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Selectivity in Chemical Reactions

  • J. C. Whitehead

Part of the NATO ASI Series book series (ASIC, volume 245)

Table of contents

  1. Front Matter
    Pages i-xi
  2. Introduction

    1. Richard B. Bernstein
      Pages 1-21
  3. Specificty of Reagent States in Chemical Reactions

  4. Spin-Orbit Effects in Chemical Reactions

    1. Paul J. Dagdigian
      Pages 147-177
    2. V. Aquilanti, R. Candori, G. Liuti, F. Pirani
      Pages 179-194
  5. Orientation and Alignment in Chemical Reactions

  6. Reactions of van der Waals Complexes and Clusters

    1. C. Jouvet, M. Boivineau
      Pages 341-352
    2. George C. Schatz, Michael S. Fitzcharles
      Pages 353-364
  7. Accuracy and Availability of Potential Energy Surfaces

  8. Multiple Pathways in Chemical Reactions

  9. Applied Aspects of Chemical Selectivity

    1. Stephen J. Davis, Anne M. Woodward
      Pages 497-513
    2. D. Raybone, T. M. Watkinson, J. C. Whitehead
      Pages 515-523
    3. David R. Crosley, Karen J. Rensberger, Richard A. Copeland
      Pages 543-554
  10. Conclusion

    1. R. J. Donovan
      Pages 555-560
  11. Back Matter
    Pages 561-570

About this book

Introduction

The aim of this Workshop on "Selectivity in Chemical Reactions" was to examine the specific preferences exhibited by simple chemical reactions with regards to reagents having particular energy states, symmetries, alignment and orientation and the resulting formation of certain products with their corresponding energies, states, alignment and polarisation. Such problems come close to the ultimate goal of reaction dynamics of being able to determine experimentally and theoretically state-to-state cross sections and stereochemical effects under well defined and characterised conditions. There are many examples of highly selective and specific processes to be found in atmospheric and combustion chemistry and the production of population inversions amongst vibrational and electronic states lies at the heart of the development of chemical laser systems. Only when we can understand the fundamental processes that underlie the selectivity in the formation of products in a chemical reaction and the specific requirements of initial states of the reagents, can we expect to be able to develop the explanatory and predictive tools necessary to apply the subject to the development of new laser systems, efficient combustion schemes and specific methods of chemical synthesis, to the control of atmospheric pollution and to all problems in which it is necessary to direct the outcome of a chemical reaction in a specific way. The brief given to the Workshop was to critically review the field, to discuss the present limitations and difficulties and to identify new directions.

Keywords

Atom chemical reaction chemical synthesis combustion fluorescence

Editors and affiliations

  • J. C. Whitehead
    • 1
  1. 1.Department of ChemistryUniversity of ManchesterManchesterUK

Bibliographic information

  • DOI https://doi.org/10.1007/978-94-009-3047-6
  • Copyright Information Springer Science+Business Media B.V. 1988
  • Publisher Name Springer, Dordrecht
  • eBook Packages Springer Book Archive
  • Print ISBN 978-94-010-7870-2
  • Online ISBN 978-94-009-3047-6
  • Series Print ISSN 1389-2185
  • Buy this book on publisher's site
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