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Lithium Metal Anodes and Rechargeable Lithium Metal Batteries

  • Ji-Guang Zhang
  • Wu Xu
  • Wesley A. Henderson

Part of the Springer Series in Materials Science book series (SSMATERIALS, volume 249)

Table of contents

  1. Front Matter
    Pages i-xv
  2. Ji-Guang Zhang, Wu Xu, Wesley A. Henderson
    Pages 1-4
  3. Ji-Guang Zhang, Wu Xu, Wesley A. Henderson
    Pages 5-43
  4. Ji-Guang Zhang, Wu Xu, Wesley A. Henderson
    Pages 45-152
  5. Ji-Guang Zhang, Wu Xu, Wesley A. Henderson
    Pages 153-188
  6. Ji-Guang Zhang, Wu Xu, Wesley A. Henderson
    Pages 189-192
  7. Back Matter
    Pages 193-194

About this book

Introduction

This book provides comprehensive coverage of Lithium (Li) metal anodes for rechargeable batteries. Li is an ideal anode material for rechargeable batteries due to its extremely high theoretical specific capacity (3860 mAh g-1), low density (0.59 g cm-3), and the lowest negative electrochemical potential (−3.040 V vs. standard hydrogen electrode). Unfortunately, uncontrollable dendritic Li growth and limited Coulombic efficiency during Li deposition/stripping inherent in these batteries have prevented their practical applications over the past 40 years. With the emergence of post Li-ion batteries, safe and efficient operation of Li metal anode has become an enabling technology which may determine the fate of several promising candidates for the next generation energy storage systems, including rechargeable Li-air batteries, Li-S batteries, and Li metal batteries which utilize intercalation compounds as cathodes. 


In this work, various factors that affect the morphology and Coulombic efficiency of Li anode are analyzed. The authors also present the technologies utilized to characterize the morphology of Li deposition and the results obtained by modeling of Li dendrite growth. Finally, recent developments, especially the new approaches that enable safe and efficient operation of Li metal anode at high current densities are reviewed. The urgent need and perspectives in this field are also discussed. The fundamental understanding and approaches presented in this work will be critical for the application of Li metal anodes. The general principles and approaches can also be used in other metal electrodes and general electrochemical deposition of metal films.

  • Summarizes the opportunities and main challenges in the application of Li metal anodes in electrochemical devices
  • Reveals the fundamental mechanism of metal dendrite growth during electrochemical processes
  • Reviews the main approaches and techniques used to investigate Li metal deposition processes and Li film morphologies
  • Suggests key areas for the further development of Li metal anodes
  • Highlights how the general principles and approaches developed for repeated deposition/stripping of smooth Li metal films can be used in other metal electrode and general electrochemical deposition of metal films

Keywords

Coulombic Efficiency Dendrite Lithium Electrochemical Deposition Energy Storage Batteries Li Anode Li Metal Batteries Li-S batteries Li-air Batteries Li-ion Batteries Metal Electrode Batteries Rechargeable Batteries Li

Authors and affiliations

  • Ji-Guang Zhang
    • 1
  • Wu Xu
    • 2
  • Wesley A. Henderson
    • 3
  1. 1.Energy & Environment DirectoratePacific Northwest National LaboratoryRichlandUSA
  2. 2.Energy & Environment DirectoratePacific Northwest National Laboratory RichlandUSA
  3. 3.U.S. Army Research Office (ARO) Research Triangle ParkUSA

Bibliographic information

  • DOI https://doi.org/10.1007/978-3-319-44054-5
  • Copyright Information Springer International Publishing Switzerland 2017
  • Publisher Name Springer, Cham
  • eBook Packages Energy
  • Print ISBN 978-3-319-44053-8
  • Online ISBN 978-3-319-44054-5
  • Series Print ISSN 0933-033X
  • Series Online ISSN 2196-2812
  • Buy this book on publisher's site
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