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Subpicosecond Time Resolved Multiphoton Ionization: Excited State Dynamics of CIS-Stilbene under Collision Free Conditions

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Abstract

We report the results of a novel subpicosecond measurement performed on a cis-stilbene in the vapor phase. As will be described below, we have extended a well-known pulsed laser technique1,2 into the 10−13 sec time regime, and choose to focus renewed scientific attention on the dynamics of stilbene photoisomerization. We believe this measurement will establish the technique of gas phase multiphoton ionization as a viable and potentially powerful subpicosecond probe of intramolecular dynamics.

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References

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© 1984 Springer Science+Business Media New York

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Greene, B.I., Farrow, R.C. (1984). Subpicosecond Time Resolved Multiphoton Ionization: Excited State Dynamics of CIS-Stilbene under Collision Free Conditions. In: Mandel, L., Wolf, E. (eds) Coherence and Quantum Optics V. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0605-5_122

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  • DOI: https://doi.org/10.1007/978-1-4757-0605-5_122

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-0607-9

  • Online ISBN: 978-1-4757-0605-5

  • eBook Packages: Springer Book Archive

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