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High-Temperature Coordination Chemistry of Group VIII

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Advances in Molten Salt Chemistry

Abstract

The bulk of our discussion is concerned with electronic spectroscopy but we shall indicate the various other methods available to help in the elucidation of the coordination of Group VIII metal ions at high temperatures. The two types of information which electronic spectroscopy can provide under favorable circumstances are the number and arrangement of ligands about the central metal and the distribution of electronic charge within the moiety, albeit the expression of the latter is usually restricted to a listing of the first few energy levels.

“When I use a word,” Humpty Dumpty said, in rather a scornful tone, “it means just what I choose it to mean—neither more nor less.”

“The question is,” said Alice, “whether you can make words mean so many different things.”

“The question is,” said Humpty Dumpty, “which is to be master—that’s all.”

L. Carroll

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Authors and Affiliations

  1. Department of Chemistry, University of Saskatchewan, Regina Campus, Regina, Saskatchewan, Canada

    Keith E. Johnson

  2. Department of Chemistry, University of Virginia, Charlottesville, Virginia, USA

    John R. Dickinson

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  1. Oak Ridge National Laboratory, Oak Ridge, Tennessee, USA

    J. Braunstein  & G. P. Smith  & 

  2. The University of Tennessee, Knoxville, Tennessee, USA

    Gleb Mamantov

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Johnson, K.E., Dickinson, J.R. (1973). High-Temperature Coordination Chemistry of Group VIII. In: Braunstein, J., Mamantov, G., Smith, G.P. (eds) Advances in Molten Salt Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0662-8_3

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