Abstract
Stable intrinsic semiconductors, which exhibit conductivities of 0.1 S/cm without any doping process can be easily prepared by using our “shish-kebab” approach. Hereby stacked transition metal macrocycles [MacM(L)]n. with M e.g. Fe, Ru, Os and Mac = phthalocya- nine (Pc) or 2,3-naphthalocyanine (2,3-Nc) are used. The bridging ligands (L) are special heteroaromatic systems, e.g. s-tetrazine (tz), substituted tetrazines, triazine (tri), substituted triazines, but also special organic dinitriles, e.g. tetrafluoroterephthalic acid dinitrile, fuma- rodinitrile, dicyanoacetylene, and cyanogen. We report about the preparation and the characterization of the corresponding transition metal complexes [MacM(L)]n.
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References
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© 1996 Springer Science+Business Media New York
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Hanack, M. (1996). Bridged Macrocyclic Transition Metal-Oligomers, Synthesis and Electrical Properties. In: Pittman, C.U., Carraher, C.E., Zeldin, M., Sheats, J.E., Culbertson, B.M. (eds) Metal-Containing Polymeric Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0365-7_26
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DOI: https://doi.org/10.1007/978-1-4613-0365-7_26
Publisher Name: Springer, Boston, MA
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