Abstract
Groundwater resources are mainly used as the supply of drinking water in Slovakia (87.3% of inhabitants are supplied with drinking water from underground resources), of which approximately 22% of this amount has to be treated. Water treatment is mostly needed for the removal of iron and/or manganese. Concentrations of dissolved iron and manganese are evaluated every year within the groundwater monitoring done by the Slovak Hydrometeorological Institute (SHMI) for the whole territory of Slovakia.
The presence of iron and manganese compounds in water creates technological problems, failures of water supply systems and deterioration of water quality with respect to sensory properties. Also, if these waters are slightly over-oxidized, unfavourable incrustations are formed.
The objective of the pilot plant tests in the water treatment plant Kúty was to verify the efficiency of manganese and iron removal from water with the use of different filtration materials with MnO2 layer on the surface – Klinopur-Mn, Greensand and Cullsorb M.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Ministry of Environment of the Slovak Republic (2012) Water management in the Slovak Republic in 2012 (Blue Report). Prepared by Water Research Institute, Bratislava 2013, p 23 (in Slovak). http://www.minzp.sk/files/sekcia-vod/modra-sprava-2012-slovenska.pdf
(2017) www.enviroportal.sk http://www1.enviroportal.sk/indikatory/detail.php?id_indikator=1624
Čaučík P, Leitmann Š, Možiešiková K, Sopková M, Molnár Ľ, Bodácz B, Lehotová D, Mada I (2013) Balance of water management. Water balance of groundwater quality for 2012. SHMI, Bratislava, 318 p (in Slovak)
Lieskovská Z, Némethová M et al (eds) (2016) Report on the State of the Environment of the Slovak Republic in 2015. The Ministry of the Environment of the Slovak Republic, Slovak Environmental Agency, Bratislava, p 236. ISBN 978-80-89503-60-5
Rapant S, Vrana K, Bodiš D (1996) Geochemical atlas of Slovakia-part I. Groundwater. Ministry of the Environment of the Slovak Republic, Geological Survey of Slovak Republic, Bratislava, p 127. ISBN 80-85314-67-3
Barloková D, Ilavský J (2012) Modified clinoptilolite in the removal of iron and manganese from water. Slovak J Civil Eng 20(3):1–8. https://doi.org/10.2478/v10189-012-0012-9
Pitter P (2009) Hydrochemie, 4th edn. Institute of Chemical Technology Press, Prague, 568 pp, (in Czech)
Edzwald JK (2011) Water quality and treatment. A handbook of drinking water, 6th edn. AWWA, McGraw-Hill Companies, New York, 1696 pp
Stumm W, Morgan JJ (1996) Aquatic chemistry. Wiley, New York, 1022 pp
Scheffer F, Schachtschabel P (1989) Lehrbuch der Bodenkunde. Enke Verlag, Stuttgart, 491 pp
Brezonik PL, Arnold WA (2011) Water chemistry: an introduction to the chemistry of natural and engineered aquatic systems. Oxford University Press, New York, 809 pp
Mouchet P (1992) From conventional to biological removal of iron and manganese in France. J AWWA 84(4):158–167
Katsoyiannis IA, Zouboulis AI (2004) Biological treatment of Mn(II) and Fe(II) containing groundwater: kinetic considerations and product characterization. Water Res 38(7):1922–1932
Trace Inorganic Substances Committee (1987) Committee report: research needs for the treatment of iron and manganese. J AWWA 79:119–122
Sommerfeld EO (2007) Iron and manganese removal handbook. AWWA, Denver, 172 pp
Buamah R, Petrusevski B, Schippers JC (2008) Adsorptive removal of manganese(II) from the aqueous phase using iron oxide coated sand. J Water Supply Res Technol-AQUA 57:1–11
Barloková D, Ilavský J (2010) Removal of iron and manganese from water using filtration by natural materials. Polish J Environ Stud 19:1117–1122. http://www.pjoes.com/pdf/19.6/1117-1122.pdf, 2017
Doula KK (2006) Removal of Mn2+ ions from drinking water by using Clinoptilolite and a Clinoptilolite-Fe oxide system. Water Res 40:3167–3176
Knocke WR, Van Benschoten JE, Keanny MJ, Soborski AW, Reckhow DA (1991) Kinetics of manganese (II) and iron (II) oxidation by potassium permanganate and chlorine dioxide. J AWWA 83:80–87
Knocke WR, Occiano S, Hungate R (1991) Removal of soluble manganese by oxide-coated filter media: sorption rate and removal mechanism issues. J AWWA 83:64–69
Knocke WR, Hamon JR, Thompson CP (1988) Soluble manganese removal on oxide-coated filter media. J AWWA 80:65–70
Merkle PB, Knocke WR, Gallagher DL, Solberg T (1996) Characterizing filter media mineral coatings. J AWWA 88:62–73
Bruins JH (2016) Manganese removal from groundwater. Role of biological and physico-chemical autocatalytic processes. Dissertation of the Delft University of Technology and of the Academic Board of the UNESCO-IHE Institute for Water Education. CRC Press/Balkema, Leiden, The Netherlands, 163 p
Jeż-Walkowiak J, Dymaczewski Z, Weber L (2015) Iron and manganese removal from groundwater by filtration through a chalcedonite bed. Water Supply Res Technol-AQUA 64(1):19–34
Taffarel SR, Rubio J (2010) Removal of Mn2+ from aqueous solution by manganese oxide coated zeolite. Miner Eng 23:1131–1138
Olańczuk-Neyman K, Częścik P, Łasińska E, Bray R (2001) Evaluation of the effectivity of selected filter beds for iron and manganese removal. Water Sci Technol Water Supply 1(2):159–165
Bruins JH, Petrusevski B, Slokar YM, Kruithof JC, Kennedy MD (2015) Manganese removal from groundwater: characterization of filter media coating. Desalin Water Treat 55(7):1851–1863
Bruins JH, Petrusevski B, Slokar YM, Huysman K, Joris K, Kruithof JC, Kennedy MD (2015) Reduction of ripening time of full-scale manganese removal filters with manganese oxide-coated media. J Water Supply Res Technol-AQUA 64(4):434–441. https://doi.org/10.2166/aqua.2015.117
Coffey BM, Gallagher DL, Knocke WR (1993) Modeling soluble manganese removal by oxide-coated filter media. J Environ Eng 119:679–695
Hargette AC, Knocke WR (2001) Assessment of fate of manganese in oxide-coated filtration systems. J Environ Eng 127:1132–1138
Merkle PB, Knocke WR, Gallagher DL (1997) Method for coating filter media with synthetic manganese oxide. J Environ Eng 123:642–649
Merkle PB, Knocke WR, Gallagher DL, Little JC (1997) Dynamic model for soluble Mn2+ removal by oxide-coated filter media. J Environ Eng 123:650–658
Islam AA, Goodwill JE, Bouchard R, Tobiason JE, Knocke WR (2010) Characterization of filter media MnOx(s) surfaces and Mn removal capability. J AWWA 102:71–83
Kim J, Jung S (2008) Soluble manganese removal by porous media filtration. Environ Technol 29:1265–1273
Chen L, Zhang J, Zheng X (2016) Coupling technique for deep removal of manganese and iron from potable water. Environ Eng Sci 33(4):261–269
Tiwari D, Yu MR, Kim MN, Lee SM, Kwon OH, Choi KM, Lim GJ, Yang JK (2007) Potential application of manganese coated sand in the removal of Mn(II) from aqueous solutions. Water Sci Technol 56:153–160
Inglezakis VJ, Doula KK, Aggelatou V, Zorpas AA (2010) Removal of iron and manganese from underground water by use of natural minerals in batch mode treatment. Desalin Water Treat 18:341–346
Buamah R, Petrusevski B, de Ridder D, van de Wetering TSCM, Shippers JC (2009) Manganese removal in groundwater treatment: practice, problems and probable solutions. Water Sci Technol Water Supply 9:89–98
Rose P, Hager S, Glas K, Rehmann D, Hofmann T (2017) Coating techniques for glass beads as filter media for removal of manganese from water. Water Sci Technol Water Supply 17:95–106
Hamilton G, Chiswell B, Terry J, Dixon D, Sly L (2013) Filtration and manganese removal. J Water Supply Res Technol AQUA 62:417–425
Birm, Pyrolusite, Greensand – Osmo Sistemi (2017) www.osmosistemi.it. http://www.osmosistemi.it/index.php?option=com_content&view=article&id=14&Itemid=126&lang=en
Barloková D, Ilavský J, Sokáč M (2015) Modified zeolites in ground water treatment. GeoSci Eng LXI(1):10–17. ISSN 1802-5420
Barloková D (2008) Natural zeolites in the water treatment process. Slovak J Civil Eng 16(2):8–12. https://www.svf.stuba.sk/buxus/docs/sjce/2008/2008_2/file1.pdf, 2017
(2017) http://www.zeoclay.eu/domain/zeoclay/files/klinomangan-1000-data-sheet.pdf
Acknowledgements
The technological trials were performed within the APVV-15-0379 grant project and VEGA 1/0400/15 project.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 Springer International Publishing AG
About this chapter
Cite this chapter
Barloková, D., Ilavský, J. (2018). Groundwater: An Important Resource of Drinking Water in Slovakia. In: Negm, A., Zeleňáková, M. (eds) Water Resources in Slovakia: Part I. The Handbook of Environmental Chemistry, vol 69. Springer, Cham. https://doi.org/10.1007/698_2017_215
Download citation
DOI: https://doi.org/10.1007/698_2017_215
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-92852-4
Online ISBN: 978-3-319-92853-1
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)