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Physical and Inorganic Chemistry pp 145–192Cite as

Subhalides of tellurium

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Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 111))

Abstract

The tellurium subhalides represent a group of recently discovered compounds which have been investigated by the methods of solid-state and structural chemistry. Because of their high tellurium content and their crystal structures containing homonuclear tellurium connections they have attained significance as “modified tellurium structures”. As a consequence, tellurium subhalides have been the subject of various investigations in the fields of solid-state and chemical physics.

In this paper a short survey of the group of tellurium halides is followed by detailed information on phase relations, preparation, crystal growth, and crystal structures of tellurium subhalides. Mössbauer investigations as well as optical, photoelectric, and electrical properties of the respective compounds are discussed. Solid-state galvanic cells containing tellurium subhalides have enabled the precise determination of relevant thermodynamic data.

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Authors and Affiliations

  1. Institut für Anorganische Chemie und Strukturchemie, Universität Düsseldorf, Universitätsstr. 1, D-4000, Düsseldorf, FRG

    Rüdiger Kniep

  2. Max-Planck-Institut für Festkörperforschung, Heisenbergstr. 1, D-7000, Stuttgart 80, FRG

    Albrecht Rabenau

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  1. Rüdiger Kniep
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  2. Albrecht Rabenau
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© 1983 Springer-Verlag

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Kniep, R., Rabenau, A. (1983). Subhalides of tellurium. In: Physical and Inorganic Chemistry. Topics in Current Chemistry, vol 111. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-12065-3_3

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  • DOI: https://doi.org/10.1007/3-540-12065-3_3

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