The Atom-Atom Potential Method

Applications to Organic Molecular Solids

  • Alexander J. Pertsin
  • Alexander I. Kitaigorodsky

Part of the Springer Series in Chemical Physics book series (CHEMICAL, volume 43)

Table of contents

  1. Front Matter
    Pages I-IX
  2. Alexander J. Pertsin, Alexander I. Kitaigorodsky
    Pages 1-5
  3. Alexander J. Pertsin, Alexander I. Kitaigorodsky
    Pages 6-68
  4. Alexander J. Pertsin, Alexander I. Kitaigorodsky
    Pages 69-148
  5. Alexander J. Pertsin, Alexander I. Kitaigorodsky
    Pages 149-225
  6. Alexander J. Pertsin, Alexander I. Kitaigorodsky
    Pages 226-282
  7. Alexander J. Pertsin, Alexander I. Kitaigorodsky
    Pages 283-337
  8. Alexander J. Pertsin, Alexander I. Kitaigorodsky
    Pages 338-371
  9. Back Matter
    Pages 373-397

About this book


The history of physics furnishes many examples of how a simple semiem­ pirical method, essentially based on intuitive considerations, may prove to be much more successful than a rigorous theoretical approach. A pertinent example is the method of atom-atom potentials, which treats the intermolec­ ular interactions between polyatomic molecules in terms of pairwise inter­ actions between their constituent atoms. Despite a few conceptual short­ comings, the method provides a fairly reliable practical means of handling, on a microscopic level, a wide range of problems that arise in the solid-state physics and chemistry of organic compounds. This monograph is an attempt to generalize the experience gained in the past twenty years in interpreting the static and dynamic properties of organic molecular solids in terms of atom-atom potentials. It embraces nearly all aspects of the application of the method, including an evaluation of cohesive energies, equilibrium crystal structures, phonon spectra, ther­ modynamic functions, and crystal defects. Many related topics such as the effect of the crystal field on molecular conformation, the determination of crystal structures from raw diffraction data, and the problem of polymor­ phic transitions are also discussed. We believe that this book will be of use to researchers in solid-state physics, chemistry, crystallography, physical chemistry, and polymer chem­ istry. It also gives us an opportunity to acknowledge our indebtedness to those who sent us published as well as unpublished information and sugges­ tions, including A.T. Amos, E.L. Bokhenkov, H. Bonadeo, R.K. Boyd, C.P.


Atom History of physics Substitution carboxylic acid crystal structure crystallography molecule phase transition physical chemistry physics polymer solid-state physics spectra structure thermodynamics

Authors and affiliations

  • Alexander J. Pertsin
    • 1
  • Alexander I. Kitaigorodsky
    • 1
  1. 1.Institute of Elemento-Organic CompoundsUSSR Academy of SciencesMoscowUSSR

Bibliographic information

  • DOI
  • Copyright Information Springer-Verlag Berlin Heidelberg 1987
  • Publisher Name Springer, Berlin, Heidelberg
  • eBook Packages Springer Book Archive
  • Print ISBN 978-3-642-82714-3
  • Online ISBN 978-3-642-82712-9
  • Series Print ISSN 0172-6218
  • Buy this book on publisher's site