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  • Book
  • © 1994

Carbon-Centered Radicals I

Editors:

Part of the book series: Landolt-Börnstein: Numerical Data and Functional Relationships in Science and Technology - New Series (LANDOLT 3, volume 18a)

Part of the book sub series: Molecules and Radicals (LANDOLT 2)

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Table of contents (61 chapters)

  1. 1.3.5 Acyl radicals

    • R. F. C. Claridge
    Pages 62-63
  2. 1.3.6 Radicals with 7 conjugated electrons

    • R. F. C. Claridge
    Pages 63-63
  3. 1.3.8 Radicals with 13 conjugated electrons

    • R. F. C. Claridge
    Pages 64-75
  4. 1.3.9 Radicals with 19 conjugated electrons

    • R. F. C. Claridge
    Pages 75-75
  5. References for 1

    • R. F. C. Claridge
    Pages 76-77
  6. 2.0 Introduction

    • E. Roduner, R. Crockett
    Pages 79-80
  7. 2.1 Primary alkyl radicals

    • E. Roduner, R. Crockett
    Pages 80-88
  8. 2.2 Noncyclic secondary alkyl radicals

    • E. Roduner, R. Crockett
    Pages 97-110
  9. [CCl3] - [C4H9]

    • E. Roduner, R. Crockett
    Pages 111-125
  10. [C4H9] - [C10H17O4]

    • E. Roduner, R. Crockett
    Pages 126-140
  11. 2.4 Cyclic and bicyclic radicals

    • E. Roduner, R. Crockett
    Pages 141-155
  12. 2.5 Benzyl radicals

    • E. Roduner, R. Crockett
    Pages 155-158
  13. 2.6 Vinyl, acyl and phenyl radicals

    • E. Roduner, R. Crockett
    Pages 158-168
  14. References for 2

    • E. Roduner, R. Crockett
    Pages 169-170
  15. 3.0 Introduction

    • A. L. J. Beckwith, S. Brumby
    Pages 171-171
  16. 3.1 Fragmentation reactions

    • A. L. J. Beckwith, S. Brumby
    Pages 172-181
  17. 3.2.1 Aryl migration

    • A. L. J. Beckwith, S. Brumby
    Pages 182-182
  18. 3.2.2 Vinyl migration

    • A. L. J. Beckwith, S. Brumby
    Pages 183-184
  19. 3.2.3 Hydrogen-atom migration

    • A. L. J. Beckwith, S. Brumby
    Pages 184-190
  20. 3.2.4 Heteroatom migration

    • A. L. J. Beckwith, S. Brumby
    Pages 190-193

About this book

Free radicals, which are key intermediates in many thermal, photochemical and radiation processes, are important for a proper understanding of fundamental natural processes and the successful development of organic syntheses. After about one decade volume II/18 serves as a supplement and extension to volume II/13 and covers rate constants and other kinetic data of free radical reactions in liquids. Furthermore II/18 contains new chapters on reactions of radicals in excited states and of carbenes, nitrenes and analogues. Selected species in aqueous solutions for which other compilations are available were deliberately omitted as before, and for the same reason electron transfer equilibria of organic radicals were not covered.

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