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  • © 2019

Organometallic Magnets

Editors:

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  • Provides an overview of the state of art in the experimental and theoretical studies of organometallic magnets

  • Presents recent advances in the field of organometallic magnets

  • Multi-authored volume with contributions from experts in the field

Part of the book series: Topics in Organometallic Chemistry (TOPORGAN, volume 64)

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  • ISBN: 978-3-030-26009-5
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  • Tax calculation will be finalised during checkout
Softcover Book
USD 219.99
Price excludes VAT (USA)
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Table of contents (13 chapters)

  1. Front Matter

    Pages i-viii
  2. Hybrid Organic–Inorganic Cyanide-Bridged Networks

    • Tomasz Korzeniak, Beata Nowicka, Barbara Sieklucka
    Pages 1-34
  3. Cobalt(II) Complexes as Single-Ion Magnets

    • Shalini Tripathi, Atanu Dey, Maheswaran Shanmugam, Ramakirushnan Suriya Narayanan, Vadapalli Chandrasekhar
    Pages 35-75
  4. Cobalt(II)/(III)–Lanthanide(III) Complexes as Molecular Magnets

    • Atanu Dey, Shalini Tripathi, Maheswaran Shanmugam, Ramakirushnan Suriya Narayanan, Vadapalli Chandrasekhar
    Pages 77-100
  5. Tetrathiafulvalene-Based Magnets of Lanthanides

    • Olivier Cador, Fabrice Pointillart
    Pages 163-189
  6. Geometry and Magnetism of Lanthanide Compounds

    • Zhenhua Zhu, Jinkui Tang
    Pages 191-226
  7. Single-Ion Anisotropy: An Insight to Complicated Magnetic Molecules

    • Shang-Da Jiang, Bing-Wu Wang, Song Gao
    Pages 227-252
  8. Lanthanide Organometallics as Single-Molecule Magnets

    • María José Heras Ojea, Lewis C. H. Maddock, Richard A. Layfield
    Pages 253-280
  9. Complete Active Space Wavefunction-Based Analysis of Magnetization and Electronic Structure

    • Frédéric Gendron, Hélène Bolvin, Jochen Autschbach
    Pages 355-390
  10. Magnetism of Actinide Coordination Compounds

    • Jan van Leusen, Manfred Speldrich, Paul Kögerler
    Pages 391-410
  11. Correction to: Cobalt(II) Complexes as Single-Ion Magnets

    • Shalini Tripathi, Atanu Dey, Maheswaran Shanmugam, Ramakirushnan Suriya Narayanan, Vadapalli Chandrasekhar
    Pages 411-411
  12. Correction to: Cobalt(II)/(III)–Lanthanide(III) Complexes as Molecular Magnets

    • Atanu Dey, Shalini Tripathi, Maheswaran Shanmugam, Ramakirushnan Suriya Narayanan, Vadapalli Chandrasekhar
    Pages 413-413
  13. Back Matter

    Pages 415-418

About this book

This volume highlights the recent advances and state of art in the experimental and theoretical studies of organometallic magnets. A plethora of organic ligands such as Mannich-base derivatives, redox-active chromophores, cyanides, Schiff base among others are used to coordinate to 3d transition metals, 4f lanthanides and 5f actinides to design the molecular magnets. Deep analysis of the coordination sphere symmetry, electronic distribution, luminescence are investigated to perform magneto-structural correlation leading to a better understanding of the magnetic properties. Furthermore, the rationalization of the magnetic behavior can be reached using ab initio calculations. The multiple applications that these molecular magnets offer could revolutionize the high-density data storage, spintronics and quantum computing technologies. This volume provides a discussion of these topics from leading international experts and will be a useful reference for researchers working in this field.

Keywords

  • Mannich-base ligands
  • Lanthanide Single-Molecule
  • Tetrathiafulvalene-based magnets
  • Single-Molecule Magnets
  • Organometallic magnets

Editors and Affiliations

  • Department of Chemistry, Indian Institute of Technology, Kanpur, India

    Vadapalli Chandrasekhar

  • Institut des Sciences Chimiques de Rennes, Equipe Organométalliques : Matériaux et Catalyse, Rennes Cedex, France

    Fabrice Pointillart

About the editors

Chandrasekhar is an inorganic Chemist. He obtained his Ph. D from the Indian Institute of Science, Bangalore, India in 1982 and after a post-doctoral stint at the University of Massachusetts, Amherst, USA, he joined the Indian Institute of Technology Kanpur, India, where he is a full professor. He is currently on deputation to the National Institute of Science Education and Research, Bhubaneswar, India as its Director.  Chandrasekhar’s research interests are in the general areas of main-group inorganic chemistry and molecular materials. He has published over 325 papers, a monograph and several book chapters.  He has extensive collaborations with research groups in Spain, France, England and Germany.  He has been recognized both in India and outside for his contributions including membership of the editorial boards of several journals, awards such as the Shanti Swarup Bhatnagar Prize of the Council of Scientific and Industrial Research, India and the Wilhelm-Bessel Prize of the Alexander von Humboldt Foundation of Germany. He is a Fellow of all the science academies of India as well as the academy of sciences, Trieste, Italy.

Fabrice Pointillart obtained his PhD in physics and chemistry of materials from Pierre et Marie Curie University in 2005, supervised by Profs. C. Train and M. Verdaguer. After a two-year period of postdoctoral research at the Department of Chemistry “Ugo Schiff” and INSTM Research Unit, University of Florence with Profs. R. Sessoli and D. Gatteschi, he joined the University of Rennes 1 in 2007, as a CNRS researcher. His current research interests are focused on multifunctional molecular materials based on tetrathiafulvalene ligands combining single-molecule magnet behavior and optical properties. He has extensive collaborations with research groups in Switzerland, Japan, India, Russia and Italy. He was awarded of the CNRS Bronze Medal in 2014 and received the ERC consolidator grant in 2016 (acronym: MULTIPROSMM, full title: MULTIple PROperties Single Molecule Magnets, N° 725184).


Bibliographic Information

Buying options

eBook
USD 169.00
Price excludes VAT (USA)
  • ISBN: 978-3-030-26009-5
  • Instant PDF download
  • Readable on all devices
  • Own it forever
  • Exclusive offer for individuals only
  • Tax calculation will be finalised during checkout
Softcover Book
USD 219.99
Price excludes VAT (USA)
Hardcover Book
USD 299.99
Price excludes VAT (USA)