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Doping of Carbon Nanotubes

  • Sergey Bulyarskiy
  • Alexandr Saurov

Part of the NanoScience and Technology book series (NANO)

Table of contents

  1. Front Matter
    Pages i-xiii
  2. Sergey Bulyarskiy, Alexandr S. Basaev, Darya A. Bogdanova
    Pages 57-101
  3. Sergey Bulyarskiy, Alexandr S. Basaev, Darya A. Bogdanova, Alexandr Pavlov
    Pages 103-113
  4. Alexandr Saurov, Sergey Bulyarskiy, Darya A. Bogdanova, Alexandr Pavlov
    Pages 115-169
  5. Alexandr Saurov, Sergey Bulyarskiy, Alexandr Pavlov
    Pages 171-182
  6. Back Matter
    Pages 183-187

About this book

Introduction

This book addresses the control of electronic properties of carbon nanotubes. It presents thermodynamic calculations of the formation of impurities and defects in the interaction of nanotubes with hydrogen, oxygen, nitrogen and boron, based on theoretical models of the formation of defects in carbon nanotubes. It is shown that doping and adsorption lead to changes in the electronic structure of the tubes as well as to the appearance of impurity states in the HOMO-LUMO gap. The book presents examples of specific calculations for doping of carbon nanotubes with oxygen, hydrogen, nitrogen and boron, together with numerous experimental results and a comparison with the author’s thermodynamic calculations. Possible directions of the technological processes of optimization are pointed out, as well as the perspectives of p-n-transition creation with the help of carbon nanotube arrays.

The results presented were derived from the physics of the processes and a theoretical model of the technological processes. Though a wealth of empirical information on doping nanotubes has been accumulated in the scientific literature, what is lacking is a theoretical model for their analysis. As such, the book develops a thermodynamic model of the self-organization of structural elements in multicomponent systems – including carbon nanotubes, clusters and precipitates in condensed matter – and subsequently adapts it to the doping of carbon nanotubes. This approach allows readers to gain a far deeper understanding of the processes of doping carbon nanotubes.

Keywords

Interaction of Carbon Nanotubes and Gas Molecules Defects in Carbon Nanotubes Influence of Defects on Electronic Properties of Nanotubes Electronic Properties of Single-walled CNTs Theoretical Thermodynamic Treatment

Editors and affiliations

  • Sergey Bulyarskiy
    • 1
  • Alexandr Saurov
    • 2
  1. 1.Institute Nanotechnology of MicroelectronicsRussian Academy of SciencesMoscowRussia
  2. 2.Institute Nanotechnology of MicroelectronicsRussian Academy of SciencesMoscowRussia

Bibliographic information

  • DOI https://doi.org/10.1007/978-3-319-55883-7
  • Copyright Information Springer International Publishing AG 2017
  • Publisher Name Springer, Cham
  • eBook Packages Chemistry and Materials Science
  • Print ISBN 978-3-319-55882-0
  • Online ISBN 978-3-319-55883-7
  • Series Print ISSN 1434-4904
  • Series Online ISSN 2197-7127
  • Buy this book on publisher's site
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