Skip to main content
SpringerLink
Log in

SCTA and Adsorbents

  • Chapter
Sample Controlled Thermal Analysis

Part of the book series: Hot Topics in Thermal Analysis and Calorimetry ((HTTC,volume 3))

Abstract

The preparation, characterisation and pre-treatment (or “outgassing”) of technological adsorbents (for gas adsorption, liquid adsorption or heterogeneous catalysis) was among the two first applications of Sample Controlled Thermal Analysis (SCTA) (the other being the study of phase changes in metallic alloys [1]) and it was the topic of most papers published about SCTA in the sixties (with the exception of one paper on sintering [2]). This interest is still as vivid as ever and can be explained by the fragility of the surface state and porous texture of a number of these materials and by the difficulty to obtain highly homogeneous and reproducible adsorbents at the end of a thermal treatment. We shall see, indeed, that SCTA, mainly in the form of Controlled Rate Thermal Analysis (CRTA) can provide a reproducible thermal pathway to a given adsorbent state, may this be during adsorbent preparation where it is possible to isolate interesting intermediate states, or whilst outgassing prior to the adsorption application in question. Such reproducibility is obtained due to the ability to control and thus minimise (if the rate of transformation or outgassing is fixed at a low value) both temperature and pressure gradients within each individual grain as well as in the sample bed. A control of the temperature gradient allows the minimisation of hotspots in the sample bed in case the sample heating auto-accelerates.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 74.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 99.00
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. C.S. Smith, Trans. A.I.M.E. (Metal Division) 137 (1940) 23.

    Google Scholar 

  2. H. Palmour, D.R. Johnson, in “Sintering and Related Phenomena”, G.C. Kuczynski, N.A. Hooton and C.F. Gibbon (Eds.), Gordon and Breach, New-York (1967) 779.

    Google Scholar 

  3. H.C. Stumpf, A.S. Russell, J.W. Newsome and C.H. Tucker, Ind. Eng. Chem. 42 (1950) 1398–1403.

    Article  CAS  Google Scholar 

  4. S.J. Gregg and K.S.W. Sing, J. Phys. Chem. 55 (1951) 592 & 597.

    Article  CAS  Google Scholar 

  5. J.H. de Boer, J.M.H. Fortuin and J.J. Steggerda, Kkl. Nederl. Akad. Wetensch. Proc., B., 57 (1954) 434.

    Google Scholar 

  6. D. Papée and R. Tertian, Bull. Soc. Chim. Fr., (1955) 983.

    Google Scholar 

  7. J. Rouquerol, Thesis, Faculty of Sciences of Paris University, 19th November 1964 (Série A, No. 4348, No. d’ordre 5199).

    Google Scholar 

  8. F. Rouquerol, Thesis, Faculty of Sciences of Paris University, 20th December 1965 (Série A, No. 4654, No. d’ordre 5501).

    Google Scholar 

  9. J. Rouquerol, J. Fraissard, J. Elston and B. Imelik, J. Chim. Phys., 4 (1966) 607.

    Google Scholar 

  10. J. Mayet, J. Rouquerol, J. Fraissard and B. Imelik, Bull. Soc. Chim. Fr., (1966), 2805–11.

    Google Scholar 

  11. J. Rouquerol, J. Therm. Anal., 2 (1970) 123.

    Article  CAS  Google Scholar 

  12. F. Rouquerol, J. Rouquerol and B. Imelik, Bull. Soc. Chim. Fr., 10 (1970) 3816.

    Google Scholar 

  13. M. Ganteaume and J. Rouquerol, J. Therm. Anal., 3 (1971) 413–20.

    Article  CAS  Google Scholar 

  14. J. Rouquerol, J. Thermal Analysis, 5 (1973) 203–16A.

    Article  CAS  Google Scholar 

  15. M. Ganteaume, Thesis, Université de Provence, Marseille, 24th February 1973.

    Google Scholar 

  16. J. Rouquerol, F. Rouquerol and M. Ganteaume, J. Catal., 36 (1975) 99–110A.

    Article  CAS  Google Scholar 

  17. J. Rouquerol and M. Ganteaume, J. Therm. Anal., 11 (1977) 201–210A.

    Article  CAS  Google Scholar 

  18. J. Rouquerol, F. Rouquerol and M. Ganteaume, J. Catal., 57 (1979) 222–30A.

    Article  CAS  Google Scholar 

  19. F. Paulik, J. Paulik, R. Naumann, R. Köhnke and D. Petzold, Thermochim. Acta, 64 (1983).

    Google Scholar 

  20. M.H. Stacey, Langmuir, 3 (1987) 681.

    Article  CAS  Google Scholar 

  21. B.C. Lippens and J.H. de Boer, J. Catal., 4 (1965) 319.

    Article  CAS  Google Scholar 

  22. F. Rouquerol, J. Rouquerol and K.S.W. Sing, “Adsorption by powders and porous solids: principles, methodology and applications”, Academic Press, London, New-York (1999) 467 pages.

    Google Scholar 

  23. E.A. Dawson, G.M.B. Parkes, P.A. Barnes, M.J. Chinn and P.R. Norman, Thermochim. Acta, 355 (1999) 141–146.

    Article  Google Scholar 

  24. J. Díaz-Terán, P. Llewellyn, J. Rouquerol, A.J. López-Peinado and A. Jerez, Proceedings of the 6th Meeting of the Spanish Carbon Group, 23–25 oct. 2001, Cáceres-Mérida, Spain.

    Google Scholar 

  25. C. Sauerland, P.L. Llewellyn, Y. Grillet and F. Rouquerol, In: Proceedings of the 12th Int. Zeolite Conference, (M.M.J. Treacy, B.K. Marcus, M.E. Bisher & J.B. Higgins (Eds.), MRS, Warrendale (USA), 1999, pp. 1707–1714.

    Google Scholar 

  26. J. Rouquerol, Thermochim. Acta, 144 (1989) 209.

    Article  CAS  Google Scholar 

  27. N. Dufau, L. Luciani, F. Rouquerol and P. Llewellyn, J. Mat. Chem., 11 (4) (2001) 1300–1304.

    Article  CAS  Google Scholar 

  28. K. Peters, R. Carleer, J. Mullens and E.F. Vansant, Microporous Materials, 4 (1995) 475.

    Article  Google Scholar 

  29. M.T.J. Keene, R. Gougeon, R. Denoyel, P.L. Llewellyn, R.K. Harris and J. Rouquerol, J. Mat. Chem., 9 (1999) 2843–2850.

    Article  CAS  Google Scholar 

  30. L. Sicard, P.L. Llewellyn, J. Patarin and F. Kolenda, Micro. Meso. Mat., 44–45 (2001) 195–201.

    Article  Google Scholar 

  31. V.I. Bogillo and P. Staszczuk, J. Therm. Anal. Cal., 55 (1999) 493–510.

    Article  CAS  Google Scholar 

  32. V. Chevrot, P.L. Llewellyn, F. Rouquerol, J. Godlewski and J. Rouquerol, Thermochim. Acta, 360 (2000) 77–83.

    Article  CAS  Google Scholar 

  33. J. Goworek, W. Stefaniak and A. Dabrowski, Thermochim. Acta, 259 (1995) 87–94.

    Article  CAS  Google Scholar 

  34. J. Goworek and W. Stefaniak, Colloids Surfaces A, 134 (1998) 343–347.

    Article  CAS  Google Scholar 

  35. H. Naono and M. Hakuman, J. Coll. Interf. Sci., 145 (1991) 405.

    Article  CAS  Google Scholar 

  36. J. Goworek and W. Stefaniak, Colloids Surfaces A, 80 (1993) 251–256.

    Article  CAS  Google Scholar 

  37. J. Goworek, W. Stefaniak and A. Dabrowski, Thermochim. Acta, 259 (1995) 87–94.

    Article  CAS  Google Scholar 

  38. P. Staszczuk, J. Therm. Anal., 53 (1998) 597–616.

    Article  CAS  Google Scholar 

  39. J. Goworek, W. Stefaniak and M. Prudaczuk, Thermochim. Acta, 379 (2001) 117–121.

    Article  CAS  Google Scholar 

  40. J. Goworek and W. Stefaniak, Thermochim. Acta, 286 (1996) 199–207.

    Article  CAS  Google Scholar 

  41. J. Kristóf, R.L. Frost, W.N. Martens and E. Horwáth, Langmuir, 18 (2002) 1244–1249.

    Article  Google Scholar 

  42. J. Goworek and W. Stefaniak, in “Thermal Analysis of Active Carbons”, p. 39–46.

    Google Scholar 

  43. Z. Hubicki, J. Goworek and W. Stefaniak, Bull. Pol. Acad. Sci. Chem., 42 (2) (1997) 169–176.

    Google Scholar 

  44. J. Goworek, W. Stefaniak and W. Zgrajka, Mat. Chem. Phys., 59 (1999) 149–153.

    Article  CAS  Google Scholar 

  45. J. Goworek and W. Stefaniak, Colloids Surfaces A, 82 (1994) 71–75.

    Article  CAS  Google Scholar 

  46. J. Rouquerol, S. Bordère and F. Rouquerol, in “Thermal Analysis in the Geosciences”, W. Smykatz-Kloss, S. St. J. Warne (Eds.), Springer-Verlag, Berlin, 1991, pp. 134–150.

    Chapter  Google Scholar 

  47. J. Godlewski, A. Giordano, V. Chevrot, P. Llewellyn, F. Rouquerol and J. Rouquerol, CEA Technical Note No. DEC/SECA/LCG/98.003, June 1998.

    Google Scholar 

  48. M.J. Torralvo, Y. Grillet, F. Rouquerol and J. Rouquerol, J. Therm. Anal., 41 (1994) 1529.

    Article  CAS  Google Scholar 

  49. P.A. Barnes, G.M.B. Parkes, D.R. Brown and E.L. Charsley, Thermochim. Acta, 269/270 (1995) 665.

    Article  CAS  Google Scholar 

  50. F. Villiéras, L.J. Michot, G. Gérard, J.M. Cases and W. Rudzinski, J. Therm. Anal. & Cal., 55 (1999) 511–530.

    Article  Google Scholar 

  51. E.A. Fesenko, P.A. Barnes, G.M.B. Parkes, D.R. Brown and M. Naderi, J. Phys. Chem. B, 105 (2001) 6178–6185.

    Article  CAS  Google Scholar 

  52. L.J. Michot, F. Didier, F. Villiéras and J.M. Cases, Pol. J. Chem., (1997) 665–678.

    Google Scholar 

  53. J. Rivera-Utrilla, M.A. Ferro-Garcia, C. Moreno-Castilla, I. Baautista-Toledo and J.P. Joly, J. Chem. Soc. Farad. Trans. 91 (1995) 3213.

    Article  CAS  Google Scholar 

  54. M.A. Ferro-Garcia, J.P. Joly, J. Rivera-Utrilla and C. Moreno-Castilla, Langmuir, 11 (1995) 2648.

    Article  CAS  Google Scholar 

  55. J. Rouquerol, F. Rouquerol, M. Triaca and O. Cerclier, Thermochim. Acta, 85 (1985) 305.

    Article  CAS  Google Scholar 

  56. F. Rouquerol, J. Rouquerol, G. Thevand and M. Triaca, Surface Science, 162 (1985) 239.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. MADIREL Laboratory, CNRS-Université de Provence, Marseille, France

    P. Llewellyn, F. Rouquerol & J. Rouquerol

Authors
  1. P. Llewellyn
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. Rouquerol
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. Rouquerol
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Risø National Laboratory, Roskilde, Denmark

    O. Toft Sørensen

  2. MADIREL, CNRS-Université de Provence, Marseille, France

    J. Rouquerol

Rights and permissions

Reprints and permissions

Copyright information

© 2003 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Llewellyn, P., Rouquerol, F., Rouquerol, J. (2003). SCTA and Adsorbents. In: Sørensen, O.T., Rouquerol, J. (eds) Sample Controlled Thermal Analysis. Hot Topics in Thermal Analysis and Calorimetry, vol 3. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-3735-6_6

Download citation

  • DOI: https://doi.org/10.1007/978-1-4757-3735-6_6

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4419-5249-3

  • Online ISBN: 978-1-4757-3735-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation