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MWW-Type Titanosilicate

Synthesis, Structural Modification and Catalytic Applications to Green Oxidations

  • Peng Wu
  • Hao Xu
  • Le Xu
  • Yueming Liu
  • Mingyuan He

Part of the SpringerBriefs in Molecular Science book series (BRIEFSMOLECULAR)

Also part of the SpringerBriefs in Green Chemistry for Sustainability book sub series (GREENCHEMIST)

Table of contents

  1. Front Matter
    Pages i-viii
  2. Peng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He
    Pages 1-8
  3. Peng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He
    Pages 9-34
  4. Peng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He
    Pages 35-61
  5. Peng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He
    Pages 63-123
  6. Peng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He
    Pages 125-125

About this book

Introduction

This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.

Keywords

Aldehyde Ammoximation Alkene Epoxidation Heterogeneous Catalysis Hydrogen Peroxide Ketone Ammoximation Selective Oxidation TS-1 Zeolite Ti-MWW Zeolite Titanosilicate Zeolite Zeolite Catalysts

Authors and affiliations

  • Peng Wu
    • 1
  • Hao Xu
    • 2
  • Le Xu
    • 3
  • Yueming Liu
    • 4
  • Mingyuan He
    • 5
  1. 1.Department of ChemistryEast China Normal UniversityShanghaiChina, People's Republic
  2. 2.Department of ChemistryEast China Normal UniversityShanghaiChina, People's Republic
  3. 3.Department of ChemistryEast China Normal UniversityShanghaiChina, People's Republic
  4. 4.Department of ChemistryEast China Normal UniversityShanghaiChina, People's Republic
  5. 5.Department of ChemistryEast China Normal UniversityShanghaiChina, People's Republic

Bibliographic information

  • DOI https://doi.org/10.1007/978-3-642-39115-6
  • Copyright Information The Author(s) 2013
  • Publisher Name Springer, Berlin, Heidelberg
  • eBook Packages Chemistry and Materials Science
  • Print ISBN 978-3-642-39114-9
  • Online ISBN 978-3-642-39115-6
  • Series Print ISSN 2191-5407
  • Series Online ISSN 2191-5415
  • Buy this book on publisher's site
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