© 2017

Construction and Reactivity of Pt-Based Bi-component Catalytic Systems


  • Nominated by the Chinese Academy of Sciences as an outstanding PhD thesis

  • Outlines the development of Pt-based bi-component catalysts

  • Elucidates the correlation between the surface structure and reactivity of Pt-Ni catalysts

  • Describes the confinement effect of graphene for chemical reactions on the Pt(111) surface


Part of the Springer Theses book series (Springer Theses)

Table of contents

  1. Front Matter
    Pages i-xii
  2. Rentao Mu
    Pages 1-15
  3. Rentao Mu
    Pages 17-22
  4. Rentao Mu
    Pages 89-90

About this book


In this thesis, the author outlines the construction of active structure and modulation of catalytic reactivity of Pt-based bi-component catalysts, from the model systems to real supported catalysts. The thesis investigates the promotion effect of the second components on catalytic performance of Pt catalysts, and presents the reversible generation of the “sandwich-like” structure of Pt-Ni catalysts, containing both surface NiO1-X and subsurface Ni by alternating redox treatments at medium temperature. With the aid of single layer graphene, the dynamic process of chemical reactions occurring on the Pt(111) surface can be visualized using in-situ LEEM and DUV-PEEM techniques, the results of which are included here. The author reveals that the graphene layer exhibits a strong confinement effect on the chemistry of molecules underneath and the intercalated CO can desorb from the Pt surface around room temperature and in UHV, which may promote the CO oxidation confined under graphene.


Bi-component catalysts Confinement effect Nanocatalysis Pt-Ni bimetallic catalysts Redox treatments Single layer graphene Structure-performance correlation Heterogeneous catalysts

Authors and affiliations

  1. 1.Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalianUnited Kingdom

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