Abstract
Soluble polysilanes are most commonly prepared using the Wurtz type reaction between dichloroorganosilanes and molten sodium metal in refluxing toluene1 or by the action of sodium dispersions in refluxing diethylether.2
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References
R.D.Miller and J.Michl, Chem.Rev., (1989), 89, 1361 and references therein.
R.H.Cragg, R.G.Jones, A.C.Swain and S.J.Webb, J.Chem.Soc.,Chem.Commun., (1990), 1147.
P.Trefonas, R.West, R.D.Miller and D.Hofer, J.Polym.Sci., Polym.Lett.Ed., (1983), 21, 823.
P.Trefonas, R.West and R.D.Miller, J.Am.Chem.Soc., (1985), 107, 2737.
R.West, L.D.David, P.L.Djurovich, K.L.Stearly, K.S.V.Srinivasan and H.Yu, J.Am.Chem.Soc., (1981), 103, 7352.
R.West, L.D.David, P.I.Djurovich, H.Yu and R.Sinclair, Ceram.Bull., (1983), 62, 899.
S.Gauthier and D.Worsfold, Macromolecules, (1989), 22, 2213.
R.D.Miller, J.Rabolt, R.Sooriyakumaran, W.Fleming, G.N.Fickes, B.L.Farmer and H.Kuzmany, Inorganic and Organometallic Polymers; M.Zeldin, K.H.Wynne, H.R. Allcock, Eds, ACS Symposium Series; Am.Chem.Soc.:Washington, DC, (1988); Vol. 360, pp 43–60.
R.West, A.R. Wolff and D.J.Peterson, J.Radiat. Curing, (1986), 13, 35.
A.R. Wolff and R. West, Applied Organomet. Chem., (1987), 1, 7.
S.Yajima, Y.Hasegawa, J.Hayashi and M.Iiomora, J.Mater.Sci., (1980), 15, 720.
S.Yajima, J.Hayashi and M.Omori, Chem.Lett, (1975), 931.
J.P. Wesson and T.C.Williams, J.Polym.Sci.,Polym.Chem.Ed., (1980), 15, 720.
J.P.Wesson and T.C.Williams, ibid., (1981), 19, 65.
T.Uhsirogauchi, T.Tada and H.Watanabe, Proceedings of Conference on RadiationCuring Ashia, (1986), 101.
P.Trefonas, P.I.Djurovich, X.-H.Zhang, R.West, R.D.Miller and D.Hofer, J.Polym.Sci., Polym.Lett.Ed., (1983), 21, 819.
X.-H.Zhang and R.West, J.Polym.Sci.,Polym.Chem.Ed., (1984), 22, 159.
X.-H.Zhang and R.West, ibid., (1984), 22, 225.
H.Stuger and R.West, Macromolecules, (1985), 18, 2349.
S.Ho.Yi, N.Maeda, T.Suzuki and H.Sato, Polymer J, (1992), 24, 865.
R.D.Miller, D.Thompson, R.Sooriyakumaran and G.N.Fickes, J.Polym.Sci.,Polym.Chem.Ed., (1991), 29, 813.
L.A.Harrah and J.M.Zeigler, Macromolecules, (1987), 20, 2037.
R.Horiguchi, Y.Onishi and S.Hayase, ibid, (1988), 21, 304.
H.Ban, K.Sukegawa and S.Tagawa, ibid, (1987), 21, 304.
R.E.Benfield, RH.Cragg, R.G.Jones, A.C.Swain, S.J.Webb and M.J.Went, Polymer, in press.
T.Seki, T.Tamaki and K.Ueno, Macromolecules, (1992), 25, 3825.
B.L.Van Duisen, A.Sivak, B.M.Goldschmidt, C.Katz and S.Melchionne, J.Natl.Cancer Inst. (1969), 43, 481.
M.E.Wright, E.G.Toplikar and S.A.Svejda, Macromolecules, (1991), 24, 5879.
H.Sakurai and F.Kondo, J.Organomet.Chem., (1975), 92, C46.
C.U.Pittman and R F.Felis, J.Organometallic.Chem., (1974), 72, 389.
H.Sakurai, persional communication.
H.K.Kim and K.Matyjaszewski, J.Polym.Sci., Part A: Polym.Chem, (1993), 31, 299.
Ch.Elschenbroich and A.Salzer, Organometallics,VCH Verlagsgesellschaft/VCH Publishers, Weinheim/New York (1989)
S.Bhaduri, H.Khwaja and V.Khanwalkar, J.Chem.Soc., Dalton Trans., (1981), 445
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Swain, A.C., Holder, S.J., Jones, R.G., Wiseman, A.J., Went, M.J., Benfield, R.E. (1996). Chemical Modifications of Halomethylated Poly(Methylphenylsilane): A New and Facile Route to Functionalized Polysilanes. In: Pittman, C.U., Carraher, C.E., Zeldin, M., Sheats, J.E., Culbertson, B.M. (eds) Metal-Containing Polymeric Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0365-7_12
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DOI: https://doi.org/10.1007/978-1-4613-0365-7_12
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