Abstract
Neutron diffraction is the most powerful tool to determine the hydrogen location in metal hydrides, and many investigations have been carried out. This paper reviews recent progress in the structural studies of the Va transition metal — hydrogen system using neutron diffraction.
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References
T. Schober and H. Wenzl, The systems NbH(D), TaH(D), VH(D): structures, phase diagrams, morphologies, methods of preparation, in; “Hydrogen in Metals II,” G. Alefeld and J. Völkl, ed, Springer-Verlag, Berlin-Heidelberg-New York (1978).
H. Asano and M. Hirabayashi, Hydrogen ordering in Va transition metal hydrides, Z. Phys. Chem. Neue Folge 114: 1 (1979).
V. A. Somenkov and S. S. Shilstein, Phase transitions of hydrogen in metals, Prog. Mat. Sci. 24: 267 (1980).
A. J. Maeland, Investigation of the vanadium-hydrogen system by X-ray diffraction techniques, J. phys. Chem. 68: 2197 (1964).
M. A. Pick and R. Bausch, The determination of the force-dipole tensor of hydrogen in niobium, J. Phys. F: Metal Phys. 6: 1751 (1976).
B. Stalinski, X-ray analysis and magnetic susceptibilities of tantalum hydrides, Bull. Acad. Polon. Sci. Cl. III 2: 245 (1954).
B. W. Roberts, A neutron diffraction study of VDx, Phys. Rev. 100: 1257 (1955).
W. G. Saba, W. E. Wallace, H. Sandmo, and R. S. Craig, Heat capacities and the residual entropy of Ta2H, J. chem. Phys. 35: 2148 (1961).
W. E. Wallace, Neutron diffraction data for Ta2D and the probable arrangement of the deuteriums in two of its polymorphic varieties, J. chem. Phys. 35: 2156 (1961).
V. A. Somenkov, A. V. Gurskaya, M. G. Zemlyanov, M. E. Kost, N. A. Chernoplekov, and A. A. Chertkov, Neutron scattering study of structures and phase transitions in niobium hydrides and deuterides, Soviet Phys. - Solid State 10: 1076 (1968).
A. Yu. Chervyakov, I. R. Entin, V. A. Somenkov, S. Sh. Shil’shtein, and A. A. Chertkov, Order-disorder transition in VD0.8, Soviet Phys. - Solid State 13: 2172 (1972).
V. A. Somenkov, A. V. Gurskaya, M. G. Zemlyanov, M. E. Kost, N. A. Chernoplekov, and A. A. Chertkov, Neutron-diffraction study of the structure and phase transformations of tantalum hydrides and deuterides, Soviet Phys. - Solid State 10: 2123 (1969).
V. A. Somenkov, I. R. Entin, A. Yu. Chervyakov, S. Sh. Shil’shtein, and A. A. Chertkov, Abnormal phase transition in the vanadium deuteride, V2D, Soviet Phys. - Solid State 13: 2178 (1972).
V. A. Somenkov, V. F. Petrunin, S. Sh. Shil’shtein, and A. A. Chertkov, Neutron-diffraction study of the decomposition and ordering in the niobium-hydrogen system, Soviet Phys. - Cryst. 14: 522 (1970).
V. F. Petrunin, V. A. Somenkov, S. Sh. Shil’shtein, and A. A. Chertkov, The structure of Ta2D, Soviet Phys. - Cryst. 15: 137 (1970).
V. A. Somenkov, A. Yu. Chervyakov, S. Sh. Shil’shtein, and A. A. Chertkov, Stepwise phase transitions in Ta4D3, Soviet Phys. Cryst. 17: 274 (1972).
V. A. Somenkov, Structure of hydrides, Ber. Bunsenges. Phys. Chem. 76: 733 (1972).
K. I. Hardcastle and T. R. P. Gibb, Jr., An X-ray diffraction investigation of the vanadium-deuterium system, J. phys. Chem. 76: 927 (1972).
D. G. Westlake, M. H. Mueller, and H. W. Knott, Structural transitions at low temperatures in vanadium deuterides, J. appl. Cryst. 6: 206 (1973).
H. Asano and M. Hirabayashi, Interstitial superstructures of vanadium deuterides, phys. stat. sol. (a) 15: 267 (1973).
R. R. Arons, H. G. Bohn, and H. Lütgemeier, Comparison of the V-H and V-D phase diagrams by means of NMR, J. Phys. Chem. Solids 35: 207 (1974).
M. Hirabayashi, Structural phase transitions of metal hydrides; V-H and V-D, Proc. JIMIS-2 Hydrogen in Metals, Suppl. Trans. Jpn. Inst. Met. 21: 49 (1980).
H. Asano, Y. Ishino, R. Yamada, and M. Hirabayashi, Interstitial superstructures in the Ta-D system, J. Solid State Chem. 15: 45 (1975).
I. Okada, H. Asano, and M. Hirabayashi, Refinement of the structure of (3-V2D by single crystal neutron diffraction, Proc. JIMIS-2 Hydrogen in Metals, Suppl. Trans. Jpn. Inst. Met. 21: 89 (1980).
I. Okada, Structures and phase transitions in the V-H(D) systems (in Japanese), Master Thesis, Tohoku University (1980).
H. Metzger, H. Jo, S. C. Moss, and D. G. Westlake, Single crystal X-ray study of the superstructure modulation and long-range order in V2D, phys. stat. sol. (a) 47: 631 (1978).
H. Asano, Y. Abe, and M. Hirabayashi, A neutron diffraction study of V2H, J. Phys. Soc. Jpn. 41: 974 (1976).
H. Asano, Y. Abe, and M. Hirabayashi, A calorimetric study of the phase transformation of vanadium hydrides VH0oe-VHo77, Acta Met. 24: 95 (1976).
H. Asano and M. Hirabayashi, Low-temperature phase transition near V3H2, phys. stat, sol. (a) 16: 69 (1973).
J. Wanagel, S. L. Sass, and B. W. Batterman, Low-temperature phase transformation in the vanadium-hydrogen system, phys. stat. sol. (a) 11: 767 (1972).
T. Schober and H. Wenzl, An electron microscope study of the lattice distortions in ordered (3-Ta2H alloys, Scripta Met. 10: 819 (1976).
H. Asano, Y. Ishikawa, and M. Hirabayashi, Single-crystal X-ray diffraction study on the hydrogen ordering in Ta2H, J. appl. Cryst, 11: 681 (1978).
H. Asano, K. Kishi, and M. Hirabayashi, Static displacement of Ta in Ta2H studied by single crystal X-ray and neutron diffraction, Proc. JIMIS-2 Hydrogen in Metals, Suppl. Trans. Jpn. Inst. Met. 21: 93 (1980).
M. Antonini and H. D. Carstanjen, Location of interstitial deuterium in TaDooe7 by channeling, phys. stat. sol. (a) 34: K153 (1976).
J. Takahashi, M. Koiwa, M. Hirabayashi, S. Yamaguchi, Y. Fujino, K. Ozawa, and K. Doi, A lattice location study of oxygen in vanadium by 1-MeV deuteron channeling, J. Phys. Soc. Jpn. 45: 1690 (1978).
K. Ozawa, S. Yamaguchi, Y. Fujino, O. Yoshinari, M. Koiwa, and M. Hirabayashi, Channeling studies on the trapping of deuterium in vanadium by oxygen interstitials, Nucl. Instr. and Meth. 149: 405 (1978).
K. Hiraga, T. Onozuka, and M. Hirabayashi, Location of oxygen, nitrogen and carbon atoms in vanadium determined by neutron diffraction, Mat. Sci. and Eng. 27: 35 (1977).
S. Yamaguchi, private communication.
O. Yoshinari, M. Koiwa, H. Asano, and M. Hirabayashi, Low frequency internal friction study on vanadium-deuterium alloys, Trans. Jpn. Inst. Met. 19: 171 (1978).
M. Kimura, M. Sugawara, M. Oyamada, Y.,Yamada, S. Tomiyoshi, T. Suzuki, N. Watanabe, and S. Takeda, Neutron Debye-Scherrer diffraction works using a linear electron accelerator, Nucl. Instr. and Meth. 71: 102 (1969).
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Asano, H., Hirabayashi, M. (1981). Neutron Diffraction Studies of Metal Hydrides. In: Bambakidis, G. (eds) Metal Hydrides. NATO Advanced Study Institutes Series, vol 76. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-5814-6_4
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DOI: https://doi.org/10.1007/978-1-4757-5814-6_4
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