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Chromium Oxidations in Organic Chemistry

  • Gianfranco Cainelli
  • Giuliana Cardillo
Book

Part of the Reactivity and Structure Concepts in Organic Chemistry book series (REACTIVITY, volume 19)

Table of contents

  1. Front Matter
    Pages I-X
  2. Gianfranco Cainelli, Giuliana Cardillo
    Pages 1-7
  3. Gianfranco Cainelli, Giuliana Cardillo
    Pages 8-58
  4. Gianfranco Cainelli, Giuliana Cardillo
    Pages 59-117
  5. Gianfranco Cainelli, Giuliana Cardillo
    Pages 118-216
  6. Gianfranco Cainelli, Giuliana Cardillo
    Pages 217-228
  7. Gianfranco Cainelli, Giuliana Cardillo
    Pages 229-237
  8. Gianfranco Cainelli, Giuliana Cardillo
    Pages 250-257
  9. Back Matter
    Pages 259-264

About this book

Introduction

Chromium oxidation, well known and widely explored in organic chemistry since the very beginning of this science, is a topic of current interest for the organic chemist as evidenced by the continuous development of new techni­ ques and procedures reported in the literature. Chromium oxidation is a simple process which can be easily performed in the laboratory and scaled up in industry as well. Although almost every oxidizable organic functional group may undergo chromium oxidation, the most important fields of appli­ cation are the oxidation of alcohols, allylic and benzylic oxidation, oxidative degradation and oxidation of some organometallic compounds. A high degree of selectivity is often possible by choosing the most suitable reagent among those several ones now available. This book takes account of the various functional groups that undergo oxidation and the entire literature up to 1982. It has been written in the hope to help the synthetic organic chemist in his experimental work. For this purpose a number of tables comprising yields and references have been included; detailed descriptions of typical procedures are meant to show the experimental conditions and the scope of the reactions. We wish to thank Dr. Mario Orena for his valuable scientific and technical assistence and Prof. Bruno Camerino, who read the entire manuscript and corrected many of the errors. Bologna, February 1984 Gianfranco Cainelli Giuliana Cardillo Table of Contents I. Introduction . . . . . . . . . . .

Keywords

Alkane Amine Hydroxylamin Ketone Phenol aromatic chromium heterocyclic compound metals organic chemistry phosphorus polymer silver sodium stereochemistry

Authors and affiliations

  • Gianfranco Cainelli
    • 1
  • Giuliana Cardillo
    • 1
  1. 1.Istituto Chimico Giacomo CiamicianUniversità degli Studi di BolognaBolognaItaly

Bibliographic information

  • DOI https://doi.org/10.1007/978-3-642-69362-5
  • Copyright Information Springer-Verlag Berlin Heidelberg 1984
  • Publisher Name Springer, Berlin, Heidelberg
  • eBook Packages Springer Book Archive
  • Print ISBN 978-3-642-69364-9
  • Online ISBN 978-3-642-69362-5
  • Series Print ISSN 0341-2377
  • Buy this book on publisher's site
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