Skip to main content
SpringerLink
Log in

Polymer-Supported Ziegler-Natta Catalysts for the Polymerization of α-Olefins and Butadiene

  • Chapter
Metal-Containing Polymeric Materials

  • 50 Accesses

Abstract

Over the past ten years, we have developed a series of polymer-supported Lewis acid catalysts for use in such synthetic reactions as esterification, ketone formation and etherification etc.1-8 These catalysts exhibited very good catalytic activity. The catalysts were also used for cationic polymerization of styrene and α-methylstyrene10-11. A polymer-supported Ziegler-Natta catalyst, polystyrene-titanium chloride-diethylaluminum chloride (PS-TiCl4/Et2AlCl) for the polymerization of isoprene was further developed.12In this chapter two polymer-supported Ziegler-Natta catalysts, PS-TiCl4/Et2AlCl and poly (biphenylaminomethylstyrene)-titanium chloride diethylaluminum chloride (PDPAS- TiCl4/Et2AlCl) are reported. Their use in polymerization and copolymerization of ethylene, 1, 3-butadiene, isoprene and isobutylene, is also described.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. (a). R. Ran, S. Jiang, and J. Shen, Chin. J. Appl. Chem., 2: 29 (1985); Chem. Abstr. 103: 27939v (1985); (b). J. Macromol. Sci.-Chem., A24(6): 669–679 (1987); Chem. Abstr. 105: 60145x (1987).

    Google Scholar 

  2. R. Ran, W. Pei, X. Jia, J. Shen, and S. Jiang, Chem. J. Chin. Univ., 7(7): 645-50 (1986); Chem. Abstr., 106(2): 6086m (1987).

    Google Scholar 

  3. (a). R. Ran, W. Pei, X. Jia, J. Shen, and S. Jiang, Chem. J. Chin. Univ., 7(7): 645–50 (1986); Chem. Abstr., 106(2): 6086m (1987); (b).Polymer Commun., 5: 379–383 (1986); Chem. Abstr., 108(3): 21080q (1988); (c). Polym. Commun., 6: 453–457 (1986); Chem. Abstr., 108(3): 21082s (1988); (d). Sci. Bull., 32(6): 388–394 (1987); Chem. Abstr., 108(5): 36846t (1988).

    Google Scholar 

  4. (a). R. Ran, X. Jia, W. Pei, and S. Jiang, Acta Sci. Nat. Univ. Pekin., 6: 29-35 (1986); Chem. Abstr., 108(3): 21088y (1988); (b). J. Mol. Catal., 2(2): 112–118 (1988); Chem. Abstr., 111 (1): 7011y (1989).

    Google Scholar 

  5. (a). R. Ran, W. Pei, X. Jia, and X. Wu, J. Org. Chem., 4: 286-272 (1987); Chem. Abstr., 108(17): 150013u (1988); (b). Acta Polym. Sinica, 6: 67–70 (1988); Chem. Abstr., 110 (1): 7170d (1989).

    Google Scholar 

  6. R. Ran and J. Shen, J. Macromol. Sci. Chem., A25(8): 923–933 (1988); Chem. Abstr., 109: 189478v (1988).

    Google Scholar 

  7. R. Ran and G. Mao, J. Macromol. Sci. Chem., A27(2): 125–136 (1990); Chem. Abstr., 113(2): 6953m (1990).

    Google Scholar 

  8. R. Ran and D. Fit, J. Macromol. Sci. Chem., A27(5): 625–636 (1990).

    Article  Google Scholar 

  9. R. Ran, D. Fu, J. Shen, and Q. Wang, J. Polym. Sci. Part A: Polym Chem., 31: 2915–2921 (1993).

    Article  CAS  Google Scholar 

  10. R. Ran, X. Jia, and S. Jiang, Petrochem. Tech., 17(1): 15–20 (1988); Chem. Abstr., 108(20): 168034m (1988).

    Google Scholar 

  11. R. Ran, X. Jia, M. Li, and S. Jiang, J. Macromol. Sci. Chem., A25(8): 907–22 (1988); Chem. Abstr., 109: 150080j (1988).

    Google Scholar 

  12. R. Ran, J. Polym. Sci. Part A: Polym. Chem., 31: 1561–1569 (1993).

    Article  CAS  Google Scholar 

  13. R. Fierri, and J. C. W. Chien, J. Polym. Sci. Part A: Polym. Chem., 32: 661–673 (1994).

    Article  Google Scholar 

  14. S. Lee, K. W. S. Brian, M. P. Ripplinger, J. J. Wooster, et al, US Patent 5231151 A 930727.

    Google Scholar 

  15. K. E. Mitchell, D. C. Miller, D. W. Godbehere, and G. R. Hawley, US Patent 5,235,011 A 930831.

    Google Scholar 

  16. D. Hara, M. Sato, and M. Mori, Eur. Patent EP 530814 A1 930310.

    Google Scholar 

  17. S. I. Woo, and I. I. Kim, US patent 5192729 A 930309.

    Google Scholar 

  18. A. Sano, K. Suzuki, et al, Eur. Patent EP 507504 A2 921007.

    Google Scholar 

  19. J. C. A. Bailly, P. Behue, Eur. Patent EP 437080 A1 910717.

    Google Scholar 

  20. D. E. Gessell, D. P. Hosman, US Patent 4945142 A 900731.

    Google Scholar 

  21. R. Quijada, A. M. R. Wanderley, Stud. Surf. Sci. Catal., 25: 419–29 (1986).

    Article  CAS  Google Scholar 

  22. Y. Li and D. Jun, J. Macromol. Sci. -Chem., A24: 227 (1987).

    Article  Google Scholar 

  23. G. M. Chemenko, E. I. Tinyakov, Ts. V. Kakuliya, L. M. Khananashvili, Yu. V. Novikov, and M. E. Volipin, Vysokomol. Soedin. Ser. B, 25: 919 (1983).

    Google Scholar 

  24. S. A. Bedell, W. M. Coleman, and W. R. Howell, Jr., U. S. Pat., 4,623,707 (1980).

    Google Scholar 

  25. J. Collomb, D. C. Duran, L. Havas, and F. R. M. Morerol, Eur. Pat. Appl., EP 211,624 (1987).

    Google Scholar 

  26. Dow Chemcal Co.,Neth. Appl. NL 85 02,580 (1987).

    Google Scholar 

  27. T. Yano, T. Inoue, S. Ikai, M. Shimizu, Y. Kai, and M. Tamura, J. Polym. Sci. Polym. Chem. Ed., 26: 457-467, 477-490 (1988).

    Google Scholar 

  28. R. Spitz, L. Duvanel, and A. Guyot, Makromol. Chem., 189: 549 (1988).

    Article  CAS  Google Scholar 

  29. J. C. W. Chien and Y. L. Hu, J. Polym. Sci. Part A: Polym. Chem., 25: 2847, 2881 (1987).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University/Industry Chemical Research Center, Mississippi State University, Mississippi State, MS, 39762, USA

    Ruicheng Ran & Charles U. Pittman Jr.

Authors
  1. Ruicheng Ran
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Charles U. Pittman Jr.
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Mississippi State University, Mississippi State, Mississippi, USA

    Charles U. Pittman Jr.

  2. Florida Atlantic University, Boca Raton, Florida, USA

    Charles E. Carraher Jr.

  3. City University of New York, New York, New York, USA

    Martel Zeldin

  4. Rider College, Lawrenceville, New Jersey, USA

    John E. Sheats

  5. Ohio State University, Columbus, Ohio, USA

    Bill M. Culbertson

Rights and permissions

Reprints and permissions

Copyright information

© 1996 Springer Science+Business Media New York

About this chapter

Cite this chapter

Ran, R., Pittman, C.U. (1996). Polymer-Supported Ziegler-Natta Catalysts for the Polymerization of α-Olefins and Butadiene. In: Pittman, C.U., Carraher, C.E., Zeldin, M., Sheats, J.E., Culbertson, B.M. (eds) Metal-Containing Polymeric Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0365-7_19

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-0365-7_19

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-8018-4

  • Online ISBN: 978-1-4613-0365-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation