. Exciplex formation with triethylamine and energy transfer to Tb3+, proved to be very good methods to localize the solubilized probes in the reverse micellar system.
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References
H.F. Eicke, Topics in Current Chemistry, Vol. 87 86 (1979).
J.H. Fendler, Acc. Chem. Res. Vol. 9: 153 (1976).
A.S. Kertes and H. Gutman, Surface and Colloid Sci., Ed. by Matijevic, John Wiley & Sons, N.Y., 8: 193–295 (1976).
A. Kitahara, “Cationic Surfactants”, Ed. by E. Jungerman, N.Y., 289–310 (1970).
G.D. Correll, R.N. Cheser, III, F. Nome, and J.H. Fendler, J. Am. Chem. Soc., 100: 1254 (1978).
H.F. Eicke, J.C.W. Shepherd and A. Steinemann, J. Colloid Interf. Sci., 56: 168 (1976).
U.K.A. Klein, D.J. Miller and M. Hauser, Spectrochim. Acta, 32A, 379 (1976); J. Chem. Soc. Faraday Trans. I, 73: 1654 (1977).
M. Wong and J.K. Thomas, “Micellization, Solubilization and Microemulsions”, Ed. by K.L. Mittal, Plenum Press N.Y., Vol. 2: 647 (1977).
M. Wong, J.K. Thomas and M. Gratzel, J. Am. Chem. Soc. 98: 2391 (1976).
S.S. Atik and J.K. Thomas, J. Am. Chem. Soc., 103: 3543 (1981); J. Am. Chem. Soc., 103: 4367 (1981); J. Phys. Chem., 85: 3921 (1981); J.Am. Chem. Soc., 103: 7403 (1981).
P.D.I. Fletcher and B.H. Robinson; Ber Bunsenges. Phys. Chem., 85: 863 (1981).
M.A.J. Rodgers and J.C. Becker, J. Phys. Chem., 84: 2762 (1980).
E. Gelade and F.C. De Schryver, J. Photochemistry, 18: 223 (1982).
A. Kitahara, Bull. Chem. Soc. Japan, 28: 234 (1955).
C.A. Martin and L.J. Magid, J. Phys. Chem., 85: 3938 (1981).
E. Geladé, N. Boens and F.C. De Schryver, J. Am. Chem. Soc., will be published in the issue of November 17.
ref. 2–4 in ref. 6.
S.P. Van and G.S. Hammond, J. Am. Soc., 100: 3895 (1978).
J.K. Thomas, Ace. Chem. Res., 10: 133 (1977).
M. Almgren, F. Grieser, J.K. Thomas, J. Am. Chem. Soc., 101: 2021 (1979).
J.R. Escabi-Perez, F. Nome and J.H. Fendler, J. Am. Chem. Soc., 99: 7749 (1977).
H.F. Eicke and H. Christen, Helv. Chim. Acta, 61: 2258 (1978).
M. Wong, J.K. Thomas and T. Nowak, J. Am. Chem. Soc., 99: 4730 (1977).
H.F. Eicke and J. Rehake, Helv. Chim. Acta, 59: 2883 (1976).
J.C. Dederen, M. Vander Auweraer and F.C. De Schryver, J. Phys. Chem., 85: 1198 (1981).
P.P. Infelta, M. Gratzel and J.K. Thomas, J. Phys. Chem., 78: 190 (1974).
M. Tachiya, Chem. Phys. Lett., 33: 289 (1975).
R.A. Day, B.H. Robinson, J.H.R. Clarke and T.V. Doherty, J. Chem. Soc., Faraday Trans. I: 132 (1979).
F.Y.F. Lo, B.M. Escott, E.J. Fendler, E.T. Adams,Jr., R.D. Larsen and P.W. Smith, J. Phys. Chem., 79: 2609 (1975).
N. Muller, J. Phys. Chem., 79: 287 (1975).
L.A. Fucugauchi, B. Djermouni, E.D. Handel and H.J. Ache, J. Am. Chem. Soc., 101: 2841 (1979).
H.F. Eicke and A. Denns, J. Colloid Interface Sci., 64: 386 (1978).
U. Hermann and Z.A. Schelley, J. Am. Chem. Soc., 101: 2665 (1979).
K. Tsujii, J. Sunamoto, F. Nome and J.H. Fendler, J. Am. Chem. Soc., 82: 423 (1978).
M. Van der Auweraer, J.C. Dederen, E. Gelade and F.C. De Schryver, J. Chem. Phys., 74: 1140 (1981).
M.P. Pileni, J.M. Furois, B. Hickel, C. Ferradini and J. Richault, poster presentation at the “International Symposium on Surfactants in Solution”, June–July 1982,Lund (Sweden).
19.a.-N. Muller, J. Colloid Interface Sci., 63: 383 (1978).
L. Magid, “Solution Chemistry of Surfactants”, Ed. by K.L. Mittal, Plenum Press N.Y., Vol. 1: 427 (1979).
R. Zana, “Solution Chemistry of Surfactants”, Ed. by K.L. Mittal, Plenum Press N.Y., Vol. 1: 455 (1979).
J.H. Fendler, F. Nome and H.C. Woert, J. Am. Chem. Soc., 96: 6745 (1974).
H.F. Eicke, “Micellization, Solubilization and Microemulsions”, Ed. by K.L. Mittal, Plenum Press N.Y., Vol. 1: 429 (1977).
H.F. Eicke, R. Hopmann and H. Christen, Ber. Bunsenges. Phys. Chem., 79: 667 (1975).
A. Denat, B. Gosse and J.P. Gosse, J. Electrostatics, 12: 197 (1982).
S. Muto, Y. Shimazaki and K. Meguro, J. Colloid Interface Sci., 49: 173 (1974).
A. Kitahara and K. Kon-no, “Micellization, Solubilization and Microemulsions”, Ed. by K.L. Mittal, Plenum Press N.Y., Vol. 2: 1675 (1977).
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Geladé, E., De Schryver, F.C. (1984). Fluorescence: A Method to Obtain Information About Reverse Micellar Systems. In: Luisi, P.L., Straub, B.E. (eds) Reverse Micelles. Forschung Soziologie. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-6424-6_14
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DOI: https://doi.org/10.1007/978-1-4757-6424-6_14
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